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Metadata Report for BODC Series Reference Number 1871474


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Prof Patrick Holligan
Originating Organization University of Southampton School of Ocean and Earth Science
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) Atlantic Meridional Transect Phase2(AMT)
 

Data Identifiers

Originator's Identifier AMT16_CTD_PIGX_216:CTD048s
BODC Series Reference 1871474
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2005-06-18 05:24
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 31.38485 N ( 31° 23.1' N )
Longitude 42.13909 W ( 42° 8.3' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 15.1 m
Maximum Sensor or Sampling Depth 15.1 m
Minimum Sensor or Sampling Height 3462.9 m
Maximum Sensor or Sampling Height 3462.9 m
Sea Floor Depth 3478.0 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
ALLOHPP11Nanograms per litreConcentration of alloxanthin {CAS 28380-31-6} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
BUTAHPP11Nanograms per litreConcentration of 19'-butanoyloxyfucoxanthin {But-fuco(BF) CAS 111234-30-1} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CHLBHPP11Nanograms per litreConcentration of chlorophyll-b {chl-b CAS 519-62-0} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CLC2HPP11Nanograms per litreConcentration of chlorophyll-c2 {chl-c2} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CLC3HPP11Nanograms per litreConcentration of chlorophyll-c3 {chl-c3} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
CPHLHPP11Milligrams per cubic metreConcentration of chlorophyll-a {chl-a CAS 479-61-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
DIADHPP11Nanograms per litreConcentration of diadinoxanthin {CAS 18457-54-0} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
DVCAHPP11Nanograms per litreConcentration of divinyl chlorophyll-a {DVchl-a} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
FIRSEQID1DimensionlessBottle firing sequence number
FUCXHPP11Nanograms per litreConcentration of fucoxanthin {CAS 3351-86-8} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
HEXOHPP11Nanograms per litreConcentration of 19'-hexanoyloxyfucoxanthin {CAS 60147-85-5} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
LUTNHPP11Nanograms per litreConcentration of lutein {CAS 127-40-2} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
PERIHPP11Nanograms per litreConcentration of peridinin {CAS 33281-81-1} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
PRSXHPP11Nanograms per litreConcentration of prasinoxanthin {CAS 94705-97-2} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
VILXHPP11Nanograms per litreConcentration of violaxanthin {CAS 126-29-4} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)
ZEOXHPP11Nanograms per litreConcentration of zeaxanthin {CAS 144-68-3} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC)

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Pigment composition by HPLC analysis from CTD bottle and surface underway samples during cruise AMT16

Data Acquisition and Analysis

Samples were collected for pigment composition analysis from the underway sampling every 4-5 hours and from CTD bottles samples were collected from the 6 main light depths (97, 55, 33, 14, 1 and 0.1% of surface irradiance) from the pre-dawn cast. A reduced set of 3 measurements were sampled from the late morning 'optics' cast.

HPLC analysis was carried out according to Barlow et al. (1997).

References Cited

Barlow R.G., Cummings D.G. and Gibb S.W., 1997. Improved resolution of mono- and divinyl chlorophylls a and b and zeaxanthin and lutein in phytoplankton extracts using reverse phase C8 HPLC. Marine Ecology Progress Series, 161 , 303-307.

Instrumentation Description

Section not relevant.

BODC Data Processing Procedures

Data were submitted to BODC in Microsoft Excel spreadsheet format and archived with BODC's accession number SOC090128. The file was provided to BODC with the following metadata: CTD cast number, date, time, lat, lon, and bottle depth.

Sample metadata were checked against information held in the database - there were no discrepancies.

Data were reformatted and the variables assigned BODC Parameter codes as defined in the BODC parameter dictionary. A unit conversion of x 1000 was applied to the data where appropriate for conversion into nanograms per litre. Chl a data were provided with equivilent units to the BODC parameter code assigned, so no unit converesion was applied. The 'Tchl' (Total chl-a) data supplied were not loaded to the database as it is a derived parameter as the total of Chla and Dvchla. The parameter mapping is shown in the table below.

Originator's Parameter Units Description BODC Parameter Code Units Comments
Chl c3 mg m-3 Concentration of chlorophyll-c3 {chl-c3} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CLC3HPP1 ng l-1 Unit conversion x1000 applied
Chl c2 mg m-3 Concentration of chlorophyll-c2 {chl-c2} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CLC2HPP1 ng l-1 Unit conversion x1000 applied
Peridinin mg m-3 Concentration of peridinin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) PERIHPP1 ng l-1 Unit conversion x1000 applied
19 But mg m-3 Concentration of 19'-butanoyloxyfucoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) BUTAHPP1 ng l-1 Unit conversion x1000 applied
Fuco mg m-3 Concentration of fucoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) FUCXHPP1 ng l-1 Unit conversion x1000 applied
19Hex mg m-3 Concentration of 19'-hexanoyloxyfucoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) HEXOHPP1 ng l-1 Unit conversion x1000 applied
Prasino mg m-3 Concentration of prasinoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) PRSXHPP1 ng l-1 Unit conversion x1000 applied
Violoxan mg m-3 Concentration of violoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) VILXHPP1 ng l-1 Unit conversion x1000 applied
Diadino mg m-3 Concentration of diadinoxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) DIADHPP1 ng l-1 Unit conversion x1000 applied
Alloxan mg m-3 Concentration of alloxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) ALLOHPP1 ng l-1 Unit conversion x1000 applied
Zeaxan mg m-3 Concentration of zeaxanthin per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) ZEOXHPP1 ng l-1 Unit conversion x1000 applied
Lutein mg m-3 Concentration of lutein per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) LUTNHPP1 ng l-1 Unit conversion x1000 applied
Chlb mg m-3 Concentration of chlorophyll-b per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CHLBHPP1 ng l-1 Unit conversion x1000 applied
Dvchla mg m-3 Concentration of divinyl chlorophyll-a per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) DVCAHPP1 ng l-1 Unit conversion x1000 applied
Chl a mg m-3 Concentration of chlorophyll-a {chl-a} per unit volume of the water body [particulate >GF/F phase] by filtration, acetone extraction and high performance liquid chromatography (HPLC) CPHLHPP1 mg m-3 n/a

Data Quality Report

BODC was advised by the data originator that only surface data from the CTD samples were provided, as there were data quality issues with the samples collected from CTD bottles fired at depth. None of the suspect data have been supplied to BODC.

Problem Report

This section is not relevant to this data set.


Project Information

The Atlantic Meridional Transect - Phase 2 (2002-2006)

Who was involved in the project?

The Atlantic Meridional Transect Phase 2 was designed by and implemented by a number of UK research centres and universities. The programme was hosted by Plymouth Marine Laboratory in collaboration with the National Oceanography Centre, Southampton. The universities involved were:

  • University of Liverpool
  • University of Newcastle
  • University of Plymouth
  • University of Southampton
  • University of East Anglia

What was the project about?

AMT began in 1995, with scientific aims to assess mesoscale to basin scale phytoplankton processes, the functional interpretation of bio-optical signatures and the seasonal, regional and latitudinal variations in mesozooplankton dynamics. In 2002, when the programme restarted, the scientific aims were broadened to address a suite of cross-disciplinary questions concerning ocean plankton ecology and biogeochemistry and the links to atmospheric processes.

The objectives included the determination of:

  • how the structure, functional properties and trophic status of the major planktonic ecosystems vary in space and time
  • how physical processes control the rates of nutrient supply to the planktonic ecosystem
  • how atmosphere-ocean exchange and photo-degradation influence the formation and fate of organic matter

The data were collected with the aim of being distributed for use in the development of models to describe the interactions between the global climate system and ocean biogeochemistry.

When was the project active?

The second phase of funding allowed the project to continue for the period 2002 to 2006 and consisted of six research cruises. The first phase of the AMT programme ran from 1995 to 2000.

Brief summary of the project fieldwork/data

The fieldwork on the first three cruises was carried out along transects from the UK to the Falkland Islands in September and from the Falkland Islands to the UK in April. The last three cruises followed a cruise track between the UK and South Africa, only deviating from the traditional transect in the southern hemisphere. During this phase the research cruises sampled further into the centre of the North and South Atlantic Ocean and also along the north-west coast of Africa where upwelled nutrient rich water is known to provide a significant source of climatically important gases.

Who funded the project?

Natural Environment Research Council (NERC)


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2005-06-18
End Date (yyyy-mm-dd) 2005-06-18
Organization Undertaking ActivityPlymouth Marine Laboratory
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierAMT16_CTD_CTD048s
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for AMT16_CTD_CTD048s

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
515810 20.0 1 1   302.60   302.80   299.70 Niskin bottle Bottle leak    
515811 20.0 2 2   227.50   227.60   225.10 Niskin bottle No problem reported    
515812 20.0 3 3   181.20   181.60   179.30 Niskin bottle No problem reported    
515813 20.0 4 4   181.80   182.70   180.20 Niskin bottle Bottle leak    
515814 20.0 5 5   136.30   136.70   134.80 Niskin bottle No problem reported    
515815 20.0 6 6   121.40   121.70   119.90 Niskin bottle No problem reported    
515816 20.0 7 7   121.20   121.70   119.80 Niskin bottle No problem reported    
515817 20.0 8 8   120.40   121.30   119.20 Niskin bottle No problem reported    
515818 20.0 9 9   101.80   101.90   100.40 Niskin bottle No problem reported    
515819 20.0 10 10     76.10     76.20     74.90 Niskin bottle Partial sample loss    
515820 20.0 11 11     50.70     51.20     49.90 Niskin bottle No problem reported    
515821 20.0 12 12     50.60     51.20     49.80 Niskin bottle No problem reported    
515822 20.0 13 13     29.10     29.20     28.20 Niskin bottle No problem reported    
515823 20.0 14 14     29.10     29.20     28.20 Niskin bottle No problem reported    
515824 20.0 15 15     15.90     16.10     15.20 Niskin bottle No problem reported    
515825 20.0 16 16     15.80     16.20     15.20 Niskin bottle No problem reported    
515826 20.0 17 17     16.00     16.20     15.30 Niskin bottle No problem reported    
515827 20.0 18 18     15.70     16.10     15.10 Niskin bottle No problem reported    
515828 20.0 19 19     15.80     16.30     15.20 Niskin bottle No problem reported    
515829 20.0 20 20     15.70     16.10     15.10 Niskin bottle No problem reported    
515830 20.0 21 21       5.70       6.00       5.10 Niskin bottle No problem reported    
515831 20.0 22 22       2.90       3.20       2.30 Niskin bottle No problem reported    
515832 20.0 23 23       3.00       3.20       2.30 Niskin bottle No problem reported    
515833 20.0 24 24       2.70       3.00       2.10 Niskin bottle No problem reported    

Please note: the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name D294 (AMT16)
Departure Date 2005-05-20
Arrival Date 2005-06-29
Principal Scientist(s)Tony Bale (Plymouth Marine Laboratory)
Ship RRS Discovery

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: AMT16_CTD_CTD048s

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
1131870Water sample data2005-06-18 05:24:0031.38485 N, 42.13909 WRRS Discovery D294 (AMT16)
1872152Water sample data2005-06-18 05:24:0031.38485 N, 42.13909 WRRS Discovery D294 (AMT16)