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Metadata Report for BODC Series Reference Number 2296016


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country Germany
Originator Dr Robin Keir
Originating Organization Research Center for Marine Geosciences, Kiel (now GEOMAR Helmholtz Centre for Ocean Research, Kiel (East Shore Campus))
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) OMEX I
 

Data Identifiers

Originator's Identifier M27_1_CTD_CH4X_73:159401
BODC Series Reference 2296016
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 1994-01-15 13:50
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 48.33178 N ( 48° 19.9' N )
Longitude 11.50208 W ( 11° 30.1' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 13.6 m
Maximum Sensor or Sampling Depth 3693.3 m
Minimum Sensor or Sampling Height 28.0 m
Maximum Sensor or Sampling Height 3707.7 m
Sea Floor Depth 3721.3 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Variable common depth - All sensors are grouped effectively at the same depth, but this depth varies significantly during the series
Sensor or Sampling Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
CH4CGCXX1Nanomoles per litreConcentration of methane {CH4 CAS 74-82-8} per unit volume of the water body [dissolved plus reactive particulate phase] by gas chromatography
SAMPRFNM1DimensionlessSample reference number

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Public domain data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

The recommended acknowledgment is

"This study uses data from the data source/organisation/programme, provided by the British Oceanographic Data Centre and funded by the funding body."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Methane for cruises Meteor M27_1, Belgica BG9506 and Poseidon PS211

Document History

Converted from CDROM documentation.

Content of data series

CH4AGCXX Atmospheric methane
Gas chromatography
Nanomoles per litre
CH4CGCXX Dissolved methane
Gas chromatography
Nanomoles per litre

Data Originator

Professor Robin Keir, GEOMAR, Kiel, Germany.

Sampling strategy and methodology

Water samples were collected from the CTD rosette and analysed on board ship for dissolved methane. The gas phase was obtained by two methods. The first involved a partial separation of gas and water phases under vacuum using repeated application of ultrasound. The second utilised equilibration of the water sample with a small volume of added pure nitrogen head space. Dissolved methane was then computed from the measured gas phase mixing ratio and the methane solubility at the laboratory conditions of temperature and salinity.

Measurements of surface dissolved methane were obtained as a by-product of the underway pCO2 determination. Surface sea water (from an inlet in the bow of Belgica or the 'moon pool' of Poseidon) was continuously pumped through the gas equilibrator where the dissolved gases exchanged with a closed loop of air. The gas loop was sampled periodically (approximately every 10 minutes) and the CO2 separated from the methane by the GC column. The CO2 was then reduced by hydrogen over a nickel catalyst and analysed as methane. This resulted in two peaks that could be quantified separately for methane and carbon dioxide.

Air samples were collected periodically (approximately hourly) from an inlet mounted on the bow of the ship and analysed in the same way as the equilibrated gases.

The surface methane data were reduced by the data originator to average values for each one degree square traversed by the ship. The data in this reduced form could be loaded into the database for Poseidon PS211 because the cruise track was a simple straight line. However, Belgica passed through a number of squares several times during the cruise making loading of the spatially averaged data impossible. Consequently, the full raw data set (water samples every 10 minutes with an air sample approximately every hour) has been loaded for this cruise.


Project Information

Ocean Margin EXchange (OMEX) I

Introduction

OMEX was a European multidisciplinary oceanographic research project that studied and quantified the exchange processes of carbon and associated elements between the continental shelf of western Europe and the open Atlantic Ocean. The project ran in two phases known as OMEX I (1993-1996) and OMEX II - II (1997-2000), with a bridging phase OMEX II - I (1996-1997). The project was supported by the European Union under the second and third phases of its MArine Science and Technology Programme (MAST) through contracts MAS2-CT93-0069 and MAS3-CT97-0076. It was led by Professor Roland Wollast from Université Libre de Bruxelles, Belgium and involved more than 100 scientists from 10 European countries.

Scientific Objectives

The aim of the Ocean Margin EXchange (OMEX) project was to gain a better understanding of the physical, chemical and biological processes occurring at the ocean margins in order to quantify fluxes of energy and matter (carbon, nutrients and other trace elements) across this boundary. The research culminated in the development of quantitative budgets for the areas studied using an approach based on both field measurements and modeling.

OMEX I (1993-1996)

The first phase of OMEX was divided into sub-projects by discipline:

  • Physics
  • Biogeochemical Cycles
  • Biological Processes
  • Benthic Processes
  • Carbon Cycling and Biogases

This emphasises the multidisciplinary nature of the research.

The project fieldwork focussed on the region of the European Margin adjacent to the Goban Spur (off the coast of Brittany) and the shelf break off Tromsø, Norway. However, there was also data collected off the Iberian Margin and to the west of Ireland. In all a total of 57 research cruises (excluding 295 Continuous Plankton Recorder tows) were involved in the collection of OMEX I data.

Data Availability

Field data collected during OMEX I have been published by BODC as a CD-ROM product, entitled:

  • OMEX I Project Data Set (two discs)

Further descriptions of this product and order forms may be found on the BODC web site.

The data are also held in BODC's databases and subsets may be obtained by request from BODC.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 1994-01-15
End Date (yyyy-mm-dd) 1994-01-15
Organization Undertaking ActivityUniversity of Bremen, Center for Marine Environmental Sciences
Country of OrganizationGermany
Originator's Data Activity IdentifierM27_1_CTD_159401
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for M27_1_CTD_159401

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
552491   12.00     3756.30 3757.80 3693.30 Niskin bottle No problem reported    
552492   12.00     3739.30 3740.80 3676.70 Niskin bottle No problem reported    
552493   12.00     3527.30 3528.80 3470.10 Niskin bottle No problem reported    
552494   12.00     3016.30 3017.80 2971.00 Niskin bottle No problem reported    
552495   12.00     2415.30 2416.80 2382.60 Niskin bottle No problem reported    
552496   12.00     1811.30 1812.80 1789.70 Niskin bottle No problem reported    
552497   12.00     1009.30 1010.80  999.80 Niskin bottle No problem reported    
552498   12.00      403.30  404.80  400.90 Niskin bottle No problem reported    
552499   12.00      247.30  248.80  246.50 Niskin bottle No problem reported    
552500   12.00      154.30  155.80  154.30 Niskin bottle No problem reported    
552501   12.00       52.90   54.40   53.90 Niskin bottle No problem reported    
552502   12.00       12.30   13.80   13.60 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name M27_1
Departure Date 1993-12-29
Arrival Date 1994-01-17
Principal Scientist(s)Wolfgang Balzer (University of Bremen, Center for Marine Environmental Sciences)
Ship FS Meteor

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: M27_1_CTD_159401

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
1254998Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1
2295800Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1
2296121Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1
2296201Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1
2296305Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1
2296410Water sample data1994-01-15 13:50:0048.33178 N, 11.50208 WFS Meteor M27_1