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Metadata Report for BODC Series Reference Number 1985053


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Clean pumped sea water supply  continuous water samplers
unknown  unknown
Instrument Mounting research vessel
Originating Country United Kingdom
Originator Dr Micha Rijkenberg
Originating Organization National Oceanography Centre, Southampton
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) UKSOLAS
 

Data Identifiers

Originator's Identifier D326_CPUMP_TMXX_522:
BODC Series Reference 1985053
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2008-01-12 09:00
End Time (yyyy-mm-dd hh:mm) 2008-02-01 01:12
Nominal Cycle Interval -
 

Spatial Co-ordinates

Southernmost Latitude 12.51131 N ( 12° 30.7' N )
Northernmost Latitude 25.88804 N ( 25° 53.3' N )
Westernmost Longitude 35.35635 W ( 35° 21.4' W )
Easternmost Longitude 24.30744 W ( 24° 18.4' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 3.0 m
Maximum Sensor or Sampling Depth 3.0 m
Minimum Sensor or Sampling Height -
Maximum Sensor or Sampling Height -
Sea Floor Depth -
Sea Floor Depth Source -
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
AADYAA011DaysDate (time from 00:00 01/01/1760 to 00:00 UT on day)
AAFDZZ011DaysTime (time between 00:00 UT and timestamp)
ALATGP011DegreesLatitude north relative to WGS84 by unspecified GPS system
ALONGP011DegreesLongitude east relative to WGS84 by unspecified GPS system
DFEFICHL1Nanomoles per litreConcentration of total iron {total_Fe CAS 7439-89-6} per unit volume of the water body [dissolved plus reactive particulate <0.2um phase] by filtration and flow-injection chemiluminescence
DFEFICSD1Nanomoles per litreConcentration standard deviation of total iron {total_Fe CAS 7439-89-6} per unit volume of the water body [dissolved plus reactive particulate <0.2um phase] by filtration and flow-injection chemiluminescence

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Clean pumped sea water supply

The system comprises a precision echosounder (PES) fish attached to a clean, reinforced tube (typically composed of braided polyvinyl chloride (PVC)). The fish is designed to be towed alongside a moving ship at a depth of one to three metres and water is drawn through the system by a clean pump. The tube usually leads to a clean laboratory on board the vessel, inside which samples are drawn for analysis. The system is typically used for continuous, underway, clean sampling (e.g., trace metal studies) of near surface waters.

Dissolved iron concentrations in seawater for UK SOLAS Cruise D326

Originator's Protocol for Data Acquisition and Analysis

Samples for dissolved iron profiles were drawn from trace metal clean CTD casts. Underway samples were taken from 3 m depth, alongside the ship, using a trace metal clean fish. Sea water was filtered through a Sartobran 300 filter capsule with a 0.2 µm cut-off. Polyethylene sample bottles were washed using the protocol detailed by Achterberg et al, 2001. Samples were acidified to pH 2 (final concentration 0.011 M) using ultra clean HCL.

Dissolved iron was measured using an automated flow injection analysis and luminol based chemiluminescence detection. Dissolved Fe(II + III) was determined after reduction of all Fe(III) to Fe(II) by sulfite, and subsequent matrix elimination and preconcentration on an 8-hydroxyquinoline chelating resign column. A 0.02 M Fe(II) stock solution (prepared monthly) was used during the cruise, and other standards prepared daily by serial dilution.

For full details please see Rijkenberg et al., 2008.

References Cited

Achterberg E.A., Holland T.W., Bowie A.R., Mantoura R.F.C., Worsfold P.J., 2001. Determination of iron in seawater. Analytical Chimica Acta, 442, 1-14.

Rijkenberg M.J.A., Powell C.F., Dall'Osto M., Nielsdottir M.C., Patey M.D., Hill P.G., Baker A.R., Jickells T.D., Harrison R.M., Achterberg E.P., 2008. Changes in iron speciation following a Saharan dust event in the tropical North Atlantic Ocean. Marine Chemistry, 110, 56-67.

BODC Data Processing Procedures

Data from trace metal clean CTD casts were submitted to BODC in a spreadsheet format file (Compendium_CTDstations_D326_230109.xls) containing dissolved iron and assoicated standard deviation, other measured parameters from multiple originators, and the following metadata fields: cast number, date, julian day, CTD bottle number, time, latitude and longitude.

Data from the trace metal clean towed fish were received by BODC in a spreadsheet format file (Complexation_data_for_BODC_121009.xls) containing dissolved iron and associated standard deviation, Fe ligand data and the following metadata fields: sample I.D., julian day, date, time, latitude and longitude.

Parameter codes defined in the BODC parameter dictionary were mapped to the variables as follows:

Originator's Parameter Unit Description BODC Parameter Code BODC Unit Comments
[DFe] nM nM Dissolved iron concentration (<0.2 µm) DFEFICHL nmol l-1 n/a
stdev nM Dissolved iron concentration (<0.2 µm) standard deviation DFEFICSD nmol l-1 n/a

Data Quality Report

No data quality issues to report.


Project Information

UK Surface Ocean Lower Atmosphere Study

The UK Surface Ocean Lower Atmosphere Study (UK SOLAS) is the UK's contribution to the international SOLAS programme.

UK SOLAS formed interdisciplinary teams to address three primary aims

  • To determine the mechanisms controlling rates of chemical transfer and improve estimates of chemical exchanges
  • To evaluate the impact of these exchanges on the biogeochemistry of the surface ocean and lower atmosphere and on feedbacks between the ocean and atmosphere
  • To quantify the impacts of these boundary layer processes on the global climate system

UK SOLAS started in 2003, to run for seven years. The programme was funded by the Natural Environment Research Council.

Funded projects

In total, 19 projects have been funded by UK SOLAS, over four funding rounds.

Project Title Short Title Principal Investigator
Impact of atmospheric dust derived material and nutrient inputs on near-surface plankton microbiota in the tropical North Atlantic Dust Eric Achterberg
The role and effects of photoprotective compounds in marine plankton - Steve Archer
Field observations of sea spray, gas fluxes and whitecaps SEASAW Ian Brooks
Factors influencing the biogeochemistry of iodine in the marine environment - Lucy Carpenter
Global model of aerosol processes - effects of aerosol in the marine atmospheric boundary layer GLOMAP Ken Carslaw
Ecological controls on fluxes of dimethyl sulphide (DMS) to the atmosphere - David Green
Dust outflow and deposition to the ocean DODO Ellie Highwood
Investigation of near surface production of iodocarbons - rates and exchanges INSPIRE Gill Malin
Reactive halogens in the marine boundary layer RHaMBLe Gordon McFiggans
The role of bacterioneuston in determining trace gas exchange rates - Colin Murrell
Measuring methanol in sea water and investigating its sources and sinks in the marine environment - Phil Nightingale
The impact of coastal upwellings on air-sea exchange of climatically important gases ICON Carol Robinson
The Deep Ocean Gas Exchange Experiment DOGEE Rob Upstill-Goddard
High wind air-sea exchanges HiWASE Margaret Yelland
Aerosol characterisation and modelling in the marine environment ACMME James Allan
3D simulation of dimethyl sulphide (DMS) in the north east Atlantic - Icarus Allen
Processes affecting the chemistry and bioavailability of dust borne iron - Michael Krom
The chemical structure of the lowermost atmosphere - Alastair Lewis
Factors influencing the oxidative chemistry of the marine boundary layer - Paul Monks

UK SOLAS has also supported ten tied studentships, and two CASE studentships.

Fieldwork

UK SOLAS fieldwork has included eight dedicated research cruises in the North Atlantic Ocean. Continuous measurements were made aboard aboard the Norwegian weather ship, Polarfront, until her decommission in 2009. Time series have been established at the SOLAS Cape Verde Observatory, and at the Plymouth Marine Laboratory L4 station. Experiments have taken place at the Bergen mesocosm facility.

A series of collaborative aircraft campaigns have added complementary atmospheric data. These campaigns were funded by UK SOLAS, African Monsoon Multidisciplinary Analyses (AMMA-UK), Dust and Biomass Experiment (DABEX) and the Facility for Airborne Atmospheric Measurements (FAAM).

Weblink: http://www.nerc.ac.uk/research/programmes/solas/


Data Activity or Cruise Information

Cruise

Cruise Name D326
Departure Date 2008-01-05
Arrival Date 2008-02-05
Principal Scientist(s)Eric Pieter Achterberg (University of Southampton School of Ocean and Earth Science)
Ship RRS Discovery

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification