Metadata Report for BODC Series Reference Number 2002340

• Metadata Summary

• Problem Reports

• Data Access Policy

• Narrative Documents

• Project Information

• Data Activity or Cruise Information

• Fixed Station Information

• BODC Quality Flags

• SeaDataNet Quality Flags

Metadata Summary

Problem Reports

No Problem Report Found in the Database

Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."

Narrative Documents

SEAL Analytical QuAAtro colorimetric autoanalyser

The SEAL QuAAtro high Performance Microflow Analyzer is the latest generation of the original world-class Technicon^TM Segmented Flow Analysis (SFA) systems.

A basic SFA system consists of an autosampler, a peristaltic pump, a chemistry manifold, a detector and data acquisition software. Sample and reagents are pumped continuously through the chemistry manifold. Air bubbles are introduced at regular intervals forming unique reaction segments which are mixed using glass coils. Glass is ideal, as it is inert, stays clean and enables easy visual checks.

In SFA, reactions run to completion and the ratio of sample to reagents in the detector reaches a constant maximum value. This results in ultra-low detection limits and exceptional reproducibility. Variations in reaction time, temperature and sample matrix do not affect the results as they do in other colorimetric techniques, such as flow injection analysis, where the reaction is not brought to completion.

QuAAtro is a microflow SFA system, the internal diameter of all glassware being 1 mm. This reduces reagent consumption and increases throughput, with most methods running at 100 - 120 samples hour. The integrated enclosed manifold and detector are heated to 37 °C. Flow stability is ensured as the optimal bubble frequency for each method is programmed by silent air valves. Automatic start-up, method changeover and shutdown allows true unattended operation and overnight running. QuAAtro checks its own performance, with automatic monitoring of noise, drift, bubble pattern and light energy, before and during a run.

Up to four methods can run at the same time on one console, and there is a special 5-channel version for nutrients in seawater. Two consoles can be combined to give an 8-channel system.

Further details can be found in the manufacturer's specification sheet.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

DY054 Nutrients from CTD Bottles Processing Document

Originator's Protocol for Data Acquisition and Analysis

Seawater samples were collected from 38 CTD casts at varying depths during cruise RRS Discovery cruise DY054. Seawater was taken from Niskin bottles attached to the CTD frame and put into sample bottles that had been rinsed three times. A syringe was then used to draw the water from the larger sample bottle into a smaller one using 0.8/0.2µmol filters, which had also been rinsed three times by the filtered water. The final water sample was saved and frozen in -20°C freezers for future analysis on shore at the Royal Netherlands Institute for Sea Research (NIOZ) using a SEAL Analytical QuAAtro Autoanalyser. Measurements were made simultaneously for Phosphate (PO4), Nitrate with Nitrite (NO3+NO2), Nitrate (NO3), and Nitrite (NO2). They were all calibrated with stock-standards diluted into low nutruent seawater (LNSW) in the same salinity range as the samples. For more information, please refer to the cruise report.

BODC Data Processing Procedures

The nutrient data were supplied in an excel spreadsheet. The data were mapped to BODC parameters as specified below:

Project Information

UK - Overturning in the Subpolar North Atlantic Programme (UK-OSNAP) Programme

UK-OSNAP is part of an international collaboration to establish a transoceanic observing system in the subpolar North Atlantic. The aim is to quantify and understand the Subpolar Gyre's response to local and remote forcing of mass, heat and freshwater fluxes, within the conceptual framework of the Atlantic Meridional Overturning Circulation (AMOC).

UK-OSNAP is developing a new observing system to provide a continuous record of full-depth, trans-basin mass, heat, and freshwater fluxes. Combining these sustained measurements with innovative modelling techniques will enable the project to characterise the circulation and fluxes of the North Atlantic Subpolar Gyre.

UK-OSNAP is funded by the Natural Environment Research Council (NERC). The project is led by the National Oceanography Centre (NOC) with partners in the University of Liverpool, the University of Oxford and the Scottish Association for Marine Science (SAMS). It is a part of international OSNAP that is led by USA and includes 10 further partner groups in Canada, France, Germany, the Netherlands and China. The project involves fieldwork at sea and model studies.

The OSNAP observing system consists of two legs: one extending from southern Labrador to the southwestern tip of Greenland across the mouth of the Labrador Sea (OSNAP West), and the second from the southeastern tip of Greenland to Scotland (OSNAP East). The observing system also includes subsurface floats (OSNAP Floats) in order to trace the pathways of overflow waters in the basin and to assess the connectivity of currents crossing the OSNAP line.

NERC have added an extension to UK-OSNAP, until October 2024. This will result in the UK-OSNAP-Decade: 10 years of observing and understanding the overturning circulation in the subpolar North Atlantic (2014-2024).

Data Activity or Cruise Information

Data Activity

BODC Sample Metadata Report for DY054_CTD_CTD38

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Cruise

Complete Cruise Metadata Report is available here

Fixed Station Information

No Fixed Station Information held for the Series

BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle: