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Metadata Report for BODC Series Reference Number 2131695


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Dr Sheldon Bacon
Originating Organization National Oceanography Centre, Southampton
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) Rapid Climate Change Programme
 

Data Identifiers

Originator's Identifier D298_CTD_DOXY_188:C003
BODC Series Reference 2131695
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2005-08-31 13:32
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 57.27052 N ( 57° 16.2' N )
Longitude 34.78220 W ( 34° 46.9' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 7.4 m
Maximum Sensor or Sampling Depth 2197.4 m
Minimum Sensor or Sampling Height 20.7 m
Maximum Sensor or Sampling Height 2210.7 m
Sea Floor Depth 2218.1 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Unspecified -
Sensor or Sampling Depth Datum Unspecified -
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
DOXYWITX1Micromoles per litreConcentration of oxygen {O2 CAS 7782-44-7} per unit volume of the water body [dissolved plus reactive particulate phase] by Winkler titration
FIRSEQID1DimensionlessBottle firing sequence number
SAMPRFNM1DimensionlessSample reference number

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data supplied by Natural Environment Research Council (NERC)

You must always use the following attribution statement to acknowledge the source of the information: "Contains data supplied by Natural Environment Research Council."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

D298 Discrete Dissolved Oxygen Sampling Document

Originator's Protocol for Data Acquisition and Analysis

Water samples were collected from a total of 63 CTD stations visited during the cruise.

Samples were drawn from 10L Niskin bottles following the collection of samples for CFC analysis. Samples were drawn through short pieces of silicon tubing into clear, pre-calibrated, wide necked glass bottles. The temperature of each sample was recorded whilst on deck to determine temperature dependent volume changes of samples. Samples were then fixed with 1 ml of Manganous Chloride solution followed by 1 ml of Alkali Iodate solution. Care was taken to avoid introducing air bubbles to samples when inserting the bottle specific lid, and samples were then shaken, transferred to the chemsitry laboratory and stored in a dark cupboard prior to analysis.

Analysis was conducted approximately 8 hours after samples were collected using the Winkler whole bottle titration method with spectrophotometric end-point determination.

References

Bacon, S. (2006) 'RRS Discovery Cruise 298, 23 AUG - 25 SEP 2005, Cape Farewell and Eirik Ridge', Cruise Report No. 10, National Oceanography Centre, Southampton.

Available - D298 Cruise Report

BODC Data Processing Procedures

The data were supplied to BODC in original sample files. Values were extracted from these and saved in ASCII format prior to being loaded into BODC's ocean database under the ORACLE Relational Database Management System. Data that were considered unrealistic were flagged suspect.

Content of data series

Originator's Parameter Unit Description BODC Parameter code BODC Unit Comments
Oxygen mg l-1 Concentration of oxygen {O2} per unit volume of the water body [dissolved phase] by Winkler titration DOXYWITX mg l-1 -
Temperature degrees Celsius Temperature of the water body by hand-held digital thermometer TEMPDTNX degrees Celsius -

Project Information

Rapid Climate Change (RAPID) Programme

Rapid Climate Change (RAPID) is a £20 million, six-year (2001-2007) programme of the Natural Environment Research Council (NERC). The programme aims to improve our ability to quantify the probability and magnitude of future rapid change in climate, with a main (but not exclusive) focus on the role of the Atlantic Ocean's Thermohaline Circulation.

Scientific Objectives

  • To establish a pre-operational prototype system to continuously observe the strength and structure of the Atlantic Meridional Overturning Circulation (MOC).
  • To support long-term direct observations of water, heat, salt, and ice transports at critical locations in the northern North Atlantic, to quantify the atmospheric and other (e.g. river run-off, ice sheet discharge) forcing of these transports, and to perform process studies of ocean mixing at northern high latitudes.
  • To construct well-calibrated and time-resolved palaeo data records of past climate change, including error estimates, with a particular emphasis on the quantification of the timing and magnitude of rapid change at annual to centennial time-scales.
  • To develop and use high-resolution physical models to synthesise observational data.
  • To apply a hierarchy of modelling approaches to understand the processes that connect changes in ocean convection and its atmospheric forcing to the large-scale transports relevant to the modulation of climate.
  • To understand, using model experimentation and data (palaeo and present day), the atmosphere's response to large changes in Atlantic northward heat transport, in particular changes in storm tracks, storm frequency, storm strengths, and energy and moisture transports.
  • To use both instrumental and palaeo data for the quantitative testing of models' abilities to reproduce climate variability and rapid changes on annual to centennial time-scales. To explore the extent to which these data can provide direct information about the thermohaline circulation (THC) and other possible rapid changes in the climate system and their impact.
  • To quantify the probability and magnitude of potential future rapid climate change, and the uncertainties in these estimates.

Projects

Overall 38 projects have been funded by the RAPID programme. These include 4 which focus on Monitoring the Meridional Overturning Circulation (MOC), and 5 international projects jointly funded by the Netherlands Organisation for Scientific Research, the Research Council of Norway and NERC.

The RAPID effort to design a system to continuously monitor the strength and structure of the North Atlantic Meridional Overturning Circulation is being matched by comparative funding from the US National Science Foundation (NSF) for collaborative projects reviewed jointly with the NERC proposals. Three projects were funded by NSF.

A proportion of RAPID funding as been made available for Small and Medium Sized Enterprises (SMEs) as part of NERC's Small Business Research Initiative (SBRI). The SBRI aims to stimulate innovation in the economy by encouraging more high-tech small firms to start up or to develop new research capacities. As a result 4 projects have been funded.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2005-08-31
End Date (yyyy-mm-dd) 2005-08-31
Organization Undertaking ActivityNational Oceanography Centre, Southampton
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierD298_CTD_C003
Platform Categorylowered unmanned submersible

No Document Information Held for the Series

Cruise

Cruise Name D298
Departure Date 2005-08-23
Arrival Date 2005-09-25
Principal Scientist(s)Sheldon Bacon (National Oceanography Centre, Southampton)
Ship RRS Discovery

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification