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Metadata Report for BODC Series Reference Number 1704737


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Dr Alex Poulton
Originating Organization Southampton Oceanography Centre (now National Oceanography Centre, Southampton)
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) Atlantic Meridional Transect Phase2(AMT)
 

Data Identifiers

Originator's Identifier AMT13_CTD_PIGX_215:A13_03
BODC Series Reference 1704737
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2003-09-14 10:22
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 47.97685 N ( 47° 58.6' N )
Longitude 11.53530 W ( 11° 32.1' W )
Positional Uncertainty Unspecified
Minimum Sensor or Sampling Depth 9.1 m
Maximum Sensor or Sampling Depth 51.4 m
Minimum Sensor or Sampling Height -
Maximum Sensor or Sampling Height -
Sea Floor Depth -
Sea Floor Depth Source -
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
ALLOHPP11Nanograms per litreConcentration of alloxanthin {CAS 28380-31-6} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
BBCAHPP11Nanograms per litreConcentration of beta,beta-carotene {beta-carotene CAS 7235-40-7} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
BUTAHPP11Nanograms per litreConcentration of 19'-butanoyloxyfucoxanthin {But-fuco(BF) CAS 111234-30-1} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CHLBHPP11Nanograms per litreConcentration of chlorophyll-b {chl-b CAS 519-62-0} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CLC2HPP11Nanograms per litreConcentration of chlorophyll-c2 {chl-c2} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CLC3HPP11Nanograms per litreConcentration of chlorophyll-c3 {chl-c3} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CPHLHPP11Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
DIADHPP11Nanograms per litreConcentration of diadinoxanthin {CAS 18457-54-0} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
DVCAHPP11Nanograms per litreConcentration of divinyl chlorophyll-a {DVchl-a} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
DVCBHPP11Nanograms per litreConcentration of divinyl chlorophyll-b {DVchl-b} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
FIRSEQID1DimensionlessBottle firing sequence number
FUCXHPP11Nanograms per litreConcentration of fucoxanthin {CAS 3351-86-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
HEXOHPP11Nanograms per litreConcentration of 19'-hexanoyloxyfucoxanthin {CAS 60147-85-5} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
PERIHPP11Nanograms per litreConcentration of peridinin {CAS 33281-81-1} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
VILXHPP11Nanograms per litreConcentration of violaxanthin {CAS 126-29-4} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
ZEOXHPP11Nanograms per litreConcentration of zeaxanthin {CAS 144-68-3} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

AMT13 pigment composition by HPLC analysis from CTD bottle samples

Data Acquisition and Analysis

Fresh seawater samples from upto five light depths were collected from 57 stations during the cruise. The main sampling was conducted on the pre-dawn cast each day with a reduced set of samples from the midday cast. All samples and replicates were stored at -80 °C and were returned to SOC in liquid-N for analysis.

HPLC analysis was carried out according to Barlow et al. (1997).

References Cited

Barlow R.G., Cummings D.G. and Gibb S.W., 1997. Improved resolution of mono- and divinyl chlorophylls a and b and zeaxanthin and lutein in phytoplankton extracts using reverse phase C8 HPLC. Marine Ecology Progress Series, 161 , 303-307.

Instrumentation Description

Section not relevant.

BODC Data Processing Procedures

Data were submitted to BODC in Microsoft Excel spreadsheet format and saved to the archive with reference SOC040134. The file was provided to BODC with CTD cast number, date, and bottle depth as metadata.

Sample metadata were checked against information held in the database - there was one minor depth discrepancy. Data were provided from a sample collected from 160m during cast 21, but no bottle was fired at this depth instead bottles were fired at 150m and the data were loaded against this depth.

Parameter codes defined in BODC parameter dictionary were assigned to the variables as shown in the table below. Values were multiplied by one thousand where appropriate for conversion into nanograms per litre. Cells where a value was logged as 'Present' were changed to 0 and the flag '<' was added to show values were below the detection level of the instrument. Column headings were substituted for the appropriate BODC parameter code except for Tpigm and Tchla, which were derived from the summation of all pigment values and ChlA and Dv ChlA values repectively. These derived values were not loaded into the database.

Data loaded into BODC's database without any changes.

Originator's Parameter Units Description BODC Parameter Code Units Comments
Chl c3 mg m-3 Concentration of chlorophyll-c3 {chl-c3} per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CLC3HPP1 ng l-1 Unit conversion x1000 applied
Chl c2 mg m-3 Concentration of chlorophyll-c2 {chl-c2} per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CLC2HPP1 ng l-1 Unit conversion x1000 applied
Peridinin mg m-3 Concentration of peridinin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) PERIHPP1 ng l-1 Unit conversion x1000 applied
19'But mg m-3 Concentration of 19'-butanoyloxyfucoxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) BUTAHPP1 ng l-1 Unit conversion x1000 applied
Fucox mg m-3 Concentration of fucoxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) FUCXHPP1 ng l-1 Unit conversion x1000 applied
19'Hex mg m-3 Concentration of 19'-hexanoyloxyfucoxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) HEXOHPP1 ng l-1 Unit conversion x1000 applied
Violax mg m-3 Concentration of violaxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) VILXHPP1 ng l-1 Unit conversion x1000 applied
Diadinox mg m-3 Concentration of diadinoxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) DIADHPP1 ng l-1 Unit conversion x1000 applied
Allox mg m-3 Concentration of alloxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) ALLOHPP1 ng l-1 Unit conversion x1000 applied
Zeax mg m-3 Concentration of zeaxanthin per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) ZEOXHPP1 ng l-1 Unit conversion x1000 applied
Dv ChlB mg m-3 Concentration of divinyl chlorophyll-b per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) DVCBHPP1 ng l-1 Unit conversion x1000 applied
Chl B mg m-3 Concentration of chlorophyll-b per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CHLBHPP1 ng l-1 Unit conversion x1000 applied
Dv ChlA mg m-3 Concentration of divinyl chlorophyll-a per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) DVCAHPP1 ng l-1 Unit conversion x1000 applied
ChlA mg m-3 Concentration of chlorophyll-a {chl-a} per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CPHLHPP1 mg m-3 n/a
B-Carot mg m-3 Concentration of beta-carotene {beta,beta-carotene} per unit volume of the water column [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) BCARHPP1 ng l-1 Unit conversion x1000 applied

Data Quality Report

The following values were reported as suspect by the originator and were flagged 'L' in the database: AMT13_30, 12m: Value for DV ChlA too low. AMT13_65, 52m: Value for DV ChlA too high.

Problem Report

This section is not relevant to this data set.


Project Information

The Atlantic Meridional Transect - Phase 2 (2002-2006)

Who was involved in the project?

The Atlantic Meridional Transect Phase 2 was designed by and implemented by a number of UK research centres and universities. The programme was hosted by Plymouth Marine Laboratory in collaboration with the National Oceanography Centre, Southampton. The universities involved were:

  • University of Liverpool
  • University of Newcastle
  • University of Plymouth
  • University of Southampton
  • University of East Anglia

What was the project about?

AMT began in 1995, with scientific aims to assess mesoscale to basin scale phytoplankton processes, the functional interpretation of bio-optical signatures and the seasonal, regional and latitudinal variations in mesozooplankton dynamics. In 2002, when the programme restarted, the scientific aims were broadened to address a suite of cross-disciplinary questions concerning ocean plankton ecology and biogeochemistry and the links to atmospheric processes.

The objectives included the determination of:

  • how the structure, functional properties and trophic status of the major planktonic ecosystems vary in space and time
  • how physical processes control the rates of nutrient supply to the planktonic ecosystem
  • how atmosphere-ocean exchange and photo-degradation influence the formation and fate of organic matter

The data were collected with the aim of being distributed for use in the development of models to describe the interactions between the global climate system and ocean biogeochemistry.

When was the project active?

The second phase of funding allowed the project to continue for the period 2002 to 2006 and consisted of six research cruises. The first phase of the AMT programme ran from 1995 to 2000.

Brief summary of the project fieldwork/data

The fieldwork on the first three cruises was carried out along transects from the UK to the Falkland Islands in September and from the Falkland Islands to the UK in April. The last three cruises followed a cruise track between the UK and South Africa, only deviating from the traditional transect in the southern hemisphere. During this phase the research cruises sampled further into the centre of the North and South Atlantic Ocean and also along the north-west coast of Africa where upwelled nutrient rich water is known to provide a significant source of climatically important gases.

Who funded the project?

Natural Environment Research Council (NERC)


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2003-09-14
End Date (yyyy-mm-dd) 2003-09-14
Organization Undertaking ActivityPlymouth Marine Laboratory
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierAMT13_CTD_A13_03
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for AMT13_CTD_A13_03

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
508487 20.0 1 24       3.10       3.60       2.10 Niskin bottle No problem reported    
508535 20.0 23 1   305.90   307.30   302.60 Niskin bottle No problem reported    
508536 20.0 24 2   305.50   306.30   301.90 Niskin bottle No problem reported    
508537 20.0 22 3   254.80   255.10   251.40 Niskin bottle No problem reported    
508538 20.0 20 5   154.40   154.90   152.10 Niskin bottle No problem reported    
508539 20.0 19 6   123.10   123.60   121.00 Niskin bottle No problem reported    
508540 20.0 18 7   103.00   104.10   101.40 Niskin bottle No problem reported    
508541 20.0 16 9     62.20     64.10     61.40 Niskin bottle No problem reported    
508542 20.0 12 10     52.90     53.20     51.40 Niskin bottle No problem reported    
508543 20.0 13 11     53.00     54.30     52.00 Niskin bottle No problem reported    
508544 20.0 15 13     53.50     53.80     52.00 Niskin bottle No problem reported    
508545 20.0 11 14     46.60     47.70     45.50 Niskin bottle No problem reported    
508546 20.0 10 15     42.80     44.10     41.80 Niskin bottle No problem reported    
508547 20.0 8 17     32.30     35.10     32.20 Niskin bottle No problem reported    
508548 20.0 7 18     26.90     26.90     25.40 Niskin bottle No problem reported   minp set to maxp as recorded as -4144
508549 20.0 6 19     22.40     23.70     21.60 Niskin bottle No problem reported    
508550 20.0 4 21     15.50     17.00     14.90 Niskin bottle No problem reported    
508551 20.0 3 22     13.80     14.20     12.60 Niskin bottle No problem reported    
508552 20.0 2 23     10.20     10.70       9.10 Niskin bottle No problem reported    
510107 20.0 21 4   202.50   203.00   199.70 Niskin bottle No problem reported    
510108 20.0 17 8     76.90     79.40     76.20 Niskin bottle No problem reported    
510109 20.0 14 12     52.80     54.10     51.80 Niskin bottle No problem reported    
510110 20.0 9 16     37.10     38.90     36.40 Niskin bottle No problem reported    
510111 20.0 5 20     17.10     18.70     16.50 Niskin bottle No problem reported    

Please note: the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name JR20030910 (AMT13, JR91)
Departure Date 2003-09-10
Arrival Date 2003-10-14
Principal Scientist(s)Carol Robinson (Plymouth Marine Laboratory)
Ship RRS James Clark Ross

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: AMT13_CTD_A13_03

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
1131138Water sample data2003-09-14 10:22:0047.97685 N, 11.5353 WRRS James Clark Ross JR20030910 (AMT13, JR91)