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Metadata Report for BODC Series Reference Number 2259325


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Technicap NOEX bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country Netherlands
Originator Dr Wim Helder
Originating Organization Royal Netherlands Institute for Sea Research
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) OMEX I
 

Data Identifiers

Originator's Identifier CD86_CTD_DOXY_11:01
BODC Series Reference 2259325
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 1994-05-23 08:13
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 49.48474 N ( 49° 29.1' N )
Longitude 11.13522 W ( 11° 8.1' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 3.0 m
Maximum Sensor or Sampling Depth 198.0 m
Minimum Sensor or Sampling Height 11.4 m
Maximum Sensor or Sampling Height 206.4 m
Sea Floor Depth 209.4 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Variable common depth - All sensors are grouped effectively at the same depth, but this depth varies significantly during the series
Sensor or Sampling Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
DOXYWITX1Micromoles per litreConcentration of oxygen {O2 CAS 7782-44-7} per unit volume of the water body [dissolved plus reactive particulate phase] by Winkler titration
SAMPRFNM1DimensionlessSample reference number

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Public domain data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

The recommended acknowledgment is

"This study uses data from the data source/organisation/programme, provided by the British Oceanographic Data Centre and funded by the funding body."


Narrative Documents

Technicap NOEX bottle

The Technicap NOEX water bottle was designed for oceanographic sampling. The bottle comprises a plastic tube with caps at each end and is deployed with the caps held open, then closed at the target depth. Multiple bottles can be deployed on a CTD frame rosette. Bottle capacity is variable, but normally several litres. The bottle was developed by Technicap in the 1990s but has been superseded by more recent models. There is no known source of support available for this sampler.

Dissolved Oxygen for cruises Pelagia PLG93 and PLG95B and Charles Darwin CD86

Document History

Converted from CDROM documentation.

Content of data series

DOXYPR01 Beckman oxygen
Beckman oxygen probe
Micromoles/litre
DOXYWITX Winkler oxygen
Winkler titration
Micromoles/litre
OXYSBB01 Oxygen saturation (Bens.Kr./Beckman)
Benson and Krause algorithm from Beckman data
Per Cent

Data Originator

Dr Wim Helder, NIOZ, Texel, the Netherlands.

Sampling strategy and methodology

Water samples from CTD rosette bottles were analysed using the classical Winkler technique with minor modifications. Calibrated 100 ml oxygen bottles with ground glass stoppers were thoroughly flushed then filled without trapping any air. 1 ml of solution A (600g MnCl2.4H2O per litre) and 2 ml of solution B (250g NaOH, 350g KI per litre) were added immediately and the closed bottles shaken vigorously. The samples were shaken again once the precipitate had settled. The bottles were stored under water with the stoppers held closed by elastic bands.

Prior to analysis, about 25 ml of the supernatant was removed by syringe and then 1 ml of 20N sulphuric acid was added. Titration was carried out with 0.01N sodium thiosulphate in a Brand Digital Burette.

When the solutions in the bottle turned light yellow, 0.5 ml of 1% starch solution was added and titration continued until the solution became colourless. The sodium thiosulphate solution was made from a 0.1N stock solution in ampoules (Merck) and its strength was regularly checked by titration with 0.01N KIO3. Blank corrections were applied.

All samples were determined in duplicate at least. Accuracy is reported to be within 1%.

For Pelagia 95 a modified automatic Metrohm titration unit was introduced with spectrophotometric end point detection.

References

Aminot, A. and Chaussepied, M. (eds), 1983. Manuel des analyses chimiques en milieau marin. C.N. L'Exploitation des Oceans. 395 pp.

Benson, B.B., Krause D. (1984). The concentration and isotopic fractionation of oxygen dissolved in fresh water and sea water in equilibrium with the atmosphere. Limnol.Oceanogr., 29, 620-632.


Project Information

Ocean Margin EXchange (OMEX) I

Introduction

OMEX was a European multidisciplinary oceanographic research project that studied and quantified the exchange processes of carbon and associated elements between the continental shelf of western Europe and the open Atlantic Ocean. The project ran in two phases known as OMEX I (1993-1996) and OMEX II - II (1997-2000), with a bridging phase OMEX II - I (1996-1997). The project was supported by the European Union under the second and third phases of its MArine Science and Technology Programme (MAST) through contracts MAS2-CT93-0069 and MAS3-CT97-0076. It was led by Professor Roland Wollast from Université Libre de Bruxelles, Belgium and involved more than 100 scientists from 10 European countries.

Scientific Objectives

The aim of the Ocean Margin EXchange (OMEX) project was to gain a better understanding of the physical, chemical and biological processes occurring at the ocean margins in order to quantify fluxes of energy and matter (carbon, nutrients and other trace elements) across this boundary. The research culminated in the development of quantitative budgets for the areas studied using an approach based on both field measurements and modeling.

OMEX I (1993-1996)

The first phase of OMEX was divided into sub-projects by discipline:

  • Physics
  • Biogeochemical Cycles
  • Biological Processes
  • Benthic Processes
  • Carbon Cycling and Biogases

This emphasises the multidisciplinary nature of the research.

The project fieldwork focussed on the region of the European Margin adjacent to the Goban Spur (off the coast of Brittany) and the shelf break off Tromsø, Norway. However, there was also data collected off the Iberian Margin and to the west of Ireland. In all a total of 57 research cruises (excluding 295 Continuous Plankton Recorder tows) were involved in the collection of OMEX I data.

Data Availability

Field data collected during OMEX I have been published by BODC as a CD-ROM product, entitled:

  • OMEX I Project Data Set (two discs)

Further descriptions of this product and order forms may be found on the BODC web site.

The data are also held in BODC's databases and subsets may be obtained by request from BODC.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 1994-05-23
End Date (yyyy-mm-dd) 1994-05-23
Organization Undertaking ActivityRoyal Netherlands Institute for Sea Research
Country of OrganizationNetherlands
Originator's Data Activity IdentifierCD86_CTD_01
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for CD86_CTD_01

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
551209   12.00        2.30    3.90    3.00 Technicap NOEX bottle No problem reported    
551210   12.00       11.40   13.00   12.00 Technicap NOEX bottle No problem reported    
551211   12.00       22.40   24.00   23.00 Technicap NOEX bottle No problem reported    
551212   12.00       32.50   34.10   33.00 Technicap NOEX bottle No problem reported    
551213   12.00       52.60   54.20   53.00 Technicap NOEX bottle No problem reported    
551214   12.00      102.90  104.50  103.00 Technicap NOEX bottle No problem reported    
551215   12.00      198.50  200.10  198.00 Technicap NOEX bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name CD86
Departure Date 1994-05-20
Arrival Date 1994-06-13
Principal Scientist(s)Tjeerd van Weering (Royal Netherlands Institute for Sea Research)
Ship RRS Charles Darwin

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: CD86_CTD_01

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
2252025Water sample data1994-05-23 08:13:3049.48474 N, 11.13522 WRRS Charles Darwin CD86
2258475Water sample data1994-05-23 08:13:3049.48474 N, 11.13522 WRRS Charles Darwin CD86
1259825Water sample data1994-05-23 08:14:0049.48474 N, 11.13522 WRRS Charles Darwin CD86
1663736Water sample data1994-05-23 08:14:0049.48474 N, 11.13522 WRRS Charles Darwin CD86