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Metadata Report for BODC Series Reference Number 1982079


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Turner Designs Trilogy fluorometer  bench fluorometers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Ms Charlotte Smith
Originating Organization University of Liverpool Department of Earth, Ocean and Ecological Sciences
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) RidgeMix
 

Data Identifiers

Originator's Identifier JR15007_CTD_PIGX_4925:CTD_058
BODC Series Reference 1982079
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2016-06-24 23:01
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 36.24755 N ( 36° 14.9' N )
Longitude 40.67538 W ( 40° 40.5' W )
Positional Uncertainty 0.01 to 0.05 n.miles
Minimum Sensor or Sampling Depth 10.0 m
Maximum Sensor or Sampling Depth 300.0 m
Minimum Sensor or Sampling Height 4081.9 m
Maximum Sensor or Sampling Height 4371.9 m
Sea Floor Depth 4381.9 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
FIRSEQID1DimensionlessBottle firing sequence number
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
SCHLFLPF1Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate 0.2-2um phase] by filtration, acetone extraction and fluorometry
SCHLFLPG1Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate 2-20um phase] by filtration, acetone extraction and fluorometry
SCHLFLPQ1Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate >20um phase] by filtration, acetone extraction and fluorometry

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Turner Designs Trilogy Fluorometer

The Trilogy Laboratory Fluorometer is a compact laboratory instrument for making fluorescence, absorbance and turbidity measurements using the appropriate snap-in Application Module.

The following snap-in application modules are available:

Application Minimum Detection Limit Linear Range Comments
Ammonium 0.05µmol 0-50µmol  
CDOM/FDOM 0.1 ppb 0 - 1000 ppb Quinine sulphate
Chlorophyll-a extracted (acidification) 0.025 µg l-1 0-300 µg l-1  
Chlorophyll-a extracted (non-acidification) 0.025 µg l-1 0-300 µg l-1  
Chlorophyll in vivo 0.025 µg l-1 0-300 µg l-1  
Fluorescein dye standard range 0.01 ppb 0-200 ppb  
Fluorescein dye extended range 0.75 ppb 0-8000 ppb Minicell adapter P/N 8000-936 and P/N 7000-950 required
Histamine 0.001 ppm 0-100 ppm  
Histamine (PTSA) 0.5 ppm 0-2,000 ppm  
Nitrate (absorbance) 0.04 mg l-1 0 - 14 mg l-1  
Crude Oil 0.2 ppb 0 - 2,000 ppb Quinine sulphate
Refined Oil 0.25 ppb 0 - 6,000 ppb Napthalene 1,5 Naphthalene disulfonic disodium salt
Optical Brighteners 1 ppb 0 - 10,000 ppb Quinine sulphate
Phosphate (absorbance) 1 µg l-1 0 - 930 µg l-1  
Phycocyanin (freshwater) 150 cells ml-1 0 - 150,000 cells ml-1  
Phycoerythrin (marine) 150 cells ml-1 0 - 150,000 cells ml-1  
Pyrene tetra sulfonic acid (PTSA) 0.1 ppb >10,000 ppb  
Rhodamine WT 0.01 ppb 0 - 500 ppb  
Silicate (absorbance) 3 µg l-1 0 - 3000 µg l-1  
Turbidity 0.05 NTU 0 - 1000 NTU  

For extracted chlorophyll measurements using EPA 445, Trilogy automatically calculates the concentration using the filtered and solvent volumes. The turbidity modules use an IRLED with a wavelength of 860nm to meet ISO 7027 standards for turbidity water quality measurements.

Specifications

Power 100 to 240VAC Universal Power Supply, Output 12VDC 0.84A Max
Operating Temperature 15-40 °C
Size 32.82 cm depth, 26.52 cm width, 21.39 height
Weight 3.65 kg
Readout Direct concentration (µg l-1, ppb etc.)
Light source and detector Light emitting diode and photodiode
Data output 100% ASCII format through a 9-pin RS-232 serial cable at 9600 baud
PC operating system Windows 98 or later

Further details can be found in the manufacturer's specification sheet.

Size fractionated chlorophyll-a concentrations from CTD bottle samples on RidgeMix cruise JR15007

Originator's Protocol for Data Acquisition and Analysis

Seawater samples were taken from 20 L Niskin bottles on a rosette sampler throughout the RidgeMix cruise JR15007.

8 to 14 samples were analysed for chlorophyll concentration to characterise the shape of the deep chlorophyll maximum. The deepest sample was at 300 m. Seawater samples for size-fractionated chlorophyll-a were collected by transferring 1L of seawater from the Niskin bottle into 1 L brown bottles, which were triple rinsed with milli-Q and seawater. Analysis was performed on-board by filtering between 0.25 and 1L through sequential filters of pore size 20 µm, 2 µm and 0.2 µm (45 mm polycarbonate filters) in a size-fractionated chlorophyll 'rig'. After filtration samples were folded and transferred into labelled glass tubes with screw-cap lids. 5 ml of 90% acetone was added in the fume cupboard and samples were stored at 4°C in the fridge for 24 hours. Sample raw fluorescence (RFU) was measured using a Turner Trilogy Fluorometer and chlorophyll-a concentrations calculated by calibrating fluorescence with chlorophyll-a standards of known concentration. Prior to sample fluorescence measurement, three blanks and two solid standards were measured to confirm instrument stability. The fluorometer cuvette was triple acetone rinsed between samples.

Instrumentation Description

Turner Designs Trilogy fluorometer

BODC Data Processing Procedures

Data were submitted by email to BODC as an Excel spreadsheet containing size fractionated chlorophyll-a concentrations along with the cruise number, CTD number, latitude, longitude, and depth. A pdf copy of the PhD thesis this data was collected for, which detailed the sampling protocol and analytical methods, was submitted alongside the data. The data and metadata were archived following standard BODC procedure.

The data were reformatted and assigned BODC parameter codes which were in equivalent units to the data and so no unit conversions were necessary. During reformatting, replicate measurements were averaged and standard deviation was calculated. Data were then loaded into BODC's samples database under Oracle Relational Database Management System using established data banking procedures.

The originator's parameters were mapped to BODC parameter codes as follows:

Originator's Parameter Unit BODC Parameter Code BODC Unit Comments
>20um mg m-3 SCHLFLPQ mg m-3 -
2-20um mg m-3 SCHLFLPG mg m-3 -
0.2-2 um mg m-3 SCHLFLPF mg m-3 -
- - SCHDSDPQ mg m-3 Calculated by BODC
- - SCHDSDPG mg m-3 Calculated by BODC
- - SCHDSDPS mg m-3 Calculated by BODC

Data Quality Report

The originator did not provide any quality control comments and during BODC processing it was not deemed that any values required flagging.


Project Information

A nutrient and carbon pump over mid-ocean ridges (RidgeMix)

RidgeMix is a five year (August 2014 to February 2019) research programme which received funding from the Natural Environment Research Council (NERC). The aim of the programme was to address the problem of how deep nutrients are transported into the surface waters in mid-latitudes, by testing a new view: tides passing over the mid-Atlantic ridge generate enhanced turbulence and mixing, which in turn provides a nutrient supply to the upper thermocline waters. These nutrients are then transported horizontally along density surfaces over the western side of the basin, probably being swept along the Gulf Stream and eventually passing into the winter mixed surface layer. When this surface layer shallows and warms in spring, the nutrients are then available to the phytoplankton.

Fieldwork involved collecting measurements of the turbulence and nutrient concentrations over and adjacent to the Mid-Atlantic Ridge, using a novel long-term moored array of instruments along the ridge, deployed over a five-week research cruise. Sampling was done sufficiently quickly to resolve tidal changes in currents and mixing over the ridge. A second component of the fieldwork will use computer models of circulation in the Atlantic to explore the wider implications of the fieldwork observations, to determine whether or not mixing over the mid-Atlantic ridge really does provide enough nutrients to explain the phytoplankton production in the mid-latitude North Atlantic.

RidgeMix was a collaborative project involving five organisations, of which three were UK based and two were US based. The project was led by the Professor Jonathan Sharples, University of Liverpool, Earth, Ocean and Ecological Sciences. Collaborators were:

  • National Oceanography Centre, Science and Technology (UK)
  • University of Southampton, School of Earth and Ocean Science (UK)
  • Woods Hole Oceanographic Institute (US)
  • Monterey Bay Aquarium Research Institute (US)

  • Data Activity or Cruise Information

    Data Activity

    Start Date (yyyy-mm-dd) 2016-06-24
    End Date (yyyy-mm-dd) Ongoing
    Organization Undertaking ActivityNational Oceanography Centre, Liverpool
    Country of OrganizationUnited Kingdom
    Originator's Data Activity IdentifierJR15007_CTD_CTD_058
    Platform Categorylowered unmanned submersible

    BODC Sample Metadata Report for JR15007_CTD_CTD_058

    Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
    1347476   20.00 1 1     4400.00 Niskin bottle No problem reported    
    1347479   20.00 2 2     4000.00 Niskin bottle No problem reported    
    1347482   20.00 3 3     3500.00 Niskin bottle No problem reported    
    1347485   20.00 4 4     3000.00 Niskin bottle No problem reported    
    1347488   20.00 5 5     2500.00 Niskin bottle No problem reported    
    1347491   20.00 6 6     2000.00 Niskin bottle No problem reported    
    1347494   20.00 7 7     1750.00 Niskin bottle No problem reported    
    1347497   20.00 8 8     1500.00 Niskin bottle No problem reported    
    1347500   20.00 9 9     1250.00 Niskin bottle No problem reported    
    1347503   20.00 10 10     1000.00 Niskin bottle No problem reported    
    1347506   20.00 11 11      900.00 Niskin bottle No problem reported    
    1347509   20.00 12 12      800.00 Niskin bottle No problem reported    
    1347512   20.00 13 13      700.00 Niskin bottle No problem reported    
    1347515   20.00 14 14      600.00 Niskin bottle No problem reported    
    1347518   20.00 15 15      500.00 Niskin bottle No problem reported    
    1347521   20.00 16 16      400.00 Niskin bottle No problem reported    
    1347524   20.00 17 17      300.00 Niskin bottle No problem reported    
    1347527   20.00 18 18      200.00 Niskin bottle No problem reported    
    1347530   20.00 19 19      150.00 Niskin bottle No problem reported    
    1347533   20.00 20 20       87.00 Niskin bottle No problem reported    
    1347536   20.00 21 21       75.00 Niskin bottle No problem reported    
    1347539   20.00 22 22       70.00 Niskin bottle No problem reported    
    1347542   20.00 23 23       50.00 Niskin bottle No problem reported    
    1347545   20.00 24 24       10.00 Niskin bottle No problem reported    

    Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

    Related Data Activity activities are detailed in Appendix 1

    Cruise

    Cruise Name JR15007
    Departure Date 2016-05-25
    Arrival Date 2016-07-10
    Principal Scientist(s)Jonathan Sharples (National Oceanography Centre, Liverpool)
    Ship RRS James Clark Ross

    Complete Cruise Metadata Report is available here


    Fixed Station Information


    No Fixed Station Information held for the Series


    BODC Quality Control Flags

    The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

    Flag Description
    Blank Unqualified
    < Below detection limit
    > In excess of quoted value
    A Taxonomic flag for affinis (aff.)
    B Beginning of CTD Down/Up Cast
    C Taxonomic flag for confer (cf.)
    D Thermometric depth
    E End of CTD Down/Up Cast
    G Non-taxonomic biological characteristic uncertainty
    H Extrapolated value
    I Taxonomic flag for single species (sp.)
    K Improbable value - unknown quality control source
    L Improbable value - originator's quality control
    M Improbable value - BODC quality control
    N Null value
    O Improbable value - user quality control
    P Trace/calm
    Q Indeterminate
    R Replacement value
    S Estimated value
    T Interpolated value
    U Uncalibrated
    W Control value
    X Excessive difference

    SeaDataNet Quality Control Flags

    The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

    Flag Description
    0 no quality control
    1 good value
    2 probably good value
    3 probably bad value
    4 bad value
    5 changed value
    6 value below detection
    7 value in excess
    8 interpolated value
    9 missing value
    A value phenomenon uncertain
    B nominal value
    Q value below limit of quantification

    Appendix 1: JR15007_CTD_CTD_058

    Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

    If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

    Series IdentifierData CategoryStart date/timeStart positionCruise
    2049445Water sample data2016-06-24 23:00:5336.24755 N, 40.67538 WRRS James Clark Ross JR15007
    2138400Water sample data2016-06-24 23:00:5336.24755 N, 40.67538 WRRS James Clark Ross JR15007
    1987914Water sample data2016-06-24 23:01:0036.24755 N, 40.67538 WRRS James Clark Ross JR15007