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Metadata Report for BODC Series Reference Number 2119242


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Skalar SAN+ System colorimetric autoanalyser  colorimeters; autoanalysers
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Mr Mark Stinchcombe
Originating Organization National Oceanography Centre, Southampton
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) UKSOLAS
 

Data Identifiers

Originator's Identifier D326_CTD_DCDN_257:16396A
BODC Series Reference 2119242
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2008-01-12 06:53
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 23.39705 N ( 23° 23.8' N )
Longitude 27.50981 W ( 27° 30.6' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 4.8 m
Maximum Sensor or Sampling Depth 302.1 m
Minimum Sensor or Sampling Height 5180.3 m
Maximum Sensor or Sampling Height 5477.6 m
Sea Floor Depth 5482.4 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
FIRSEQID1DimensionlessBottle firing sequence number
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
TPHSWCD11Micromoles per litreConcentration of total phosphorus {total_P CAS 7723-14-0} {TDP} per unit volume of the water body [dissolved plus reactive particulate

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Skalar San+ Autoanalyzer

The San+ Autoanalyzer is an Automated Wet Chemistry Analyzer (Continuous Flow Analyzer) which has been designed as a modular system to measure a variety of water chemistry characteristics, such as nutrient concentrations in seawater. Individual modules are tailored to specific needs. It uses Continuous Flow Analysis (CFA), allowing up to 16 analytical measurements to be made on a single sample simultaneously. The system comprises a sampler, chemistry section, detector and specialist software.

Chemistry section
The San+ includes a chemistry section which has hundreds of applications. It houses up to five chemistry cartridges with built-in dosing pump and air injection systems, up to five interchangeable cartridges with build-in photometric detectors and five separate waste receptacles. The throughput of the analyser depends upon application and can vary from 25 to 120 analyses per hour. It has a double diameter pump deck for accurate dosing with 32 pump tubes, two separated pump decks for 2 x 2 channel concept, and controlled synchronised eight channel air injection with separate built-in compressor for increased flow stability and fast start-up. It has easy access to chemistry cartridges with flexible ultra low carry-over connections between dialysers, reactors, coils, flow cells and other components, leak detection, 3-cuffs long life pump tubes, and has manually operated and automatic rinsing valves for easy automatic start up and overnight operation.

Detectors
The San+ range of detectors comprises dual channel colorimetric detectors, the unique matrix correction detector with automatic background correction for difficult sample matrixes, but also covers a range of detectors for I.R., U.V., fluorimetry, ISE, flame photometry, refractometers, density meters, etc.

Software
The San+ 'Flow Access' windows software package controls the complete analyser, with auto start-up, function control, and auto-scaling, pre-and post run sample dilutions, result calculation and statistics. Up to 16 channels can be handled simultaneously, with multiple samplers, and chemistries can be grouped for analysis.

The San+ is also known as San++.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Total dissolved phosphorus concentrations for UK SOLAS cruise D326

Originator's Protocol for Data Acquisition and Analysis

Samples for total dissolved phosphorus (TDP) were collected from the stainless steel CTD deployments and filtered through a GF/F filter. The filtrates were exposed under a UV irradiation with a mercury lamp to oxidise organic phosphorus into phosphate, which was measured colorimetrically onboard.

BODC Data Processing Procedures

The data were submitted to BODC in a spreadsheet format file (D326_nuts_data_TDP.xls) containing TDP concentrations and the following metadata fields: cast number and rosette position number. Total dissolved nitrogen (TDN) concentrations were also included in the spreadsheet; however, BODC was advised to discard the TDN data as they will be analysed using a different, preferable method in a shore-based laboratory and submitted separately.

Parameter codes defined in BODC parameter dictionary were assigned to the variables as follows:

Originator's Parameter Unit Description BODC Parameter Code BODC Unit Comments
Phosphate uM Total dissolved phosphorus TPHSWCD1 umol l-1 none

The data were banked according to BODC standard procedures. The data were banked as received, with no averaging applied. Three replicate data were removed at cast 384A, 417A and 433A after consultation with the originator.

Data Quality Report

There are no major data quality issues to report apart from two data points flagged as being 'suspect' by BODC, which should be used with care.


Project Information

UK Surface Ocean Lower Atmosphere Study

The UK Surface Ocean Lower Atmosphere Study (UK SOLAS) is the UK's contribution to the international SOLAS programme.

UK SOLAS formed interdisciplinary teams to address three primary aims

  • To determine the mechanisms controlling rates of chemical transfer and improve estimates of chemical exchanges
  • To evaluate the impact of these exchanges on the biogeochemistry of the surface ocean and lower atmosphere and on feedbacks between the ocean and atmosphere
  • To quantify the impacts of these boundary layer processes on the global climate system

UK SOLAS started in 2003, to run for seven years. The programme was funded by the Natural Environment Research Council.

Funded projects

In total, 19 projects have been funded by UK SOLAS, over four funding rounds.

Project Title Short Title Principal Investigator
Impact of atmospheric dust derived material and nutrient inputs on near-surface plankton microbiota in the tropical North Atlantic Dust Eric Achterberg
The role and effects of photoprotective compounds in marine plankton - Steve Archer
Field observations of sea spray, gas fluxes and whitecaps SEASAW Ian Brooks
Factors influencing the biogeochemistry of iodine in the marine environment - Lucy Carpenter
Global model of aerosol processes - effects of aerosol in the marine atmospheric boundary layer GLOMAP Ken Carslaw
Ecological controls on fluxes of dimethyl sulphide (DMS) to the atmosphere - David Green
Dust outflow and deposition to the ocean DODO Ellie Highwood
Investigation of near surface production of iodocarbons - rates and exchanges INSPIRE Gill Malin
Reactive halogens in the marine boundary layer RHaMBLe Gordon McFiggans
The role of bacterioneuston in determining trace gas exchange rates - Colin Murrell
Measuring methanol in sea water and investigating its sources and sinks in the marine environment - Phil Nightingale
The impact of coastal upwellings on air-sea exchange of climatically important gases ICON Carol Robinson
The Deep Ocean Gas Exchange Experiment DOGEE Rob Upstill-Goddard
High wind air-sea exchanges HiWASE Margaret Yelland
Aerosol characterisation and modelling in the marine environment ACMME James Allan
3D simulation of dimethyl sulphide (DMS) in the north east Atlantic - Icarus Allen
Processes affecting the chemistry and bioavailability of dust borne iron - Michael Krom
The chemical structure of the lowermost atmosphere - Alastair Lewis
Factors influencing the oxidative chemistry of the marine boundary layer - Paul Monks

UK SOLAS has also supported ten tied studentships, and two CASE studentships.

Fieldwork

UK SOLAS fieldwork has included eight dedicated research cruises in the North Atlantic Ocean. Continuous measurements were made aboard aboard the Norwegian weather ship, Polarfront, until her decommission in 2009. Time series have been established at the SOLAS Cape Verde Observatory, and at the Plymouth Marine Laboratory L4 station. Experiments have taken place at the Bergen mesocosm facility.

A series of collaborative aircraft campaigns have added complementary atmospheric data. These campaigns were funded by UK SOLAS, African Monsoon Multidisciplinary Analyses (AMMA-UK), Dust and Biomass Experiment (DABEX) and the Facility for Airborne Atmospheric Measurements (FAAM).

Weblink: http://www.nerc.ac.uk/research/programmes/solas/


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2008-01-12
End Date (yyyy-mm-dd) 2008-01-12
Organization Undertaking ActivityUniversity of Southampton School of Ocean and Earth Science
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierD326_CTD_16396A
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for D326_CTD_16396A

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
193722   20.00 5 5  152.20  153.20  151.70 Niskin bottle No problem reported    
193723   20.00 6 6  152.70  153.20  151.90 Niskin bottle No problem reported    
193724   20.00 7 7  122.40  122.80  121.80 Niskin bottle No problem reported    
193725   20.00 8 8  121.50  122.90  121.40 Niskin bottle No problem reported    
193726   20.00 9 9  122.20  123.20  121.90 Niskin bottle No problem reported    
193727   20.00 10 10  121.90  122.70  121.50 Niskin bottle No problem reported    
193728   20.00 11 11  101.70  103.30  101.80 Niskin bottle No problem reported    
193729   20.00 12 12  101.50  102.80  101.50 Niskin bottle No problem reported    
193730   20.00 13 13   76.60   78.50   77.00 Niskin bottle No problem reported    
193731   20.00 14 14   76.50   78.20   76.80 Niskin bottle No problem reported    
193732   20.00 15 15   52.10   53.00   52.20 Niskin bottle No problem reported    
193733   20.00 16 16   51.80   53.40   52.30 Niskin bottle No problem reported    
193734   20.00 17 17   31.60   33.20   32.20 Niskin bottle No problem reported    
193735   20.00 18 18   31.30   32.30   31.60 Niskin bottle No problem reported    
193736   20.00 19 19   11.20   13.00   12.00 Niskin bottle No problem reported    
193737   20.00 20 20   11.70   12.00   11.80 Niskin bottle No problem reported    
193738   20.00 21 21    4.30    5.30    4.80 Niskin bottle No problem reported    
193739   20.00 22 22    2.70    4.70    3.70 Niskin bottle No problem reported    
193740   20.00 23 23    3.70    5.10    4.40 Niskin bottle No problem reported    
193741   20.00 24 24    3.30    5.20    4.20 Niskin bottle No problem reported    
193811   20.00 1 1  303.70  304.70  302.10 Niskin bottle No problem reported    
193812   20.00 2 2  304.10  304.50  302.20 Niskin bottle No problem reported    
193813   20.00 3 3  203.20  203.40  201.90 Niskin bottle No problem reported    
193814   20.00 4 4  202.40  203.40  201.50 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name D326
Departure Date 2008-01-05
Arrival Date 2008-02-05
Principal Scientist(s)Eric Pieter Achterberg (University of Southampton School of Ocean and Earth Science)
Ship RRS Discovery

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: D326_CTD_16396A

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
2124834Water sample data2008-01-12 06:53:3023.39705 N, 27.50981 WRRS Discovery D326
2134644Water sample data2008-01-12 06:53:3023.39705 N, 27.50981 WRRS Discovery D326
1346011Water sample data2008-01-12 06:54:0023.39705 N, 27.50981 WRRS Discovery D326
1347524Water sample data2008-01-12 06:54:0023.39705 N, 27.50981 WRRS Discovery D326
1984800Water sample data2008-01-12 06:54:0023.39705 N, 27.50981 WRRS Discovery D326