Metadata Report for BODC Series Reference Number 1044793
Metadata Summary
Problem Reports
Data Access Policy
Narrative Documents
Project Information
Data Activity or Cruise Information
Fixed Station Information
BODC Quality Flags
SeaDataNet Quality Flags
Metadata Summary
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Problem Reports
No Problem Report Found in the Database
Quality report M81/1
The chlorophyll profiles show numerous instances where there are negative values, especially where the instrument output should be 0. This suggests the manufacturer calibration is underestimating the concentrations. Negative data values have been flagged all data should be used with caution.
Data Access Policy
GEOTRACES - data access conditions
Access to this data is currently restricted and it is not available via BODC's normal delivery mechanisms.
GEOTRACES data are published via the GEOTRACES IDP, available at:
Narrative Documents
Sea-Bird Dissolved Oxygen Sensor SBE 43 and SBE 43F
The SBE 43 is a dissolved oxygen sensor designed for marine applications. It incorporates a high-performance Clark polarographic membrane with a pump that continuously plumbs water through it, preventing algal growth and the development of anoxic conditions when the sensor is taking measurements.
Two configurations are available: SBE 43 produces a voltage output and can be incorporated with any Sea-Bird CTD that accepts input from a 0-5 volt auxiliary sensor, while the SBE 43F produces a frequency output and can be integrated with an SBE 52-MP (Moored Profiler CTD) or used for OEM applications. The specifications below are common to both.
Specifications
Housing | Plastic or titanium |
Membrane | 0.5 mil- fast response, typical for profile applications 1 mil- slower response, typical for moored applications |
Depth rating | 600 m (plastic) or 7000 m (titanium) 10500 m titanium housing available on request |
Measurement range | 120% of surface saturation |
Initial accuracy | 2% of saturation |
Typical stability | 0.5% per 1000 h |
Further details can be found in the manufacturer's specification sheet.
Instrument Description M81/1
Standard Rosette CTD Unit and Auxiliary Sensors
The CTD unit was a Sea-Bird 9/11 plus with dual SBE5 PUMPs and a SBE 11plus V2 Deck Unit.
The table below lists detailed information about the various sensors.
Sensor | Model | Comments |
---|---|---|
Pressure transducer | SBE-911 plus Digiquartz pressure sensor | - |
Conductivity sensor | SBE 4C | Primary sensor |
Conductivity sensor | SBE 4C | Secondary sensor |
Temperature sensor | SBE 3 | Primary sensor |
Temperature sensor | SBE 3 | Secondary sensor |
Dissolved oxygen | SBE 43 | - |
Fluorometer | Seapoint | - |
Sea-Bird Electronics SBE 911 and SBE 917 series CTD profilers
The SBE 911 and SBE 917 series of conductivity-temperature-depth (CTD) units are used to collect hydrographic profiles, including temperature, conductivity and pressure as standard. Each profiler consists of an underwater unit and deck unit or SEARAM. Auxiliary sensors, such as fluorometers, dissolved oxygen sensors and transmissometers, and carousel water samplers are commonly added to the underwater unit.
Underwater unit
The CTD underwater unit (SBE 9 or SBE 9 plus) comprises a protective cage (usually with a carousel water sampler), including a main pressure housing containing power supplies, acquisition electronics, telemetry circuitry, and a suite of modular sensors. The original SBE 9 incorporated Sea-Bird's standard modular SBE 3 temperature sensor and SBE 4 conductivity sensor, and a Paroscientific Digiquartz pressure sensor. The conductivity cell was connected to a pump-fed plastic tubing circuit that could include auxiliary sensors. Each SBE 9 unit was custom built to individual specification. The SBE 9 was replaced in 1997 by an off-the-shelf version, termed the SBE 9 plus, that incorporated the SBE 3 plus (or SBE 3P) temperature sensor, SBE 4C conductivity sensor and a Paroscientific Digiquartz pressure sensor. Sensors could be connected to a pump-fed plastic tubing circuit or stand-alone.
Temperature, conductivity and pressure sensors
The conductivity, temperature, and pressure sensors supplied with Sea-Bird CTD systems have outputs in the form of variable frequencies, which are measured using high-speed parallel counters. The resulting count totals are converted to numeric representations of the original frequencies, which bear a direct relationship to temperature, conductivity or pressure. Sampling frequencies for these sensors are typically set at 24 Hz.
The temperature sensing element is a glass-coated thermistor bead, pressure-protected inside a stainless steel tube, while the conductivity sensing element is a cylindrical, flow-through, borosilicate glass cell with three internal platinum electrodes. Thermistor resistance or conductivity cell resistance, respectively, is the controlling element in an optimized Wien Bridge oscillator circuit, which produces a frequency output that can be converted to a temperature or conductivity reading. These sensors are available with depth ratings of 6800 m (aluminium housing) or 10500 m (titanium housing). The Paroscientific Digiquartz pressure sensor comprises a quartz crystal resonator that responds to pressure-induced stress, and temperature is measured for thermal compensation of the calculated pressure.
Additional sensors
Optional sensors for dissolved oxygen, pH, light transmission, fluorescence and others do not require the very high levels of resolution needed in the primary CTD channels, nor do these sensors generally offer variable frequency outputs. Accordingly, signals from the auxiliary sensors are acquired using a conventional voltage-input multiplexed A/D converter (optional). Some Sea-Bird CTDs use a strain gauge pressure sensor (Senso-Metrics) in which case their pressure output data is in the same form as that from the auxiliary sensors as described above.
Deck unit or SEARAM
Each underwater unit is connected to a power supply and data logging system: the SBE 11 (or SBE 11 plus) deck unit allows real-time interfacing between the deck and the underwater unit via a conductive wire, while the submersible SBE 17 (or SBE 17 plus) SEARAM plugs directly into the underwater unit and data are downloaded on recovery of the CTD. The combination of SBE 9 and SBE 17 or SBE 11 are termed SBE 917 or SBE 911, respectively, while the combinations of SBE 9 plus and SBE 17 plus or SBE 11 plus are termed SBE 917 plus or SBE 911 plus.
Specifications
Specifications for the SBE 9 plus underwater unit are listed below:
Parameter | Range | Initial accuracy | Resolution at 24 Hz | Response time |
---|---|---|---|---|
Temperature | -5 to 35°C | 0.001°C | 0.0002°C | 0.065 sec |
Conductivity | 0 to 7 S m-1 | 0.0003 S m-1 | 0.00004 S m-1 | 0.065 sec (pumped) |
Pressure | 0 to full scale (1400, 2000, 4200, 6800 or 10500 m) | 0.015% of full scale | 0.001% of full scale | 0.015 sec |
Further details can be found in the manufacturer's specification sheet.
Seapoint Chlorophyll Fluorometer
The Seapoint Chlorophyll Fluorometer (SCF) is a low power instrument for in situ measurements of chlorophyll a. The SCF uses modulated blue LED lamps and a blue excitation filter to excite chlorophyll a. The fluorescent light emitted by the chlorophyll a passes through a red emission filter and is detected by a silicon photodiode. The low level signal is then processed using synchronous demodulation circuitry which generates an output voltage proportional to chlorophyll a concentration. The SCF may be operated with or without a pump.
Sensor specifications, current at August 2006, are given in the table below. More information can be found at the manufacturer's web site.
Sensor Specifications
Power requirements | 8 - 20 VDC, 15 mA avg., 27 mA pk. |
---|---|
Output | 0 - 5.0 VDC |
Output Time Constant | 0.1 sec. |
Power-up transient period | < 1 sec. |
Excitation Wavelength | 470 nm CWL, 30 nm FWHM |
Emission Wavelength | 685 nm CWL, 30 nm FWHM |
Sensing Volume | 340 mm3 |
Minimum Detectable Level | 0.02 µg l-1 |
Gain | Sensitivity, V µg-1 l-1 | Range, µg l-1 | |
---|---|---|---|
Sensitivity/Range | 30x 10x 3x 1x | 1.0 0.33 0.1 0.033 | 5 15 50 150 |
BODC Processing M81/1
Reformatting
The data arrived at BODC as 68 ASCII files (48 standard CTD casts and 20 trace metal CTD casts), representing all of the CTD casts taken during the cruise. These were reformatted to the internal QXF format (subset of NETcdf). The following table shows how the variables within the ASCII files were mapped to the appropriate BODC parameter codes.
Originator's Parameter Name | Units | Description | BODC Parameter Code | Units | Comments |
---|---|---|---|---|---|
Pressure, Digiquartz | dbar | Pressure of water body on profiling pressure sensor | PRESPR01 | dbar | - |
Temperature [ITS-90] | °C | Temperature of water column by CTD | TEMPCU01 | °C | - |
Salinity, Practical | - | Practical salinity of the water body by CTD | PSALCC01 | - | Generated by Sea-Bird software from CTD temperature and conductivity data and calibrated against discrete samples |
Oxygen, SBE 43 | µmol/Kg | Dissolved oxygen concentration from SBE 43 sensor and calibrated against discrete samples | DOXMSDXX | µmol/Kg | - |
Fluorometer | ug/l | Concentration of chlorophyll-a from an in-situ chlorophyll fluorometer | CPHLPM01 | Milligrams per cubic metre | Manufacturer's calibration applied, no data for the Trace Metal CTD |
Sigma-theta | kg m-3 | Sigma-theta of the water body by CTD | SIGTPR01 | kg m-3 | - |
Screening
Reformatted CTD data were visualised using the in-house graphical editor EDSERPLO. No data values were edited or deleted. Quality control flags were applied to data as necessary.
References
Fofonoff, NP and Millard, RC (1983). Algorithms for computations of fundamental properties of seawater. UNESCO Technical Papers in Marine Science No. 44, 53pp.
UNESCO, 1981. Background papers and supporting data on the International Equation of State of Seawater 1980. UNESCO Technical Papers in Marine Science No. 38, 192pp
Originator's Data Processing
Sampling Strategy
The main objective of Meteor cruise M81/1 (GEOTRACES cruise A11) was to carry out a detailed sampling of the water column for trace metals and their isotopes (TEIs) along a NNE-SSW section in the tropical Atlantic Ocean as part of the international GEOTRACES program. Two CTD systems were used during out the cruise; a trace metal clean CTD (20 casts) and a normal CTD rosette (48 casts).
Data Processing
No information provided by originator.
Field Calibrations
Discrete salinity and oxygen samples were collected from each cast and used to calibrate the CTD sensor data.
Project Information
GEOTRACES
Introduction
GEOTRACES is an international programme sponsored by SCOR which aims to improve our understanding of biogeochemical cycles and large-scale distribution of trace elements and their isotopes (TEIs) in the marine environment. The global field programme started in 2009 and will run for at least a decade. Before the official launch of GEOTRACES, fieldwork was carried out as part of the International Polar Year (IPY)(2007-2009) where 14 cruises were connected to GEOTRACES.
GEOTRACES is expected to become the largest programme to focus on the chemistry of the oceans and will improve our understanding of past, present and future distributions of TEIs and their relationships to important global processes.
This initiative was prompted by the increasing recognition that TEIs are playing a crucial role as regulators and recorders of important biogeochemical and physical processes that control the structure and productivity of marine ecosystems, the dispersion of contaminants in the marine environment, the level of greenhouse gases in the atmosphere, and global climate.
Scientific Objectives
GEOTRACES mission is: To identify processes and quantify fluxes that control the distribution of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions.
Three overriding goals support the GEOTRACES mission
- Determine ocean distributions of selected TEIs at all major ocean basins
- Evaluate the sources, sinks, and internal cycling of these TEIs and thereby characterize more completely their global biogeochemical cycles
- Provide a baseline distribution in the Polar Regions as reference for assessing past and future changes.
These goals will be pursued through complementary research strategies, including observations, experiments and modelling.
Fieldwork
The central component of GEOTRACES fieldwork will be a series of cruises spanning all Ocean basins see map below.
Three types of cruise are required to meet the goals set out by GEOTRACES. These are
- Section cruises - These will measure all the key parameters (see below) over the full depth of the water column. The sections were discussed and approved by the International GEOTRACES Scientific Steering Committee at the basin workshops.
- Process Studies - These will investigate a particular process relevant to the cycling of trace metal and isotopes. They must follow the "Criteria for Establishing GEOTRACES Process Studies" and be approved by the International GEOTRACES Scientific Steering Committee.
- Cruises collecting GEOTRACES compliant data - These will collect some trace element or isotope data. They must follow the GEOTRACES Intercalibration and Data Management protocols
IPY-GEOTRACES
The IPY-GEOTRACES programme comprised of 14 research cruises on ships from 7 nations; Australia, Canada, France, Germany, New Zealand, Japan and Russia. The cruises will not be classified in the same way as the full GEOTRACES programme since the intercalibration protocols and data management protocols had not been established before the start of the IPY. But IPY-GEOTRACES data will still be quality controlled by GDAC and in the majority of cases verified versus Intercalibration standards or protocols.
Key parameters
The key parameters as set out by the GEOTRACES science plan are as follows: Fe, Al, Zn, Mn, Cd, Cu; 15N, 13C; 230Th, 231Pa; Pb isotopes, Nd isotopes; stored sample, particles, aerosols.
Weblink:
http://www.bodc.ac.uk/geotraces/
http://www.geotraces.org/
Data Activity or Cruise Information
Cruise
Cruise Name | M81_1 (GA11) |
Departure Date | 2010-02-04 |
Arrival Date | 2010-03-08 |
Principal Scientist(s) | Martin Frank (GEOMAR Helmholtz Centre for Ocean Research, Kiel (East Shore Campus)) |
Ship | FS Meteor |
Complete Cruise Metadata Report is available here
Fixed Station Information
No Fixed Station Information held for the Series
BODC Quality Control Flags
The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:
Flag | Description |
---|---|
Blank | Unqualified |
< | Below detection limit |
> | In excess of quoted value |
A | Taxonomic flag for affinis (aff.) |
B | Beginning of CTD Down/Up Cast |
C | Taxonomic flag for confer (cf.) |
D | Thermometric depth |
E | End of CTD Down/Up Cast |
G | Non-taxonomic biological characteristic uncertainty |
H | Extrapolated value |
I | Taxonomic flag for single species (sp.) |
K | Improbable value - unknown quality control source |
L | Improbable value - originator's quality control |
M | Improbable value - BODC quality control |
N | Null value |
O | Improbable value - user quality control |
P | Trace/calm |
Q | Indeterminate |
R | Replacement value |
S | Estimated value |
T | Interpolated value |
U | Uncalibrated |
W | Control value |
X | Excessive difference |
SeaDataNet Quality Control Flags
The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:
Flag | Description |
---|---|
0 | no quality control |
1 | good value |
2 | probably good value |
3 | probably bad value |
4 | bad value |
5 | changed value |
6 | value below detection |
7 | value in excess |
8 | interpolated value |
9 | missing value |
A | value phenomenon uncertain |
B | nominal value |
Q | value below limit of quantification |