Metadata Report for BODC Series Reference Number 1347481
Metadata Summary
Problem Reports
Data Access Policy
Narrative Documents
Project Information
Data Activity or Cruise Information
Fixed Station Information
BODC Quality Flags
SeaDataNet Quality Flags
Metadata Summary
Data Description |
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Data Identifiers |
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Time Co-ordinates(UT) |
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Spatial Co-ordinates | |||||||||||||||||||||||||||||||||||||||||
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Parameters |
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Definition of BOTTFLAG | |||||||||||||||||||||||||||||||||||||||||
BOTTFLAG | Definition |
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0 | The sampling event occurred without any incident being reported to BODC. |
1 | The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material. |
2 | Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling. |
3 | The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired. |
4 | During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes. |
5 | Water was reported to be escaping from the bottle as the rosette was being recovered. |
6 | The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery. |
7 | Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist). |
8 | There is reason to doubt the accuracy of the sampling depth associated with the sample. |
9 | The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage. |
Definition of Rank |
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Problem Reports
No Problem Report Found in the Database
Data Access Policy
Open Data
These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.
If the Information Provider does not provide a specific attribution statement, or if you are using Information from several Information Providers and multiple attributions are not practical in your product or application, you may consider using the following:
"Contains public sector information licensed under the Open Government Licence v1.0."
Narrative Documents
Niskin Bottle
The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.
Standard Niskin
The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.
Lever Action Niskin
The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.
Clean Sampling
A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.
Deployment
Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.
Inorganic nutrients concentrations (nanomolar sensitivity nitrate plus nitrite and phosphate) for UK SOLAS cruise Discovery D326
Originator's Protocol for Data Acquisition and Analysis
Water samples for nanomolar sensitivity nutrients were collected from the stainless steel and titanium CTD deployments. The 20 litre OTE bottles and 10 litre OTE trace metal bottles were subsampled into acid washed 60 ml LDPE bottles. Pumped surface samples were also taken from the trace metal clean fish.
Analyses for nitrate plus nitrite and phosphate at nanomolar concentrations were conducted on a purpose built, segmented flow autoanalyser. The method is described and reviewed in detail by Patey et al., 2008. Two liquid waveguide capillary flow cells provided a two metre pathlength. Two tungsten-halogen light sources were used in conjunction with fibre optic spectrometers to monitor the absorbance of the solution flowing through the waveguide. In general, samples only believed to have very low concentrations of dissolved nutrients were analysed.
References Cited
Patey M.D., Rijkenberg M.J.R., Statham P.J., Stinchcombe M.C., Achterberg E.P., Mowlem M., 2003. Determination of nitrate and phosphate in seawater at nanomolar concentrations. Trends in Analytical Chemistry. 22, 819-827.
BODC Data Processing Procedures
The final quality controlled version of the nanomolar sensitivity nutrients data were received from Matt Patey who as a UK SOLAS PhD student supervised by E. Achterberg was in charge of the analysis and processing of these data as part of his PhD. The data were sent as an updated version of the D326 CTD and underway compendium files compiled by Micha Rijkenberg. The files were archived in accession SOC090255. CTD data were identified using CTD cast number, bottle number and approximate bottle firing depth. Underway data were identified using samples identifiers and sampling date and time. No discrepancies were found between the source files and existing records in BODC database.
Parameter codes defined in BODC parameter dictionary were assigned to the variables as follows:
Originator's Parameter | Units | Description | BODC Parameter Code | Units | Comments |
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nM NO2/3 | nM | Concentration of nitrate plus nitrite (nanomolar sensitivity) | NTRZLWTX | µmol l-1 | Values converted by dividing by 1000, with precision valid to the fifth decimal place |
stdev | nM | Standard deviation of replicate nitrate plus nitrite samples | SDNZLWTX | µmol l-1 | |
nM PO4 | nM | Concentration of phosphate (nanomolar sensitivity) | PHOSLWTX | µmol l-1 | Values converted by dividing by 1000, with precision valid to the fifth decimal place |
stdev | nM | Standard deviation of replicate phosphate samples | SDPHLWTX | µmol l-1 |
The data were banked according to BODC standard procedures for sample data. The data were banked as received, with no averaging or other modifications applied.
Data Quality Report
The data have been quality controlled by the originators. Some phosphate concentrations on two casts (16415A and 16416A) were highlighted as being of poorer quality than usual by the originator due to problems with the calibration. These data have been flagged using the flag for data originator's QC issue in the BODC quality flag scheme.
Data users should be aware that the data have been measured using a method allowing nanomolar sensitivity and the values in µmol l-1 are therefore precise down to the fourth decimal place.
Project Information
UK Surface Ocean Lower Atmosphere Study
The UK Surface Ocean Lower Atmosphere Study (UK SOLAS) is the UK's contribution to the international SOLAS programme.
UK SOLAS formed interdisciplinary teams to address three primary aims
- To determine the mechanisms controlling rates of chemical transfer and improve estimates of chemical exchanges
- To evaluate the impact of these exchanges on the biogeochemistry of the surface ocean and lower atmosphere and on feedbacks between the ocean and atmosphere
- To quantify the impacts of these boundary layer processes on the global climate system
UK SOLAS started in 2003, to run for seven years. The programme was funded by the Natural Environment Research Council.
Funded projects
In total, 19 projects have been funded by UK SOLAS, over four funding rounds.
Project Title | Short Title | Principal Investigator |
---|---|---|
Impact of atmospheric dust derived material and nutrient inputs on near-surface plankton microbiota in the tropical North Atlantic | Dust | Eric Achterberg |
The role and effects of photoprotective compounds in marine plankton | - | Steve Archer |
Field observations of sea spray, gas fluxes and whitecaps | SEASAW | Ian Brooks |
Factors influencing the biogeochemistry of iodine in the marine environment | - | Lucy Carpenter |
Global model of aerosol processes - effects of aerosol in the marine atmospheric boundary layer | GLOMAP | Ken Carslaw |
Ecological controls on fluxes of dimethyl sulphide (DMS) to the atmosphere | - | David Green |
Dust outflow and deposition to the ocean | DODO | Ellie Highwood |
Investigation of near surface production of iodocarbons - rates and exchanges | INSPIRE | Gill Malin |
Reactive halogens in the marine boundary layer | RHaMBLe | Gordon McFiggans |
The role of bacterioneuston in determining trace gas exchange rates | - | Colin Murrell |
Measuring methanol in sea water and investigating its sources and sinks in the marine environment | - | Phil Nightingale |
The impact of coastal upwellings on air-sea exchange of climatically important gases | ICON | Carol Robinson |
The Deep Ocean Gas Exchange Experiment | DOGEE | Rob Upstill-Goddard |
High wind air-sea exchanges | HiWASE | Margaret Yelland |
Aerosol characterisation and modelling in the marine environment | ACMME | James Allan |
3D simulation of dimethyl sulphide (DMS) in the north east Atlantic | - | Icarus Allen |
Processes affecting the chemistry and bioavailability of dust borne iron | - | Michael Krom |
The chemical structure of the lowermost atmosphere | - | Alastair Lewis |
Factors influencing the oxidative chemistry of the marine boundary layer | - | Paul Monks |
UK SOLAS has also supported ten tied studentships, and two CASE studentships.
Fieldwork
UK SOLAS fieldwork has included eight dedicated research cruises in the North Atlantic Ocean. Continuous measurements were made aboard aboard the Norwegian weather ship, Polarfront, until her decommission in 2009. Time series have been established at the SOLAS Cape Verde Observatory, and at the Plymouth Marine Laboratory L4 station. Experiments have taken place at the Bergen mesocosm facility.
A series of collaborative aircraft campaigns have added complementary atmospheric data. These campaigns were funded by UK SOLAS, African Monsoon Multidisciplinary Analyses (AMMA-UK), Dust and Biomass Experiment (DABEX) and the Facility for Airborne Atmospheric Measurements (FAAM).
Weblink: http://www.nerc.ac.uk/research/programmes/solas/
Data Activity or Cruise Information
Data Activity
Start Date (yyyy-mm-dd) | 2008-01-10 |
End Date (yyyy-mm-dd) | 2008-01-10 |
Organization Undertaking Activity | University of Southampton School of Ocean and Earth Science |
Country of Organization | United Kingdom |
Originator's Data Activity Identifier | D326_CTD_16392A |
Platform Category | lowered unmanned submersible |
BODC Sample Metadata Report for D326_CTD_16392A
Sample reference number | Nominal collection volume(l) | Bottle rosette position | Bottle firing sequence number | Minimum pressure sampled (dbar) | Maximum pressure sampled (dbar) | Depth of sampling point (m) | Bottle type | Sample quality flag | Bottle reference | Comments |
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193932 | 20.00 | 5 | 5 | 163.20 | 164.60 | 162.80 | Niskin bottle | No problem reported | ||
193933 | 20.00 | 6 | 6 | 162.60 | 163.70 | 162.00 | Niskin bottle | No problem reported | ||
193934 | 20.00 | 7 | 7 | 142.50 | 143.30 | 141.90 | Niskin bottle | No problem reported | ||
193935 | 20.00 | 8 | 8 | 143.10 | 144.00 | 142.60 | Niskin bottle | No problem reported | ||
193936 | 20.00 | 9 | 9 | 142.20 | 143.20 | 141.70 | Niskin bottle | No problem reported | ||
193937 | 20.00 | 10 | 10 | 142.80 | 144.40 | 142.60 | Niskin bottle | No problem reported | ||
193938 | 20.00 | 11 | 11 | 123.20 | 123.90 | 122.70 | Niskin bottle | No problem reported | ||
193939 | 20.00 | 12 | 12 | 122.00 | 124.40 | 122.40 | Niskin bottle | No problem reported | ||
193940 | 20.00 | 13 | 13 | 82.60 | 83.10 | 82.30 | Niskin bottle | No problem reported | ||
193941 | 20.00 | 14 | 14 | 81.90 | 82.90 | 81.80 | Niskin bottle | No problem reported | ||
193942 | 20.00 | 15 | 15 | 52.20 | 52.90 | 52.20 | Niskin bottle | No problem reported | ||
193943 | 20.00 | 16 | 16 | 51.40 | 52.70 | 51.70 | Niskin bottle | No problem reported | ||
193944 | 20.00 | 17 | 17 | 31.60 | 33.50 | 32.30 | Niskin bottle | No problem reported | ||
193945 | 20.00 | 18 | 18 | 31.40 | 33.70 | 32.30 | Niskin bottle | No problem reported | ||
193946 | 20.00 | 19 | 19 | 11.80 | 12.80 | 12.20 | Niskin bottle | No problem reported | ||
193947 | 20.00 | 20 | 20 | 12.10 | 12.80 | 12.40 | Niskin bottle | No problem reported | ||
193948 | 20.00 | 21 | 21 | 7.30 | 8.20 | 7.70 | Niskin bottle | No problem reported | ||
193949 | 20.00 | 22 | 22 | 6.80 | 8.10 | 7.40 | Niskin bottle | No problem reported | ||
193950 | 20.00 | 23 | 23 | 7.30 | 8.10 | 7.60 | Niskin bottle | No problem reported | ||
193951 | 20.00 | 24 | 24 | 6.50 | 8.50 | 7.50 | Niskin bottle | No problem reported | ||
194044 | 20.00 | 1 | 1 | 303.20 | 304.00 | 301.40 | Niskin bottle | No problem reported | ||
194045 | 20.00 | 2 | 2 | 303.50 | 304.40 | 301.70 | Niskin bottle | No problem reported | ||
194046 | 20.00 | 3 | 3 | 202.80 | 204.20 | 202.10 | Niskin bottle | No problem reported | ||
194047 | 20.00 | 4 | 4 | 203.00 | 204.80 | 202.50 | Niskin bottle | No problem reported |
Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.
Related Data Activity activities are detailed in Appendix 1
Cruise
Cruise Name | D326 |
Departure Date | 2008-01-05 |
Arrival Date | 2008-02-05 |
Principal Scientist(s) | Eric Pieter Achterberg (University of Southampton School of Ocean and Earth Science) |
Ship | RRS Discovery |
Complete Cruise Metadata Report is available here
Fixed Station Information
No Fixed Station Information held for the Series
BODC Quality Control Flags
The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:
Flag | Description |
---|---|
Blank | Unqualified |
< | Below detection limit |
> | In excess of quoted value |
A | Taxonomic flag for affinis (aff.) |
B | Beginning of CTD Down/Up Cast |
C | Taxonomic flag for confer (cf.) |
D | Thermometric depth |
E | End of CTD Down/Up Cast |
G | Non-taxonomic biological characteristic uncertainty |
H | Extrapolated value |
I | Taxonomic flag for single species (sp.) |
K | Improbable value - unknown quality control source |
L | Improbable value - originator's quality control |
M | Improbable value - BODC quality control |
N | Null value |
O | Improbable value - user quality control |
P | Trace/calm |
Q | Indeterminate |
R | Replacement value |
S | Estimated value |
T | Interpolated value |
U | Uncalibrated |
W | Control value |
X | Excessive difference |
SeaDataNet Quality Control Flags
The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:
Flag | Description |
---|---|
0 | no quality control |
1 | good value |
2 | probably good value |
3 | probably bad value |
4 | bad value |
5 | changed value |
6 | value below detection |
7 | value in excess |
8 | interpolated value |
9 | missing value |
A | value phenomenon uncertain |
B | nominal value |
Q | value below limit of quantification |
Appendix 1: D326_CTD_16392A
Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.
If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.
Series Identifier | Data Category | Start date/time | Start position | Cruise |
---|---|---|---|---|
2119205 | Water sample data | 2008-01-10 06:50:30 | 26.76469 N, 28.93878 W | RRS Discovery D326 |
2124791 | Water sample data | 2008-01-10 06:50:30 | 26.76469 N, 28.93878 W | RRS Discovery D326 |
2134607 | Water sample data | 2008-01-10 06:50:30 | 26.76469 N, 28.93878 W | RRS Discovery D326 |
1345911 | Water sample data | 2008-01-10 06:51:00 | 26.76469 N, 28.93878 W | RRS Discovery D326 |
1984756 | Water sample data | 2008-01-10 06:51:00 | 26.76469 N, 28.93878 W | RRS Discovery D326 |