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Metadata Report for BODC Series Reference Number 1362281


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Non-toxic sea water supply  continuous water samplers
Instrument Mounting research vessel
Originating Country United Kingdom
Originator Dr Reg Uncles
Originating Organization Plymouth Marine Laboratory
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) LOIS River-Atmosphere-Coast Study (RACS)
 

Data Identifiers

Originator's Identifier SV9A_GPUMP_NUTS_4:
BODC Series Reference 1362281
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 1994-05-18 11:30
End Time (yyyy-mm-dd hh:mm) 1994-05-18 16:58
Nominal Cycle Interval -
 

Spatial Co-ordinates

Southernmost Latitude 53.53609 N ( 53° 32.2' N )
Northernmost Latitude 53.64850 N ( 53° 38.9' N )
Westernmost Longitude 0.17250 W ( 0° 10.3' W )
Easternmost Longitude 0.12040 E ( 0° 7.2' E )
Positional Uncertainty Unspecified
Minimum Sensor or Sampling Depth 1.0 m
Maximum Sensor or Sampling Depth 1.0 m
Minimum Sensor or Sampling Height -
Maximum Sensor or Sampling Height -
Sea Floor Depth -
Sea Floor Depth Source -
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
AADYAA011DaysDate (time from 00:00 01/01/1760 to 00:00 UT on day)
AAFDZZ011DaysTime (time between 00:00 UT and timestamp)
ALATGP011DegreesLatitude north relative to WGS84 by unspecified GPS system
ALONGP011DegreesLongitude east relative to WGS84 by unspecified GPS system
NTRIAAD21Micromoles per litreConcentration of nitrite {NO2- CAS 14797-65-0} per unit volume of the water body [dissolved plus reactive particulate <0.4/0.45um phase] by filtration and colorimetric autoanalysis
NTRZAAD21Micromoles per litreConcentration of nitrate+nitrite {NO3+NO2} per unit volume of the water body [dissolved plus reactive particulate <0.4/0.45um phase] by filtration and colorimetric autoanalysis
SLCAAAD21Micromoles per litreConcentration of silicate {SiO44- CAS 17181-37-2} per unit volume of the water body [dissolved plus reactive particulate <0.4/0.45um phase] by filtration and colorimetric autoanalysis

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Non-toxic (underway) sea water supply

A source of uncontaminated near-surface (commonly 3 to 7 m) seawater pumped continuously to shipboard laboratories on research vessels. There is typically a temperature sensor near the intake (known as the hull temperature) to provide measurements that are as close as possible to the ambient water temperature. The flow from the supply is typically directed through continuously logged sensors such as a thermosalinograph and a fluorometer. Water samples are often collected from the non-toxic supply. The system is also referred to as the underway supply.

Nutrients for RV Sea Vigil, RV Water Guardian, RRS Challenger CH108A and Tweed campaign cruises.

Document History

Converted from CDROM documentation.

Content of data series

AMONAAD2 Dissolved ammonium
Colorimetric autoanalysis (0.4/0.45 µm pore filtered)
Micromoles/litre
AMONFID2 Dissolved ammonium
Flow-injection ammonium analyser (0.4/0.45 µm pore filtered)
Micromoles/litre
AMONMPD1 Dissolved ammonium
Manual analysis using the phenol and sodium nitrocyanoferrate method (GF/F filtered)
Micromoles/litre
NTRIAAD2 Dissolved nitrite
Colorimetric autoanalysis (0.4/0.45 µm pore filtered)
Micromoles/litre
NTRIAATX Nitrite (unfiltered)
Colorimetric autoanalysis (unfiltered)
Micromoles/litre
NTRZAAD1 Dissolved nitrate + nitrite
Colorimetric autoanalysis (GF/F filtered)
Micromoles/litre
NTRZAAD2 Dissolved nitrate + nitrite
Colorimetric autoanalysis (0.4/0.45 µm pore filtered)
Micromoles/litre
NTRZAATX Nitrate + nitrite (unfiltered)
Colorimetric autoanalysis (unfiltered)
Micromoles/litre
PHOSAAD2 Dissolved phosphate
Colorimetric autoanalysis (0.4/0.45 µm pore filtered)
Micromoles/litre
PHOSAATX Phosphate (unfiltered)
Colorimetric autoanalysis (unfiltered)
Micromoles/litre
PHOSMAD1 Dissolved phosphate
Manual colorimetric analysis (GF/F filtered)
Micromoles/litre
SDAMMPD1 Dissolved ammonium standard deviation
Manual analysis using the phenol and sodium nitrocyanoferrate method (GF/F filtered)
Micromoles/litre
SDPHMAD1 Dissolved phosphate standard deviation
Manual colorimetric analysis (GF/F filtered)
Micromoles/litre
SDURMDD1 Dissolved urea
Manual analysis using the diacetylmonoxime method (GF/F filtered)
Micromoles/litre
SLCAAAD1 Dissolved silicate
Colorimetric autoanalysis (GF/F filtered)
Micromoles/litre
SLCAAAD2 Dissolved silicate
Colorimetric autoanalysis (0.4/0.45 µm pore filtered)
Micromoles/litre
TPHSWCD1 Dissolved total phosphorus
Oxidation then colorimetric analysis (GF/F filtered)
Micromoles/litre
UREAMDD1 Dissolved urea
Manual analysis using the diacetylmonoxime method (GF/F filtered)
Micromoles/litre

Data Originator

Dr Reg Uncles, Plymouth Marine Laboratory, UK.

NB Users interested in nutrient data should be aware that there are continuous surface nutrient measurements for each RRS Challenger cruise included in the underway data set.

Sampling strategy and methodology

RV Sea Vigil cruises SV7B, SV7C, SV9A, SV9B, SV10A, SV10B, SV12A, SV12B, SV13A, SV13B, SV14B, SV14C, SV15A, SV15B, SV16, SV18A, SV18B, SV19A, SV19B, SV20B, SV21A, SV21B, SV22B, SV22C, SV23C, SV23D, SV24A, SV24B, SV25A, SV25B, SV26A, SV26B, SV27B, SV27D, SV28A, SV28B, SV29A, SV29B, SV30A, SV30B, SV31A, SV31B, SV34A, SV34B, SV35A, and SV35B.
RV Water Guardian cruises WG11B and WG11C.
Tweed campaigns TWEED01, TWEED02, TWEED03, TWEED04, TWEED05, TWEED06, TWEED07, TWEED08, TWEED09, TWEED10, TWEED11, TWEED12 and TWEED13.
RRS Challenger cruise CH108A

For the Challenger cruise data (a small number of sub-surface samples from CH108A) the water samples were drawn from the water bottles on the CTD rosette. The unfiltered samples were stored in a refrigerator until analysed (within 24 hours) as discrete samples on an Alpkem autoanalyser using established colorimetric techniques.

The autoanalyser was operated on the Sea Vigil cruises and Tweed campaigns in real time. Water from either the ship's moon pool or an overside pump was continuously flushed through a small reservoir via a continuous filter block (Morris et al., 1978) containing a 0.45 micron pore filter. The autoanalyser inlet line was kept in a reservoir of MilliQ water. On approaching a sampling station the line was switched to the filtered seawater reservoir. In this way internal blockages of the autoanalyser plumbing, caused by continuous exposure to nutrient-rich water, were avoided. Discrete sampling and manual filtering was used as a fallback strategy if operational difficulties were encountered with the autoanalyser. Samples were analysed as soon as the instrument was repaired.

The segmented-flow autoanalyser used was either a Technicon AAII or an Akpkem. In either case it was a four-channel instrument analysing various combinations of ammonium, nitrate plus nitrite, nitrite, phosphate and silicate. The chemistries used were as follows:

Nitrate: Reduced to nitrite by a Cu/Cd coil, then reacted with sulphanilamide in acidic conditions to form a diazo compound that coupled with N-1-naphylethylenediamide dihydrochloride to form a reddish-purple azo dye.
 
Nitrite: As for nitrate without the reduction step.
 
Phosphate: Reduction of a phosphomolybdate complex in acid solution to 'molybdenum blue' by ascorbic acid with sensitivity enhanced by the catalytic action of antimony potassium tartrate.
 
Silicate: The method used for silicate was based on the reduction of a silicomolybdate in acidic solution to 'molybdenum blue' by ascorbic acid. Oxalic acid was introduced into the sample stream before the addition of ascorbic acid to eliminate interference from phosphates.
 
Ammonium: Method of Mantoura and Woodward (1983).

On some Sea Vigil cruises ammonium was analysed by a flow injection technique. The method was based upon the conversion of the ammonium ion into gaseous ammonia across a hydrophobic membrane. It is fully described in Willason and Johnson (1986).

References

Balls, P.B. and Laslett, R., 1991. A simple estuarine water sampler suitable for trace metals and other constituents. Estuarine Coastal and Shelf Science 33, 623-629.

Mantoura, R.F.C. and Woodward, E.M.S., 1983. Optimisation of the indophenol blue method for the automated determination of ammonia in estuarine waters. Estuarine, Coastal and Shelf Science, 17, 219-224.

Morris, A.W., Howland, R.J.M. and Bale, A.J. (1978). A filtration unit for use with continuous autoanalytical systems applied to highly turbid waters. Est. Coast. Mar. Sci. 6, 105-109.

Ormaza-Gonzalez, F.I. and Statham, P.J., 1996. A comparison of methods for the determination of dissolved and particulate phosphorus in natural waters. Water Research, 30(1), 2739-2747.

Parsons, T.R., Maita, Y. and Lalli, C.M., 1984. A Manual of Chemical and Biological Methods for Seawater Analysis. Pergamon Press.

Willason S.W. and Johnson, K.S, 1986. A rapid, highly sensitive technique for the determination of ammonia in sea water. Mar. Biol. 91, 285-290.


Project Information

LOIS River-Atmosphere-Coast Study (LOIS - RACS)

Introduction

The Land-Ocean Interaction Study (LOIS) was a NERC research programme designed to study processes in the coastal zone. The Rivers, Atmosphere and Coasts Study (RACS) was a major component of LOIS that looked at land-sea interactions in the coastal zone and the major exchanges (physical, chemical and biological) between rivers and estuaries and the atmosphere. The study focused on the east coast of the UK from the Wash to the Tweed.

RACS included several sub-components

  • BIOTA - A study of salt marshes of the Humber and Wash
  • RACS (A) - An atmospheric chemistry study looking at air mass changes from the Wash into East Anglia
  • RACS (C) - A study of the estuaries, coasts and coastal waters between Great Yarmouth and Berwick upon Tweed.
    1. The coastal oceangraphic survey
    2. The Humber estuarine study
    3. The Tweed estuarine study
    4. The Holderness experiment
  • RACS (R) - A study of rivers that drain into the North Sea

RACS (A) was coordinated by the University of East Anglia and RACS (C) by the Plymouth Marine Laboratory.

RACS (A)

The bulk of the RACS (A) data set was collected during two field campaigns in the winter (October/November) of 1994 and the summer (May/June) of 1995. During these campaigns data were collected continuously from the University of East Anglia Atmospheric Observatory at Weybourne on the north Norfolk coast. An instrumented vessel was stationed offshore to provide a second sampling site to allow changes in a given air mass to be monitored. The Imperial College Jetstream research aircraft made one flight during each campaign to provide a link between the two surface stations. The Jetstream made four additional flights in 1996 and 1997.

RACS (C)

The coastal oceanographic survey

The coastal oceanographic data set was collected during a series of 17 RRS Challenger cruise legs. Most cruises covered two survey grids. One from Great Yarmouth to the Humber designed around the distribution of the sandbanks and a second simple zig-zag grid from the Humber to Berwick on Tweed. A large number of anchor stations, usually over one or two tidal cycles, were worked in the area of the Humber mouth or the Holderness coast.

The Humber estuarine study

The Humber estuarine data set was collected during a series of 33 campaigns on the Environment Agency vessels Sea Vigil and Water Guardian in the Humber, Trent and Ouse river systems at approximately monthly intervals between June 1993 and December 1996. Each campaign consisted of two or three one-day cruises. The tracks covered the estuary from the tidal limits of both Trent and Ouse to Spurn Point. Instrumental and sample data are available from a series of fixed stations that were sampled during every campaign.

The Tweed estuarine study

The Tweed estuarine data set was collected during a series of 13 campaigns using RV Tamaris in association with a rigid inflatable vessel at approximately monthly intervals between July 1996 and July 1997. Each campaign covered the tidal reaches of the River Tweed.

The Holderness experiment

The Holderness Experiment was designed to monitor the process of sediment transport along the Holderness coastline. It consisted of three moored instrument deployments during the winters of 1993-1994, 1994-1995 and 1995-1996. Mooring platforms were deployed at eight stations along two lines off the Holderness coast. A northerly and a southerly line of four stations each were used (N1 - N4 and S1 to S4) with the lowest numbers being inshore. Both lines were approximately perpendicular to the coast, although the S4 station lay to the south of the S line, off Spurn Head.


Data Activity or Cruise Information

Cruise

Cruise Name SV9A
Departure Date 1994-05-18
Arrival Date 1994-05-18
Principal Scientist(s)Duncan Plummer (Plymouth Marine Laboratory)
Ship RV Sea Vigil

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification