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Metadata Report for BODC Series Reference Number 2079348


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
unknown  unknown
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Prof Toby Sherwin
Originating Organization Scottish Association for Marine Science
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) Northern Seas Programme (NSP)
 

Data Identifiers

Originator's Identifier CD176_CTD_PIGX_126:C034
BODC Series Reference 2079348
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2005-10-18 12:41
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 63.21633 N ( 63° 13.0' N )
Longitude 20.06467 W ( 20° 3.9' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 8.3 m
Maximum Sensor or Sampling Depth 652.1 m
Minimum Sensor or Sampling Height 5.9 m
Maximum Sensor or Sampling Height 649.7 m
Sea Floor Depth 658.0 m
Sea Floor Depth Source DATAHEAD
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
CPHLHPP11Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
FIRSEQID1DimensionlessBottle firing sequence number
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
SDCLHPP11Milligrams per cubic metreConcentration standard deviation of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

CD176 Chlorophyll Sampling Document

Originator's Protocol for Data Acquisition and Analysis

Water samples were collected from CTD stations throughout the cruise for later analysis at SAMS. Samples were taken at depths corresponding to discernible water masses or areas exhibiting raised or lowered values as determined from the CTD fluorescence, temperature, salinity and oxygen traces.

Samples were removed from CTD Niskin bottles and filtered through Whatman GF/F 25mm diameter filter discs which were then placed in 15mm polypropylene centrifuge tubes before freezing. The samples later underwent High Performance Liquid Chromotography analysis at SAMS.

References Cited

Sherwin, T. A. et al, (2005) 'Cruise CD176 Birkenhead to Falmouth via Rockall, Iceland and Oban', Internal Report No 248, Scottish Association for Marine Science.

Available - Cruise CD176 Internal Report

BODC Data Processing Procedures

The chlorophyll data were supplied to BODC in Microsoft Excel format and values were extracted from this and saved in ASCII format prior to being loaded into BODC's ocean database under the ORACLE Relational Database Management System. Data that were considered unrealistic were flagged suspect.

It should be noted that there were some discrepencies with the metadata provided for this cruise. For cast C016 discrete chlorophyll data was only available from 4 bottles as oposed to the 12 bottles that the cruise report log indicated were sampled.

Content of data series

Originator's Parameter Unit Description BODC Parameter code BODC Unit Comments
Chlorophyll a µg/l Concentration of chlorophyll a in the water column CPHLHPP1 mg/m3 n/a
Standard deviation of chlorophyll a µg/l Concentration standard deviation of chlorophyll a in the water column SDCLHPP1 mg/m3 n/a

Project Information

Northern Seas Programme

The Northern Seas describes an area extending from the Irish and northern North Sea across the Norwegian Sea up to the marginal Arctic pack-ice zone, including territorial waters of the UK, Norway, Iceland, Denmark and Russia. These waters are an important marine environment playing a significant part in regulating world climate due to the area's role in thermocline circulation in addition to acting as a sink for man-made pollutants carried north by ocean currents. These environments are experiencing increasing pressures from both natural and human impacts and consequently the Northern Seas Programme was developed to help advance the understanding of how marine systems in Northern Seas respond to environmental and anthropogenic change.

Scientific Objectives

The central aim of the programme was to 'improve understanding of how the sensitivity of marine ecosystems to environmental perturbation, both natural and anthropogenic, varies along a latitudinal gradient'.

This aim was addressed through the following integrated themes:

Theme A: Understanding fjordic systems: insights for coastal and oceanic processes

Theme B: Ocean Margins: the interface between the coastal zone and oceanic realm

Theme C: Measuring and modelling change: sea sensors and bioinformatics

The Northern Seas Programme was active between 2001 and 2007. The fieldwork programme to address these objectives was conducted by staff from the Scottish Association for Marine Science (SAMS).


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2005-10-18
End Date (yyyy-mm-dd) 2005-10-18
Organization Undertaking ActivityScottish Association for Marine Science
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierCD176_CTD_C034
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for CD176_CTD_C034

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
203715   1 1  659.00  660.00  652.10 Niskin bottle No problem reported    
203716   2 2  559.00  560.00  553.30 Niskin bottle No problem reported    
203717   3 3  305.60  306.60  302.90 Niskin bottle No problem reported    
203718   4 4  205.10  206.10  203.50 Niskin bottle No problem reported    
203719   5 5  104.10  105.10  103.60 Niskin bottle No problem reported    
203720   6 6   53.40   54.40   53.40 Niskin bottle No problem reported    
203721   7 7   23.20   24.20   23.50 Niskin bottle No problem reported    
203722   8 8    7.90    8.90    8.30 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name CD176
Departure Date 2005-10-06
Arrival Date 2005-11-01
Principal Scientist(s)Toby J Sherwin (Scottish Association for Marine Science)
Ship RRS Charles Darwin

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: CD176_CTD_C034

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
2139789Water sample data2005-10-18 12:41:3063.21633 N, 20.06467 WRRS Charles Darwin CD176
1351013Water sample data2005-10-18 12:42:0063.21633 N, 20.06467 WRRS Charles Darwin CD176