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Metadata Report for BODC Series Reference Number 1336090


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Ms Sharon McNeill
Originating Organization Scottish Association for Marine Science
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) -
 

Data Identifiers

Originator's Identifier JC025_CTD_NUTS_3200:JC025_CTD033
BODC Series Reference 1336090
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2008-07-21 03:48
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 49.84461 N ( 49° 50.7' N )
Longitude 7.94785 W ( 7° 56.9' W )
Positional Uncertainty Unspecified
Minimum Sensor or Sampling Depth 2.5 m
Maximum Sensor or Sampling Depth 72.6 m
Minimum Sensor or Sampling Height 14.1 m
Maximum Sensor or Sampling Height 84.2 m
Sea Floor Depth 86.7 m
Sea Floor Depth Source -
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
AMONAATX1Micromoles per litreConcentration of ammonium {NH4+ CAS 14798-03-9} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
FIRSEQID1DimensionlessBottle firing sequence number
NTRZAATX1Micromoles per litreConcentration of nitrate+nitrite {NO3+NO2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
PHOSAATX1Micromoles per litreConcentration of phosphate {PO43- CAS 14265-44-2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
SDAMAATX1Micromoles per litreConcentration standard deviation of ammonium {NH4+ CAS 14798-03-9} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
SDNZAATX1Micromoles per litreConcentration standard deviation of nitrate+nitrite {NO3+NO2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
SDPHAATX1Micromoles per litreConcentration standard deviation of phosphate {PO43- CAS 14265-44-2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
SLCAAATX1Micromoles per litreConcentration of silicate {SiO44- CAS 17181-37-2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis
SLSDAATX1Micromoles per litreConcentration standard deviation of silicate {SiO44- CAS 17181-37-2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

JC025 Dissolved Inorganic Nutrients Sampling Document

Originator's protocol for data acquisition and analysis

Water samples were drawn from the CTD rosette bottles deployed during the JC025 cruise with the majority of the sampling effort concentrated in the top 140 m of the water column.

Samples were analysed within 24 hours of collection and refridgerated prior to analysis. Measurements were made using standard colorimetric methods with a Lachat Autoanalyser.

Primary standards were prepared as follows:

  • Ammonium 10013.27 µM
  • Phosphate 10028.95 µM
  • Nitrate 10072.30 µM
  • Silicate 10511.86 µM

A mixed nutrient stock was prepared from adding 1 ml NH4, 0.5 ml PO4, 2 ml SiO2 and 3 ml NO3 of the primary standards, as listed above, and diluting to 100 ml. Five working stocks were subsequently prepared by diluting down the mixed nutrient stock, giving the highest concentration of 5 µM NH4, 2.5 µM PO4, 10.5 µM SiO2 and 15.1 µM NO3. Analyses of triplicate samples showed that results were reproducible to within 5% at concentrations >1 µM, with errors increasing at lower concentrations.

References

Sharples, J., et al. (2009) JC025 Cruise Report, Celtic Sea, 2 July - 27 July 2008. Proudman Oceanographic Laboratory, UK.

Available - JC025 Cruise Report

BODC data processing procedures

The nutrient data were supplied to BODC in Microsoft Excel format and values were extracted from these and saved in ASCII format prior to being loaded into the project database under the ORACLE Relational Database Management System without modification. Data that were considered unrealistic and lay outside of the permitted range for the parameter code were flagged suspect.

SAMS nitrate data quality warning

SAMS have notified BODC of a problem in the analytical procedure adopted for nitrate analysis on this cruise. The problem relates to the technique used to prepare the analytical standards, which results in nitrate (and consequently nitrite) values which are typically 10-15 % higher than they should be. Absolute data values should therefore be used with extreme caution.

Content of data series

Originator's Parameter Unit Description BODC Parameter code BODC Unit Comments
Ammonium µM Concentration of ammonium {NH4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis AMONAATX µmol/L -
Standard deviation of ammonium µM Concentration standard deviation of ammonium {NH4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis SDAMAATX µmol/L -
Phosphate µM Concentration of phosphate {PO4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis PHOSAATX µmol/L -
Standard deviation of phosphate µM Concentration standard deviation of phosphate {PO4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis SDPHAATX µmol/L -
Silicate µM Concentration of silicate {SiO4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis SLCAAATX µmol/L -
Standard deviation of silicate µM Concentration standard deviation of silicate {SiO4} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis SLSDAATX µmol/L -
Nitrate µM Concentration of nitrate+nitrite {NO3+NO2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis NTRZAATX µmol/L -
Standard deviation of nitrate µM Concentration standard deviation of nitrate+nitrite {NO3+NO2} per unit volume of the water body [dissolved plus reactive particulate phase] by colorimetric autoanalysis SDNZAATX µmol/L -

Project Information


No Project Information held for the Series

Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2008-07-21
End Date (yyyy-mm-dd) 2008-07-21
Organization Undertaking ActivityProudman Oceanographic Laboratory (now National Oceanography Centre, Liverpool)
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierJC025_CTD_JC025_CTD033
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for JC025_CTD_JC025_CTD033

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
237028   20.00 1 1   73.10   73.30   72.60 Niskin bottle No problem reported    
237029   20.00 2 2   72.70   73.60   72.50 Niskin bottle No problem reported    
237030   20.00 3 3   52.20   52.80   52.00 Niskin bottle No problem reported    
237031   20.00 4 4   52.10   52.50   51.80 Niskin bottle No problem reported    
237032   20.00 5 5   42.00   42.50   41.90 Niskin bottle No problem reported    
237033   20.00 6 6   42.20   42.40   41.90 Niskin bottle No problem reported    
237034   20.00 7 7   42.00   42.60   41.90 Niskin bottle No problem reported    
237035   20.00 8 8   35.80   36.20   35.70 Niskin bottle No problem reported    
237036   20.00 9 9   35.90   36.20   35.70 Niskin bottle No problem reported    
237037   20.00 10 10   30.00   30.20   29.80 Niskin bottle No problem reported    
237038   20.00 11 11   29.90   30.10   29.70 Niskin bottle No problem reported    
237039   20.00 12 12   29.70   30.20   29.70 Niskin bottle No problem reported    
237040   20.00 13 13   18.50   18.70   18.40 Niskin bottle No problem reported    
237041   20.00 14 14   18.60   18.80   18.50 Niskin bottle No problem reported    
237042   20.00 15 15   18.40   18.90   18.50 Niskin bottle No problem reported    
237043   20.00 16 16   14.30   15.00   14.50 Niskin bottle No problem reported    
237044   20.00 17 17   14.50   14.80   14.50 Niskin bottle No problem reported    
237045   20.00 18 18   14.40   14.80   14.50 Niskin bottle No problem reported    
237046   20.00 19 19    7.30    7.80    7.50 Niskin bottle No problem reported    
237047   20.00 20 20    7.50    7.70    7.50 Niskin bottle No problem reported    
237048   20.00 21 21    7.50    7.80    7.60 Niskin bottle No problem reported    
237049   20.00 22 22    2.30    2.80    2.50 Niskin bottle No problem reported    
237050   20.00 23 23    2.30    2.80    2.50 Niskin bottle No problem reported    
237051   20.00 24 24    2.30    2.80    2.50 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Cruise

Cruise Name JC025
Departure Date 2008-07-02
Arrival Date 2008-07-27
Principal Scientist(s)Jonathan Sharples (Proudman Oceanographic Laboratory)
Ship RRS James Cook

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification