AMT12 major ions and trace metals in aerosol samples
Originator's Protocol for Data Acquisition and Analysis
Atmospheric sampling was conducted on the JCR's monkey island when wind conditions permitted, i.e. the apparent wind direction was forward of the monkey island ensuring no contamination from the ship's stacks. Samplers were in general turned off while on station unless the bridge were confident of remaining head to wind throughout all manoeuvring. Sampling throughout passage allowed 16-20 hours sampling per day. Three high volume aerosol samplers (approx. 1 m 3 min -1 ) were deployed. One was for major ions and used conventional Whatman 41 filter substrates. One was for trace metals and used conventional Whatman 41 filter substrates after rigorous acid pre-cleaning. One filter system malfunctioned during the cruise and subsequently trace metal and organic samples were collected on alternate days. Filters were changed in a laminar flow cabinet and subsequently frozen. On most occasions, cascade impactors were used for major ion and trace metals sampling to allow discrimination between aerosol particles < and > 1 µm.
Analyses were carried out once the samples were returned to the laboratory at the University of East Anglia (UEA). The methodology followed that detailed in Baker et al. (2006) and the main analytical technique for each parameter is listed in the table below.
References Cited
Baker A.R., Jickells T.D., Biswas K.F. and French M., (2006). Nutrients in atmospheric aerosol particles along the Atlantic Meridional Transect. Deep Sea Research: Part II, 53, 1706-1719.
Instrumentation Description
Not relevant to this data set.
BODC Data Processing Procedures
Data were submitted to BODC on three occasions, when the data from each successive file superseded the previous data with additional parameters included in the latest submission. The most recent submission was received on 10/11/2008 and contained the data from AMT cruises 12-17 and was loaded to the archive with BODC accession number UEA060021. Data were submitted in an Excel spreadsheet with the following metadata; Sampling start and end date and time, Latitude and Longitude. Sample metadata were checked against information held in the database - there were no metadata in the database, so the data for the sampling events were loaded from the originator's file. Parameter codes were assigned to the variables; most of the parameters were provided in nmol m -3 and were converted to pmol m -3 to be consistent with parameters in the BODC parameter database. Data were loaded into BODC's database using established BODC data banking procedures.
A parameter mapping table is provided below;
Originator's Parameter | Units | Description | BODC Parameter Code | BODC StDev Parameter Code | Units | Comments |
---|---|---|---|---|---|---|
Na Fine (<1 µm) | nmol m -3 | Concentration of sodium {Na} per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACNAAE01 | ASDNAA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Na Coarse (>1 µm) | nmol m -3 | Concentration of sodium {Na} per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACNAAE02 | ASDNAA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Na Total | nmol m -3 | Concentration of sodium {Na} per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACNAXX01 | ASDNAX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NH4 Fine (<1 µm) | nmol m -3 | Concentration of ammonium {NH 4 } per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACAMAE01 | ASDAMA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NH4 Coarse (>1 µm) | nmol m -3 | Concentration of ammonium {NH 4 } per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACAMAE02 | ASDAMA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NH4 Total | nmol m -3 | Concentration of ammonium {NH 4 } per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACNH4X01 | ASDAMX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Mg Fine (<1 µm) | nmol m -3 | Concentration of magnesium {Mg} per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACMGAE01 | ASDMGA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Mg Coarse (>1 µm) | nmol m -3 | Concentration of magnesium {Mg} per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACMGAE02 | ASDMGA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Mg Total | nmol m -3 | Concentration of magnesium {Mg} per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACMGXX01 | ASDMGX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
K Fine (<1 µm) | nmol m -3 | Concentration of potassium {K} per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACKAER01 | ASDKIC01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
K Coarse (>1 µm) | nmol m -3 | Concentration of potassium {K} per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACKAER02 | ASDKIC02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
K Total | nmol m -3 | Concentration of potassium {K} per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACKXXX01 | ASDKIX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Ca Fine (<1 µm) | nmol m -3 | Concentration of calcium {Ca} per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACCAAE01 | ASDCAI01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Ca Coarse (>1 µm) | nmol m -3 | Concentration of calcium {Ca} per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACCAAE02 | ASDCAI02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Ca Total | nmol m -3 | Concentration of calcium {Ca} per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACCAXX01 | ASDCAX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Cl Fine (<1 µm) | nmol m -3 | Concentration of chloride {Cl} per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACCLAE01 | ASDCLA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Cl Coarse (>1 µm) | nmol m -3 | Concentration of chloride {Cl} per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACCLAE02 | ASDCLA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Cl Total | nmol m -3 | Concentration of chloride {Cl} per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACCLXX01 | ASDCLX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NO3 Fine (<1 µm) | nmol m -3 | Concentration of nitrate {NO 3 } per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACNITA01 | ASDNIT01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NO3 Coarse (>1 µm) | nmol m -3 | Concentration of nitrate {NO 3 } per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACNITA02 | ASDNIT02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
NO3 Total | nmol m -3 | Concentration of nitrate {NO 3 } per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACNO3X01 | ASDNIX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
SO4 Fine (<1 µm) | nmol m -3 | Concentration of sulphate {SO 4 } per unit volume of the atmosphere [aerosol <1um phase] by filtration and colorimetric analysis | ACSUAE01 | ASDSUA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
SO4 Coarse (>1 µm) | nmol m -3 | Concentration of sulphate {SO 4 } per unit volume of the atmosphere [aerosol >1um phase] by filtration and colorimetric analysis | ACSUAE02 | ASDSUA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
SO4 Total | nmol m -3 | Concentration of sulphate {SO 4 } per unit volume of the atmosphere [aerosol phase] by filtration and colorimetric analysis | ACSO4X01 | ASDSUX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
PO4 Fine (<1 µm) | pmol m -3 | Concentration of phosphate {PO 4 } per unit volume of the atmosphere [aerosol <1um phase] by filtration and colorimetric analysis | ACPAER01 | ASDPAE01 | pmol m -3 | No unit conversion necessary |
PO4 Coarse (>1 µm) | pmol m -3 | Concentration of phosphate {PO 4 } per unit volume of the atmosphere [aerosol >1um phase] by filtration and colorimetric analysis | ACPAER02 | ASDPAE02 | pmol m -3 | No unit conversion necessary |
PO4 Total | pmol m -3 | Concentration of phosphate {PO 4 } per unit volume of the atmosphere [aerosol phase] by filtration and colorimetric analysis | ACPAER03 | ASDPAE03 | pmol m -3 | No unit conversion necessary |
SiO4 Fine (<1 µm) | nmol m -3 | Concentration of silicate {SiO 4 } per unit volume of the atmosphere [aerosol <1um phase] by filtration and ion chromatography | ACSIAE01 | ASDSIA01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
SiO4 Coarse (>1 µm) | nmol m -3 | Concentration of silicate {SiO 4 } per unit volume of the atmosphere [aerosol >1um phase] by filtration and ion chromatography | ACSIAE02 | ASDSIA02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
SiO4 Total | nmol m -3 | Concentration of silicate {SiO 4 } per unit volume of the atmosphere [aerosol phase] by filtration and ion chromatography | ACSIAX01 | ASDSIX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
TDN Fine (<1 µm) | nmol m -3 | Concentration of nitrogen (total) per unit volume of the atmosphere [aerosol <1um phase] by filtration and high temperature Pt catalytic oxidation | ACTNCO01 | ASDTNC01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
TDN Coarse (>1 µm) | nmol m -3 | Concentration of nitrogen (total) per unit volume of the atmosphere [aerosol >1um phase] by filtration and high temperature Pt catalytic oxidation | ACTNCO02 | ASDTNC02 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
TDN Total | nmol m -3 | Concentration of nitrogen (total) per unit volume of the atmosphere [aerosol phase] by filtration and high temperature Pt catalytic oxidation | ACNTCX01 | ASDTNX01 | pmol m -3 | Conversion factor x1000 applied for conversion from nmol m -3 to pmol m -3 |
Soluble Fe Fine (<1 µm) | pmol m -3 | Concentration of iron (soluble) {Fe} per unit volume of the atmosphere [aerosol <1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACSFEA01 | ASDSFE01 | pmol m -3 | No unit conversion necessary |
Soluble Fe Coarse (>1 µm) | pmol m -3 | Concentration of iron (soluble) {Fe} per unit volume of the atmosphere [aerosol >1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACSFEA02 | ASDSFE02 | pmol m -3 | No unit conversion necessary |
Soluble Fe Total | pmol m -3 | Concentration of iron (soluble) {Fe} per unit volume of the atmosphere [aerosol phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACSFEX01 | ASDFEX01 | pmol m -3 | No unit conversion necessary |
Soluble Al Fine (<1 µm) | pmol m -3 | Concentration of aluminium (soluble) {Al} per unit volume of the atmosphere [aerosol <1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACALAE01 | ASDALE01 | pmol m -3 | No unit conversion necessary |
Soluble Al Coarse (>1 µm) | pmol m -3 | Concentration of aluminium (soluble) {Al} per unit volume of the atmosphere [aerosol >1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACALAE02 | ASDALE02 | pmol m -3 | No unit conversion necessary |
Soluble Al Total | pmol m -3 | Concentration of aluminium (soluble) {Al} per unit volume of the atmosphere [aerosol phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACALAX01 | ASDALX01 | pmol m -3 | No unit conversion necessary |
Soluble Mn Fine (<1 µm) | pmol m -3 | Concentration of manganese (soluble) {Mn} per unit volume of the atmosphere [aerosol <1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACMNAE01 | ASDMNE01 | pmol m -3 | No unit conversion necessary |
Soluble Mn Coarse (>1 µm) | pmol m -3 | Concentration of manganese (soluble) {Mn} per unit volume of the atmosphere [aerosol >1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACMNAE02 | ASDMNE02 | pmol m -3 | No unit conversion necessary |
Soluble Mn Total | pmol m -3 | Concentration of manganese (soluble) {Mn} per unit volume of the atmosphere [aerosol phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACMNAX01 | ASDMNX01 | pmol m -3 | No unit conversion necessary |
Soluble Zn Fine (<1 µm) | pmol m -3 | Concentration of zinc (soluble) {Zn} per unit volume of the atmosphere [aerosol <1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACZNAE01 | ASDZNE01 | pmol m -3 | No unit conversion necessary |
Soluble Zn Coarse (>1 µm) | pmol m -3 | Concentration of zinc (soluble) {Zn} per unit volume of the atmosphere [aerosol >1um phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACZNAE02 | ASDZNE02 | pmol m -3 | No unit conversion necessary |
Soluble Zn Total | pmol m -3 | Concentration of zinc (soluble) {Zn} per unit volume of the atmosphere [aerosol phase] by filtration and inductively-coupled plasma atomic emission spectroscopy | ACZNAX01 | ASDZNX01 | pmol m -3 | No unit conversion necessary |
Data Quality Report
BODC were not advised of specific quality checks carried out by the data originator. A number of the samples had concentrations lower than the detection limit. This detection limit was calculated assuming a sample volume of 1400m 3 , but since there was variation in the volumes sampled the concentrations quoted in conjunction with the 'below detection limit' flag (<) are reported as 75% of the concentration with a 1400m 3 volume.
Problem Report
Not relevant to this data set.