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Metadata Report for BODC Series Reference Number 2001822


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Metrohm 848 Titrino Plus Titrator  titrators
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Mr Tim Brand
Originating Organization Scottish Association for Marine Science
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) Changing Arctic Ocean
 

Data Identifiers

Originator's Identifier JR18007_CTD_DOXY_304:CTD031
BODC Series Reference 2001822
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2019-08-19 23:34
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 79.66660 N ( 79° 40.0' N )
Longitude 9.39960 E ( 9° 24.0' E )
Positional Uncertainty 0.0 to 0.01 n.miles
Minimum Sensor or Sampling Depth 152.0 m
Maximum Sensor or Sampling Depth 333.1 m
Minimum Sensor or Sampling Height 8.2 m
Maximum Sensor or Sampling Height 189.3 m
Sea Floor Depth 341.3 m
Sea Floor Depth Source BUDS
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
DOXYWITX1Micromoles per litreConcentration of oxygen {O2 CAS 7782-44-7} per unit volume of the water body [dissolved plus reactive particulate phase] by Winkler titration
FIRSEQID1DimensionlessBottle firing sequence number
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
SDOXWITX1Micromoles per litreConcentration standard deviation of oxygen {O2 CAS 7782-44-7} per unit volume of the water body [dissolved plus reactive particulate phase] by Winkler titration

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Metrohm 848 Titrino Plus titrator

The Metrohm 848 Titrino Plus is a titrator used for dynamic and monotonic determination of solution concentrations. The Titrino Plus is simple to operate and robust so is ideal for daily, routine laboratory titrations. The titrator can be used in applications such as aqueous and non-aqueous, acid and base, redox, precipitation, complexometric and photometric titrations as well as titrations with polarizable electrodes.

The 848 Titrino Plus is composed of an exchange unit, stirrer and USB compact printer that when connected are automatically recognized and configured. The Metrohm exchange unit contains an intelligent chip that automatically passes data necessary for an error-free titration, such as cylinder volume, reagent type and titer validity, to the titrator. The high-resolution measuring interface of the 848 Titrino also ensures that highly precise results are obtained and the large live display, with titration curve, enables the user to easily determine the status of a titration.

Either a magnetic stirrer or a propeller stirrer can be connected to the Titrino Plus and the stirring rate is stored, guaranteeing maximum reproducibility of data.

Specifications

Dosing element Exchange unit
Steps per cylinder volume 10,000
Operation, dialog Keyboard and mouse
Stirrer, titration stand 801 Magnetic Stirrer or 802 Rod Stirrer
Connection of balance, printer, USB keyboard, USB mouse, USB stick and barcode reader Via 1 USB Slave Port, RS 232/USB Box (option)
PC/LIMS report RS 232/USB Box (option) and USB stick
Balance connection RS 232/USB Box (option)
Manual operation Measuring, dosing, stirring

Further details can be found in the manufacturer's specification sheet.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Dissolved oxygen concentrations from CTD samples for Cruise JR18007

Originator's Protocol for Data Acquisition and Analysis

Analysis for dissolved oxygen levels was undertaken at each CTD site, with the exception of the ice edge station. Triplicate 150ml samples were taken using the CTD from three separate representative depths, usually near-bottom, mid-depth and surface, totalling 9 samples per station. The samples were immediately fixed using a standardised method, and transferred to the laboratory on board and analysed using the Metrohm 848 Titrino

JR18007 Cruise report

Further information can be found in the JR18007 Cruise report.

BODC Data Processing Procedures

Data received were loaded into the BODC database using established BODC data banking procedures. A parameter mapping table is provided below:

Originator's Variable Originator's Units BODC Parameter Code BODC Unit Comments
MEAN O2 umol/l DOXYWITX umol/l -
STDEV O2 umol/l SDOXWITX umol/l -

Data quality Report

Oxygen measurements that had been flagged as questionable (3) by the originator were also averaged and has standard deviations calculated. The resultant data has been flagged as L within the BODC database.


Project Information

Changing Arctic Ocean: Implications for marine biology and biogeochemistry

Changing Arctic Ocean (CAO) is a £16 million, five year (2017-2022) research programme initially funded by the Natural Environment Research Council (NERC). The aim of the CAO programme is to understand how change in the physical environment (ice and ocean) will affect the large-scale ecosystem structure and biogeochemical functioning of the Arctic Ocean, the potential major impacts and provide projections for future ecosystem services. In July 2018, additional projects were added to the programme that were jointly funded by NERC and the German Federal Ministry of Education and Research.

Background

The Arctic Ocean is responding to global climate change in ways that are not yet fully understood and in some cases, not yet identified. The impacts of change in the Arctic are global in range and international in importance. To achieve the aim, the programme has two key research challenges:

  • To develop quantified understanding of the structure and functioning of Arctic ecosystems.
  • To understand the sensitivity of Arctic ecosystem structure, functioning and services to multiple stressors and the development of projections of the impacts of change.

The decision to fund the CAO project was both scientific and political and is the second largest research programme funded by NERC.

The programme involves 33 organisations, the majority of which are research institutions in the UK and Germany, and over 170 scientists. The programme consists of four large projects with an additional 12 research projects added in July 2018.

Further information can be found on the Changing Arctic Ocean website.

Participants

There are 33 organisations involved in the Changing Arctic Ocean project, these are:

  • Alfred Wegener Institut (AWI)
  • Bangor University
  • British Antarctic Survey (BAS)
  • Centre for Environment, Fisheries and Aquaculture Science (CEFAS)
  • Durham University
  • GEOMAR
  • Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research
  • Lancaster University
  • Marine Biological Association (MBA)
  • Max Planck Institute for the Science of Human History
  • National Oceanography Centre (NOC)
  • Newcastle University
  • Northumbria University
  • Ocean Atmosphere Systems GmbH
  • Plymouth Marine Laboratory (PML)
  • Scottish Association for Marine Science (SAMS)
  • Scottish Universities Environmental Research Centre (SUERC)
  • Université Libre de Bruxelles
  • University College London (UCL)
  • University of Bristol
  • University of East Anglia (UEA)
  • University of Edinburgh
  • University of Glasgow
  • University of Huddersfield
  • University of Leeds
  • University of Liverpool
  • University of Manchester
  • University of Oldenburg
  • University of Oxford
  • University of Southampton
  • University of St Andrews
  • University of Stirling
  • University of Strathclyde

In addition to the core organisation, there are a number of international collaborators.

Research Details

The four large projects funded by NERC are:

  • Arctic Productivity in the seasonal Ice Zone (Arctic PRIZE)
  • Can we detect changes in Arctic ecosystems? (ARISE)
  • The Changing Arctic Ocean Seafloor (ChAOS) - How changing sea ice conditions impact biological communities, biogeochemical processes and ecosystems
  • Mechanistic understanding of the role of diatoms in the success of the Arctic Calanus complex and implications for a warmer Arctic (DIAPOD)

The additional 12 projects added in July 2018 funded jointly by NERC and the German Federal Ministry of Education and Research are:

  • Advective Pathways of nutrients and key Ecological substances in the Arctic (APEAR)
  • How will changing freshwater export and terrestrial permafrost thaw influence the Arctic Ocean? (CACOON)
  • Chronobiology of changing Arctic Sea Ecosystems (CHASE)
  • Potential benefits and risks of borealisation for fish stocks and ecosystems in a changing Arctic Ocean (Coldfish)
  • Diatom Autecological Responses with Changes To Ice Cover (Diatom-ARCTIC)
  • Ecosystem functions controlled by sea ice and light in a changing Arctic (Eco-Light)
  • Effects of ice stressors and pollutants on the Arctic marine cryosphere (EISPAC)
  • Linking Oceanography and Multi-specific, spatially-Variable Interactions of seabirds and their prey in the Arctic (LOMVIA)
  • Understanding the links between pelagic microbial ecosystems and organic matter cycling in the changing Arctic (Micro-ARC)
  • Microbes to Megafauna Modelling of Arctic Seas (MiMeMo)
  • Primary productivity driven by escalating Arctic nutrient fluxes? (PEANUTS)
  • Pathways and emissions of climate-relevant trace gases in a changing Arctic Ocean (PETRA)

Fieldwork and Data Collection

The programme consists of seven core cruises that survey areas in the Barents Sea and the Fram Strait on board the NERC research vessel RRS James Clark Ross. Measurements will include temperature, salinity, dissolved oxygen, dissolved inorganic carbon, total alkalinity, inorganic nutrients, oxygen and carbon isotopes and underway meteorological and surface ocean observations. In addition to ship based cruise datasets gliders, moorings and animal tags are part of the fieldwork. Further data are collected from model runs.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2019-08-19
End Date (yyyy-mm-dd) 2019-08-19
Organization Undertaking ActivityUniversity of Stirling, Institute of Aquaculture
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierJR18007_CTD_CTD031
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for JR18007_CTD_CTD031

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
1408976   20.00 1 1  336.80  336.90  333.10 Niskin bottle No problem reported    
1408979   20.00 2 2  336.80  336.90  333.00 Niskin bottle No problem reported    
1408982   20.00 3 3  305.10  305.30  301.70 Niskin bottle No problem reported    
1408985   20.00 4 4  203.60  203.90  201.50 Niskin bottle No problem reported    
1408988   20.00 5 5  203.70  203.90  201.50 Niskin bottle No problem reported    
1408991   20.00 6 6  203.70  203.80  201.50 Niskin bottle No problem reported    
1408994   20.00 8 8  103.00  103.30  102.00 Niskin bottle No problem reported    
1408997   20.00 9 9  103.00  103.20  102.00 Niskin bottle No problem reported    
1409000   20.00 10 10   76.00   76.20   75.30 Niskin bottle No problem reported    
1409003   20.00 11 11   50.60   50.80   50.20 Niskin bottle No problem reported    
1409006   20.00 12 12   50.60   50.80   50.20 Niskin bottle No problem reported    
1409009   20.00 13 13   30.40   30.70   30.20 Niskin bottle No problem reported    
1409012   20.00 14 14   18.50   18.70   18.50 Niskin bottle No problem reported    
1409015   20.00 15 15   18.60   18.90   18.50 Niskin bottle No problem reported    
1409018   20.00 17 17    5.50    5.70    5.50 Niskin bottle No problem reported    
1409777   20.00 7 7  153.50  153.90  152.00 Niskin bottle No problem reported    
1409780   20.00 16 16    5.50    5.80    5.60 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name JR18007
Departure Date 2019-08-04
Arrival Date 2019-09-06
Principal Scientist(s)David Pond (University of Stirling, Institute of Aquaculture)
Ship RRS James Clark Ross

Complete Cruise Metadata Report is available here


Fixed Station Information

Fixed Station Information

Station NameCAO D4
CategoryOffshore location
Latitude79° 40.00' N
Longitude9° 23.98' E
Water depth below MSL341.0 m

Changing Arctic Ocean Fixed Station D4

This station is one of several sites sampled in the Fram Strait as part of the Changing Arctic Ocean programme. The station has a mean water depth 341 m at the following co-ordinates:

Latitude Longitude
79.66659° N 9.39961° E

Sampling History

JR18007
CTD casts 2
Bongo nets 4
MOCNESS 2

Related Fixed Station activities are detailed in Appendix 2


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: JR18007_CTD_CTD031

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
2053481Water sample data2019-08-19 23:33:3079.6666 N, 9.3996 ERRS James Clark Ross JR18007

Appendix 2: CAO D4

Related series for this Fixed Station are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
1981316CTD or STD cast2019-08-19 21:06:1079.6667 N, 9.3997 ERRS James Clark Ross JR18007
1981328CTD or STD cast2019-08-19 23:12:5079.6665 N, 9.3995 ERRS James Clark Ross JR18007
2053481Water sample data2019-08-19 23:33:3079.6666 N, 9.3996 ERRS James Clark Ross JR18007