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Metadata Report for BODC Series Reference Number 1979060


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Metrohm 916 Ti Touch compact potentiometric titrator  titrators
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Dr Yvonne Firing
Originating Organization National Oceanography Centre, Southampton
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) ORCHESTRA
 

Data Identifiers

Originator's Identifier JR17001_CTD_DOXY_4914:3
BODC Series Reference 1979060
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2017-11-24 11:27
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 62.20587 S ( 62° 12.4' S )
Longitude 58.73985 W ( 58° 44.4' W )
Positional Uncertainty 0.0 to 0.01 n.miles
Minimum Sensor or Sampling Depth 4.8 m
Maximum Sensor or Sampling Depth 113.2 m
Minimum Sensor or Sampling Height 74.8 m
Maximum Sensor or Sampling Height 183.2 m
Sea Floor Depth 188.0 m
Sea Floor Depth Source BRIDGE
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Approximate - Depth is only approximate
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
DOKGWITX1Micromoles per kilogramConcentration of oxygen {O2 CAS 7782-44-7} per unit mass of the water body [dissolved plus reactive particulate phase] by Winkler titration
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Metrohm 916 Ti-Touch compact potentiometric titrator

The Metrohm 916 Ti-Touch is a stand-alone potentiometric titrator for dynamic (DET), monotonic (MET), set endpoint (SET) and manual titrations (MAT). The instrument consists of an intergrated buret, rod stirrer (or magnetic stirrer) and dosing system with a live touch control display.

Specifications

Dosing element with intelligent exchange unit 2 x 800 Dosino or 2 x 805 Dosimat
Dosing steps per cylinder content 800 Dosino: 10,000 pulses; 805 Dosimat: 20,000 pulses
Stirrers/Titration stands

Included - 802 rod stirrer

Additional - 1 x 801 magnetic stirrer or 1 x 802 rod stirrer or 1 x 803 KF titration stand

Attachments 2 MSB connectors, 1 sample changer (814, 815) via USB
Temperature sensor Pt1000 or NTC

More information can be found in the manufacturer's product description.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

RRS James Clark Ross JR17001 Discrete CTD Salinity, Temperature and Oxygen Samples

Originator's Protocol for Data Acquisition and Analysis

Salinity samples were taken in 200 ml glass bottle samples, rinsed three times before filling and sealed with clean dry stoppers. Crates of samples were stored in the bio Lab for a minimum of 12 hours before analysis to allow equilibration to laboratory temperature (approximately 22°C). The samples were analysed for conductivity using a Guildline 8400B Salinometer with a cell temperature of 24°C. procedures followed the standards adopted in the GO-SHIP manual and cruise reports for cruises JR306, JR15003 and JR16002. Bottle conductivity ratios readings were logged both by hand and using the OSIL Salinometer Data Logger software. IAPSO standard seawater bottles run before and after each crate of samples were used to compute a linearly drifting offset by reference to the nominal conductivity ratio of the standard.

Dissolved oxygen sampling and analysis followed the GO_SHIP manual procedures for amperometric determination of dissolved oxygen in seawater by Winkler titration.

Temperature readings from the SBE35 independent sensor were made at bottle firing dpeths.

BODC Data Processing Procedures

Data received were loaded into the BODC database using established BODC data banking procedures. Quality flags were sent alonside the data. All flags were mapped to BODC system according to the table:

Originator's flag BODC flag
2- No problems noted No flag
3- Leaking L- Improbable value - originator's quality control
9- Samples not drawn from this bottle. N- Null value

The originator variables were mapped to appropriate BODC parameter codes as follows:

Originator's Variable Units BODC Parameter Code Units
OXYGEN umol kg-1 DOKGWITX umol kg-1
SALNTY pss-78 PSALST01  
SBE35 its-90 TEMPSB35 °C

The originator's file is available upon request.


Project Information

Ocean Regulation of Climate by Heat and Carbon Sequestration and Transports (ORCHESTRA)

The Ocean Regulation of Climate by Heat and Carbon Sequestration and Transports (ORCHESTRA) is a £8.4 million, five year (2016-2021) research programme funded by the Natural Environment Research Council (NERC). The aim of the research is to to advance the understanding of, and capability to predict, the Southern Ocean's impact on climate change via its uptake and storage of heat and carbon. The programme will significantly reduce uncertainties concerning how this uptake and storage by the ocean influences global climate, by conducting a series of unique fieldwork campaigns and innovative model developments.

Background

ORCHESTRA represents the first fully-unified activity by NERC institutes to address these challenges, and will draw in national and international partners to provide community coherence, and to build a legacy in knowledge and capability that will transcend the timescale of the programme itself.

It brings together science teams from six UK research institutions to investigate the role that the Southern Ocean plays in our changing climate and atmospheric carbon draw-down. It is led by British Antarctic Survey, in partnership with National Oceanography Centre, British Geological Survey, Plymouth Marine Laboratory, the Centre for Polar Observation and Modelling and the Sea Mammal Research Unit.

The oceans around Antarctica play a critical a key role in drawing down and storing large amounts of carbon and vast quantities of heat from from the atmosphere. Due to its remoteness and harsh environment, the Southern Ocean is the world's biggest data desert, and one of the hardest places to get right in climate models. The ORCHESTRA programme will make unique and important new measurements in the Southern Ocean using a range of techniques, including use of the world-class UK research vessel fleet, and deployments of innovative underwater robots. The new understanding obtained will guide key improvements to the current generation of computer models, and will enhance greatly our ability to predict climate into the future.

The scope of the programme includes interaction of the Southern Ocean with the atmosphere, exchange between the upper ocean mixed layer and the interior and exchange between the Southern Ocean and the global ocean.

Further details are available on the ORCHESTRA page.

Participants

Six different organisations are directly involved in research for ORCHESTRA. These institutions are:

  • British Antarctic Survey (BAS)
  • National Oceanography Centre (NOC)
  • Plymouth Marine Laboratory (PML)
  • British Geological Survey (BGS)
  • Centre for Polar Observation and Modelling (CPOM)
  • Sea Mammal Research Unit (SMRU)

GO-SHIP are a third party organisation that, although not directly involved with the programme, will conduct ship based observations that will also be used by ORCHESTRA.

Research details

Three Work Packages have been funded by the ORCHESTRA programme. These are described in brief below:

  • Work Package 1: Interaction of the Southern ocean with the atmosphere
    WP1 will use new observations of surface fluxes and their controlling parameters in order to better constrain the exchanges of heat and carbon loss across the surface of the Southern Ocean.

  • Work Package 2: Exchange between the upper ocean mixed layer and the interior.
    This work package will combine observationally-derived data and model simulations to determine and understand the exchanges between the ocean mixed layer and its interior.

  • Work Package 3: Exchange between the Southern Ocean and the global ocean .
    This WP will use budget analyses of the hydrographic/tracer sections to diagnose the three-dimensional velocity field of the waters entering, leaving and recirculating within the Southern Atlantic sector of the Southern ocean.

  • Fieldwork and data collection

    The campaign consists of 12 core cruises on board the NERC research vessels RRS James Clark Ross and RRS James Cook and will include hydrographic/tracer sections conducted across Drake Passage (SR1b), the northern Weddell Sea/Scotia Sea (A23), the northern rim of the Weddell Gyre (ANDREXII) and across the South Atlantic (24S). Section I6S will be performed by GO-SHIP Project Partners. Measurements will include temperature, salinity, dissolved oxygen, velocity, dissolved inorganic carbon, total alkalinity, inorganic nutrients, oxygen and carbon isotopes, and underway meteorological and surface ocean observations including pCO2.

    Tags will be deployed on 30 Weddel seals and these will provide temperature and salinity profiles that can be used alongside the Argo data.

    Autonomous underwater ocean gliders will conduct multi-month missions and will deliver data on ocean stratification, heat content, mixed layer depth and turbulent mixing over the upper 1 km, with previously-unobtainable temporal resolution. These gliders will be deployed in the Weddell Gyre and the ACC.

    Field campaigns with the MASIN meteorological aircrafts will be conducted flying out of Rothera and Halley research stations and the Falkland Islands. These campaigns will deliver information on key variables relating to air-sea fluxes (surface and air temperature, wind, humidity, atmospheric CO2, radiation, turbulent fluxes of heat, momentum and CO2), in different sea ice conditions and oceanic regimes.

    Eart Observation datasets will be used to inform the programme on the properties of the ocean, sea ice and atmosphere and on interactions between them.

    A cluster of 6 deep ocean moorings in the Orkney Passage will collect year round series of AABW temperatre and transport. This work connects to the NERC funded project Dynamics of the Orkney Passage Outflow (DYNOPO).

    The UK Earth System model (UKESM) and underlying physical model will be used to conduct analyses of heat and carbon uptake and transport by the Southern Ocean and their links to wider climate on decadal timescales.

    An eddy-resolving (1/12°) sector model of the ocean south of 30°S with 75 vertical levels, will be built using the NEMO model coupled to the Los Alamos sea ice (CICE) model. The improvements on the ocean boundary layer will be based from the results from the NERC-funded OSMOSIS project and the inclusion of tides.

    20-5 year runs of an adjoint model will be conducted to determine how key forcings and model states affect the uptake and subduction of heat and carbon by the ocean.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2017-11-24
End Date (yyyy-mm-dd) 2017-11-24
Organization Undertaking ActivityBritish Antarctic Survey
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierJR17001_CTD_3
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for JR17001_CTD_3

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
1295594   20.00 1    113.80  114.80  113.20 Niskin bottle No problem reported    
1295597   20.00 2    110.30  111.30  109.70 Niskin bottle Vent left open    
1295600   20.00 3    102.10  103.10  101.60 Niskin bottle No problem reported    
1295603   20.00 4     96.00   97.00   95.60 Niskin bottle No problem reported    
1295606   20.00 5     86.90   87.90   86.50 Niskin bottle No problem reported    
1295609   20.00 6     72.00   73.00   71.80 Niskin bottle No problem reported    
1295612   20.00 7     61.80   62.80   61.70 Niskin bottle No problem reported    
1295615   20.00 8     46.90   47.90   46.90 Niskin bottle No problem reported    
1295618   20.00 9     36.60   37.60   36.70 Niskin bottle No problem reported    
1295621   20.00 10     26.80   27.80   27.00 Niskin bottle No problem reported    
1295624   20.00 11     16.40   17.40   16.70 Niskin bottle No problem reported    
1295627   20.00 12     11.50   12.50   11.90 Niskin bottle No problem reported    
1295630   20.00 13      4.30    5.30    4.80 Niskin bottle Vent left open    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Cruise

Cruise Name JR17001 (ORCHESTRA)
Departure Date 2017-11-21
Arrival Date 2017-12-21
Principal Scientist(s)David Barnes (British Antarctic Survey), J Alexander Brearley (British Antarctic Survey), Yvonne L Firing (National Oceanography Centre, Southampton)
Ship RRS James Clark Ross

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification