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Metadata Report for BODC Series Reference Number 2140441


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Non-toxic sea water supply  continuous water samplers
Instrument Mounting research vessel
Originating Country United Kingdom
Originator Dr Naomi Greenwood
Originating Organization Centre for Environment, Fisheries and Aquaculture Science Lowestoft Laboratory
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) UKOARP_ThemeA
 

Data Identifiers

Originator's Identifier 02_13_GPUMP_CO2X_533:
BODC Series Reference 2140441
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2013-02-16 07:22
End Time (yyyy-mm-dd hh:mm) 2013-03-13 04:23
Nominal Cycle Interval -
 

Spatial Co-ordinates

Southernmost Latitude 48.81180 N ( 48° 48.7' N )
Northernmost Latitude 52.09820 N ( 52° 5.9' N )
Westernmost Longitude 8.83550 W ( 8° 50.1' W )
Easternmost Longitude 1.90900 W ( 1° 54.5' W )
Positional Uncertainty 0.0 to 0.01 n.miles
Minimum Sensor or Sampling Depth 4.0 m
Maximum Sensor or Sampling Depth 4.0 m
Minimum Sensor or Sampling Height -
Maximum Sensor or Sampling Height -
Sea Floor Depth -
Sea Floor Depth Source -
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
AADYAA011DaysDate (time from 00:00 01/01/1760 to 00:00 UT on day)
AAFDZZ011DaysTime (time between 00:00 UT and timestamp)
ALATGP011DegreesLatitude north relative to WGS84 by unspecified GPS system
ALONGP011DegreesLongitude east relative to WGS84 by unspecified GPS system
MDMAP0141Micromoles per kilogramTotal alkalinity per unit mass of the water body
TCO2MSXX1Micromoles per kilogramConcentration of total inorganic carbon {TCO2 CAS 7440-44-0} per unit mass of the water body [dissolved plus reactive particulate phase]

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Public domain data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

The recommended acknowledgment is

"This study uses data from the data source/organisation/programme, provided by the British Oceanographic Data Centre and funded by the funding body."


Narrative Documents

Non-toxic (underway) sea water supply

A source of uncontaminated near-surface (commonly 3 to 7 m) seawater pumped continuously to shipboard laboratories on research vessels. There is typically a temperature sensor near the intake (known as the hull temperature) to provide measurements that are as close as possible to the ambient water temperature. The flow from the supply is typically directed through continuously logged sensors such as a thermosalinograph and a fluorometer. Water samples are often collected from the non-toxic supply. The system is also referred to as the underway supply.

UK Ocean Acidification (UKOA) chl-a, DIC, DO, NH4, NO2, TOxN, PO4, Si, SPM, TA and phaeopigments from bottle samples

Originator's Protocol for Data Acquisition and Analysis

These data were collected from the following CEFAS cruises: 01/13, 02/12, 02/13, 03/11, 05/12, 11/12, 13/11, 13/12, 14/11, 15/11, 15/12, 18/12 and 19/11 that took place in one or more of the North Sea, English Channel, Irish Sea and Celtic Sea between 2011 and 2013. Water samples were obtained either from CTD samples or from Ferrybox samples. CTD samples for discrete measurements were collected at selected depths using a CTD rosette of 10 litre Niskin bottles when visiting moorings for servicing. The CTD rosette was fitted with an FSI integrated CTD (Falmouth Scientific Inc., USA) to provide salinity, temperature and depth data.

Salinity, dissolved oxygen and SPM were collected and analysed according to Greenwood et al. (2010). Water samples for oxygen determination were collected and preserved in triplicate using the Winkler method. Samples were analysed on board using an automatic titration system (Sensoren Instrumente Systeme, Germany), with a photometric endpoint. For measurements of suspended particulate matter (SPM), known volumes were passed through pre-weighed 0.4 µm polycarbonate filters and rinsed with 2 x 50 ml ultrapure water. Filters were then dried in a dessicator at room temperature and weighed until filter weight remained constant. Samples were analysed for salinity using a Guildline 8400B salinometer which had been standardized with IAPSO standard seawater.

Total alkalinity and dissolved inorganic carbon were measured at NOCS according to Dickson et al. (2007).

Samples for nutrient analyses were collected from water bottle rosette sampling systems mounted on the lowered CTD. Each sample was passed through a Whatman GF/F filter and preserved with mercuric chloride to give a final concentration of 20 µg l-1. Samples were stored in the fridge at -18° C until analysed by a Skalar continuous flow analyzer, following Kirkwood (1996).

For chlorophyll measurements, known volumes were filtered through glass fibre filters (GF/F Whatman, UK) in triplicate. Pigments were immediately extracted in 90% buffered acetone and stored in the fridge prior to analysis. A Turner Designs Model 10AU filter fluorometer was used to measure the fluorescence of extracted chlorophyll and phaeopigment before and after acidification following the method described by Tett (1987).

References Cited

Dickson, A. G., Sabine, C. L., and Christian, J. R. 2007. Guide to best practices for ocean CO2 measurements, PICES Special Publication, 3, Sidney, Canada.

Greenwood, N., Parker, E.R., Fernand, L., Sivyer, D.B., Weston, K., Painting, S.J., Kröger, S., Forster, R.M., Lees, H.E., Mills, D.K., Laane, R.W.P.M. 2010. Detection of low bottom water oxygen concentrations in the North Sea; implications for monitoring and assessment of ecosystem health. Biogeosciences 7, p. 1357-1373.

Kirkwood, D. S. 1996. Nutrients: practical notes on their determination in seawater. ICES Techniques in Marine Environmental Sciences, no 17. International Council for the Exploration of the Seas, Copenhagen, p.23.

Tett, P. 1987. Plankton. In: Baker, J. M., Wolff, J. W. (Eds.), Biological surveys of estuaries and coasts. Cambridge University Press, Cambridge, p. 280-341.

Instrumentation Description

Guildline 8400B salinometer, Turner Designs Model 10AU filter fluorometer, Skalar continuous flow analyzer.

BODC Data Processing Procedures

Data were submitted to BODC in 13 individual Microsoft Excel spreadsheets for each cruise. The submission files were saved to the BODC archive with reference MAF140047. The following sample metadata were provided for each cruise: bottle number, cruise, date, time_GMT, Latitude, Longitude, station, sample_depth, water_column_depth and sampling device. The cruise, station, date and time were used to create new entries in the database. Several parameters received were not loaded because they were derived parameters (pH, fCO2, pCO2, HCO3, CO3 and calcite and aragonite saturation states). These variables were calculated from DIC and TA using CO2SYS and are available on request. Where repeat samples were provided, the average and standard were loaded to the database.

For all parameters except dissolved oxygen, no unit conversions were necessary as the units provided matched the units for the BODC parameter codes assigned. Oxygen units were converted as outlined in the table below. The dataset was loaded to the database following BODC protocols.

A parameter mapping table is provided below;

Originator's Variable Originator's Units BODC Parameter Code BODC Unit Comments
Temperature ° C TEMPCU01 degC -
Pressure db PRESPR01 dbar -
Salinity Dimensionless PSALBSTX Dimensionless -
Dissolved Oxygen mg l-1 DOXYWITX umol/l unit conversion applied x 62.502
Dissolved Oxygen standard deviation mg l-1 SDOXWITX umol/l unit conversion applied x 62.502
Chlorophyll µg l-1 CPHLFLP1 mg/m^3 -
Chlorophyll standard deviation µg l-1 CLSDFLP1 mg/m^3 -
Phaeopigments µg l-1 PHAEFLP1 mg/m^3 -
Phaeopigments standard deviation µg l-1 PHSDFLP1 mg/m^3 -
Ammonium µmol kg-1 AMONKGD1 umol/kg -
Total oxidisable Nitrogen µmol kg-1 NTRZKGD1 umol/kg -
Nitrite µmol kg-1 NTRIKGD1 umol/kg -
Phosphate µmol kg-1 PHOSKGD1 umol/kg -
Silicate µmol kg-1 SLCAKGD1 umol/kg -
Suspended Particulate Matter mg l-1 TSEDGVP2 mg/l -
Total Alkalinity µmol kg-1 MDMAP014 umol/kg -
Dissolved Inorganic Carbon µmol kg-1 TCO2MSXX umol/kg -

Project Information

UKOARP Theme A: Observations and synthesis to establish variability and trends of oceanic pH

This theme covers a programme of observations, combined with analysis of past and ongoing time series, to determine the magnitude of surface pH variations at seasonal-up-to-decadal time scales. Locations addressed will be the North Atlantic, UK shelf and slope waters, and selected locations in the Southern Ocean and Nordic Seas, using data from time series stations and volunteer observing ships (VOS), measuring three parameters of the marine carbonate system. The observations will be integrated with previous and ongoing international efforts, contributing to the SOCAT dataset, and to the internationally quality-controlled data relevant to ocean pH.

Aims:

  • To quantify the rate of progression of ocean acidification in the Atlantic (including European shelf and slope), Southern and Arctic Ocenas, including identification of when/where CaCO3 undersaturation will occur first.
  • To quantify spatial and/or seasonal variability of carbonate system parameters in these areas.
  • To improve quantification of the rate of oceanic CO2 uptake in these areas.

This theme will maintain/upgrade the following existing pCO2 observations with discrete Total Alkalinity (TA) and Dissolved Inorganic Carbon (DIC) sampling for:

  • The UK/Caribbean "Geest" line
  • The Pride of Bilbao ferry line
  • The Western Channel Observatory (WCO) and Irish Sea Coastal Observatory (ISCO)
  • The RRS James Clark Ross (previously funded under CARBON-OPS)

New observations will be established covering:

  • Weekly sampling for TA and DIC in Ryder Bay at Rothera base by the British Antarctic Survey. This will expand the Rothera Oceanographic and Biological Time Series (RaTS) to include carbonate chemistry.
  • RV CEFAS Endeavour to be equipped with an underway pCO2 measurement system to improve coverage in the shelf seas around England and Wales.
  • RV CEFAS Endeavour to sample TA and DIC during scheduled work to build up a dataset for UK coastal waters.
  • CEFAS "Smartbuoy" sites to be sampled for TA and DIC upto eight times per year on regular service visits to build up time series for each site.

Weblink: http://www.oceanacidification.org.uk/research_programme/co2_uptake.aspx


Data Activity or Cruise Information

Cruise

Cruise Name 02/13
Departure Date 2013-02-15
Arrival Date 2013-03-14
Principal Scientist(s)Richard Andrew Ayers (Centre for Environment, Fisheries and Aquaculture Science Lowestoft Laboratory)
Ship RV Cefas Endeavour

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification