Metadata Report for BODC Series Reference Number 2105511

• Metadata Summary

• Problem Reports

• Data Access Policy

• Narrative Documents

• Project Information

• Data Activity or Cruise Information

• Fixed Station Information

• BODC Quality Flags

• SeaDataNet Quality Flags

Metadata Summary

Problem Reports

No Problem Report Found in the Database

Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."

Narrative Documents

Metrohm 848 Titrino Plus titrator

The Metrohm 848 Titrino Plus is a titrator used for dynamic and monotonic determination of solution concentrations. The Titrino Plus is simple to operate and robust so is ideal for daily, routine laboratory titrations. The titrator can be used in applications such as aqueous and non-aqueous, acid and base, redox, precipitation, complexometric and photometric titrations as well as titrations with polarizable electrodes.

The 848 Titrino Plus is composed of an exchange unit, stirrer and USB compact printer that when connected are automatically recognized and configured. The Metrohm exchange unit contains an intelligent chip that automatically passes data necessary for an error-free titration, such as cylinder volume, reagent type and titer validity, to the titrator. The high-resolution measuring interface of the 848 Titrino also ensures that highly precise results are obtained and the large live display, with titration curve, enables the user to easily determine the status of a titration.

Either a magnetic stirrer or a propeller stirrer can be connected to the Titrino Plus and the stirring rate is stored, guaranteeing maximum reproducibility of data.

Specifications

Further details can be found in the manufacturer's specification sheet.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

AMT22 (JC079) dissolved oxygen concentrations from CTD bottle samples

Originator's Protocol for Data Acquisition and Analysis

This data originated from analyses on samples collected from 37 CTD casts during the cruise. Eight glass 125 mL bottle were filled with seawater taken directly from the Niskin bottles at 8 different depths using a silicone tube. Samples were fixed immediately and analysed during the following 24 hours.

Discrete dissolved oxygen concentration was measured by automated precision Winkler titration performed with a Metrohm 848 Titrino, utilising a potentiometric end point as described in Serret et al. (1999). The concentration of thiosulphate was calibrated every day.

References Cited

Serret P., Fernández E., Sostres J.A., Anadón R., 1999. Seasonal compensation of plankton production and respiration in a temperate sea. Marine Ecology Progress Series 187: 43-57.

Instrumentation Description

Metrohm 848 Titrino

BODC Data Processing Procedures

Data were submitted during the cruise in an Excel spreadsheet for calibration of the Sea-Bird 43 oxygen sensor and archived under BODC accession number BOD120217. Sample metadata (CTD cast, rosette bottle number and depth) were checked against information held in the database. Data were only provided for 36 stations, no data were received for CTD37. There was one discrepancy, CTD39 was provided with a depth of ~85 m but loaded with ~100 m but with according to the databsase.

The concentration data were provided in micromoles per litre and no unit conversions were applied.

The data were reformatted and loaded in BODC's samples database under Oracle Relational Database Management System. Data were marked up with BODC parameter codes and loaded into the database. Individual samples were matched through rosette sampling bottle number and depth.

A parameter mapping table is provided below;

Data Quality Report

In the originator's file 24 samples had additional comments indicating there were copepods or other zooplankton visible in the samples collected. These samples have been flagged to indicate the originator advises caution when interpreting these data points.

Problem Report

All of the Winkler concentrations from samples collected from CTD17, CTD19 and CTD21 were outliers in the sensor calibration. There did not appear to be a step change in the sensor over this period and after discussion with the originators' during the cruise the data were considered suspect and excluded from the Sea-Bird 43 oxygen sensor calibration dataset. These data have been flagged to indicate BODC advises caution when interpreting these data points.

Project Information

Oceans 2025 Theme 10, Sustained Observation Activity 1: The Atlantic Meridional Transect (AMT)

The Atlantic Meridional Transect has been operational since 1995 and through the Oceans 2025 programme secures funding for a further five cruises during the period 2007-2012. The AMT programme began in 1995 utilising the passage of the RRS James Clark Ross between the UK and the Falkland Islands southwards in September and northwards in April each year. Prior to Oceans 2025 the AMT programme has completed 18 cruises following this transect in the Atlantic Ocean. This sustained observing system aims to provide basin-scale understanding of the distribution of planktonic communities, their nutrient turnover and biogenic export in the context of hydrographic and biogeochemical provinces of the North and South Atlantic Oceans.

The Atlantic Meridional Transect Programme is an open ocean in situ observing system that will:

• give early warning of any fundamental change in Atlantic ecosystem functionng
• improve forecasts of the future ocean state and associated socio-economic impacts
• provide a "contextual" logistical and scientific infrastructure for independently-funded national and international open ocean biogeochemical and ecological research.

The specific objectives are:

• To collect hydrographic, chemical, ecological and optical data on transects between the UK and the Falkland Islands
• To quantify the nature and causes of ecological and biogeochemical variability in planktonic ecosystems
• To assess the effects of variability in planktonic ecosystems on biogenic export and on air-sea exchange of radiatively active gases

The measurements taken and experiments carried out on the AMT cruises will be closely linked to Themes 2 and 5. The planned cruise track also allows for the AMT data to be used in providing spatial context to the Sustained Observation Activities at the Porcupine Abyssal Plain Ocean Observatory (SO2) and the Western Channel Observatory (SO10).

More detailed information on this Work Package is available at pages 6 - 9 of the official Oceans 2025 Theme 10 document: Oceans 2025 Theme 10

Weblink: http://www.oceans2025.org/

Data Activity or Cruise Information

Data Activity

BODC Sample Metadata Report for JC079_CTD_CTD27

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Complete Cruise Metadata Report is available here

Fixed Station Information

No Fixed Station Information held for the Series

BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Appendix 1: JC079_CTD_CTD27

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.