Metadata Report for BODC Series Reference Number 2109481

• Metadata Summary

• Problem Reports

• Data Access Policy

• Narrative Documents

• Project Information

• Data Activity or Cruise Information

• Fixed Station Information

• BODC Quality Flags

• SeaDataNet Quality Flags

Metadata Summary

Problem Reports

No Problem Report Found in the Database

Data Access Policy

Public domain data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

The recommended acknowledgment is

"This study uses data from the data source/organisation/programme, provided by the British Oceanographic Data Centre and funded by the funding body."

Narrative Documents

Perkin Elmer 2400 Series II CHNSO Elemental Analyser

Basic Information

The PerkinElmer 2400 Series II CHNS/O Elemental Analyzer (2400 Series II) is an instrument for the determination of carbon, hydrogen, nitrogen, sulfur or oxygen content in organic and other types of materials. It has the capability of handling a wide variety of sample types.

The 2400 Series II CHNS/O Elemental Analyzer is capable of operating in three modes: CHN, CHNS and Oxygen, is fully automated, and includes a 60 position autosampler. The analyser has an accuracy of <=0.3% and a precision of <=02%. The analytical range is from 0.001 -3.6 mgs for C, 0.001-1.0 for H, 0.001-6 mgs for N and 0.001 to 2.0 mgs for S and O.

Instrument Specification

More information

More information can be found in the brochure.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

AMT22 (JC079) RRS James Cook, CTD bottle and surface underway sampled Particulate Inorganic Carbon (PIC), Partciulate Organic Carbon (POC), Particulate Organic Nitrogen (PON) and Biogenic Silica

Originator's Protocol for Data Acquisition and Analysis

Underway Sampling Protocol

The data originates from analyses on samples collected from CTD rosette bottle and underway samples collected from the ship's non-toxic supply during the cruise JC079 (AMT22). Discrete underway samples were collected from the ship's Surf-Met (underway surface and meteorological data collection) flow system in the CTD hanger lab 2 to 4 times per day (every 3-4 hours, spaced around stations). Samples for POC, PIC, PON, BSi, and coccolith enumeration were obtained along with chlorophyll samples taken for fluorometer calibration.

CTD Sampling Protocol

During the pre-dawn CTD, five light depths and three deeper depths down to 500 m were typically analyzed for POC, PON, PIC, BSi, and coccolith enumeration as described above. Typically, six light depths and two deeper depths down to 200m were also analyzed for PIC and BSi with only surface samples for POC and cell counts from the local noon CTD each day.

Analytical Protocol

PIC samples were collected on 0.4 µm polycarbonate filters, rinsed with potassium tetraborate buffer, dried and stored in metal-free centrifuge tubes. These were analysed by ICPOES for particulate calcium.

Biogenic silica (BSi) samples were filtered onto 0.4 µm polycarbonate filters and dried in clean centrifuge tubes, and will be analysed following the protocol of Brzezinski and Nelson (1989).

POC and PON samples were filtered onto pre-combusted (450°C for 5 hours) glass fiber filters. Filters were rinsed with filtered seawater (FSW) and then stored in individual petri-plates and dried (60°C) for storage. Prior to analysis, the plates were opened and placed overnight in a sealed container like a dessicator with saturated HCL fumes to remove any PIC. The filters were packed into pre-combusted nickel sleeves and analysed on a Perkin Elmer 2400 Series II CHNS/O for C, N, and H.

References Cited

Brzezinski, M.A., Nelson, D.M., 1989. Seasonal changes in the silicon cycle within a Gulf Stream warm-core ring. Deep-Sea Research 36, 1009-1030.

Instrumentation Description

Perkin Elmer 2400 Series II CHNS/O

BODC Data Processing Procedures

Data were received in a tab delimited text format and then loaded to the database using established BODC data banking procedures. Sample metadata (Date, time, latitude, longitude, sampling event ID and depth) for the CTD and underway samples were checked against information held in the database. Station and minor positional discrepancies between the originator's metadata and the metadata held centrally were observed. CTD corrections were applied after discussing these discrepancies with the originator. Parameter codes defined in the BODC parameter dictionary were assigned to the variables. The data for PIC and POC were converted from mg m^-3 to µmol L^-1, this was acheived by dividing by 12 (atomic mass of carbon). The same was done for PON though the conversion was made by dividing by 14 (atomic mass of Nitrogen) and the BSi data were provided in units (mmol m-3) which were consistent with the parameter used in the BODC database. Data were loaded to BODC's database with only these unit conversion applied. A table mapping these parameters is given below:

Data Quality Report

BODC were not advised of specific quality checks carried out by the data originators. There were no stand-out values in the sample data provided to the BODC.

Underway samples

One time discrepancy occurred with the originator's data for station DI. These data were loaded using the BODC time to match the existing entry when chlorophyll was taken from the underway non-toxic supply.

CTD bottle samples

There are no known concerns regarding CTD data.

Project Information

Oceans 2025 Theme 10, Sustained Observation Activity 1: The Atlantic Meridional Transect (AMT)

The Atlantic Meridional Transect has been operational since 1995 and through the Oceans 2025 programme secures funding for a further five cruises during the period 2007-2012. The AMT programme began in 1995 utilising the passage of the RRS James Clark Ross between the UK and the Falkland Islands southwards in September and northwards in April each year. Prior to Oceans 2025 the AMT programme has completed 18 cruises following this transect in the Atlantic Ocean. This sustained observing system aims to provide basin-scale understanding of the distribution of planktonic communities, their nutrient turnover and biogenic export in the context of hydrographic and biogeochemical provinces of the North and South Atlantic Oceans.

The Atlantic Meridional Transect Programme is an open ocean in situ observing system that will:

• give early warning of any fundamental change in Atlantic ecosystem functionng
• improve forecasts of the future ocean state and associated socio-economic impacts
• provide a "contextual" logistical and scientific infrastructure for independently-funded national and international open ocean biogeochemical and ecological research.

The specific objectives are:

• To collect hydrographic, chemical, ecological and optical data on transects between the UK and the Falkland Islands
• To quantify the nature and causes of ecological and biogeochemical variability in planktonic ecosystems
• To assess the effects of variability in planktonic ecosystems on biogenic export and on air-sea exchange of radiatively active gases

The measurements taken and experiments carried out on the AMT cruises will be closely linked to Themes 2 and 5. The planned cruise track also allows for the AMT data to be used in providing spatial context to the Sustained Observation Activities at the Porcupine Abyssal Plain Ocean Observatory (SO2) and the Western Channel Observatory (SO10).

More detailed information on this Work Package is available at pages 6 - 9 of the official Oceans 2025 Theme 10 document: Oceans 2025 Theme 10

Weblink: http://www.oceans2025.org/

Data Activity or Cruise Information

Data Activity

BODC Sample Metadata Report for JC079_CTD_CTD46

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Complete Cruise Metadata Report is available here

Fixed Station Information

No Fixed Station Information held for the Series

BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Appendix 1: JC079_CTD_CTD46

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.