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Metadata Report for BODC Series Reference Number 2284470


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Shimadzu Total Organic Carbon Analyser (TOC-VCPN)  elemental analysers
Instrument Mounting lowered unmanned submersible
Originating Country United Kingdom
Originator Miss Tingting Shi
Originating Organization University of Southampton School of Ocean and Earth Science
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) UKOARP_ThemeB
 

Data Identifiers

Originator's Identifier JR20120601_CTD_DCDN_3568:CTD017s
BODC Series Reference 2284470
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 2012-06-08 06:27
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 60.59422 N ( 60° 35.7' N )
Longitude 18.85645 W ( 18° 51.4' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 6.4 m
Maximum Sensor or Sampling Depth 276.5 m
Minimum Sensor or Sampling Height 2238.6 m
Maximum Sensor or Sampling Height 2508.7 m
Sea Floor Depth 2515.1 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Variable common depth - All sensors are grouped effectively at the same depth, but this depth varies significantly during the series
Sensor or Sampling Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
Sea Floor Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
CORGCOD11Micromoles per litreConcentration of organic carbon {organic_C CAS 7440-44-0} {DOC} per unit volume of the water body [dissolved plus reactive particulate
FIRSEQID1DimensionlessBottle firing sequence number
NTOTCOD11Micromoles per litreConcentration of total nitrogen {total_N} per unit volume of the water body [dissolved plus reactive particulate
ROSPOSID1DimensionlessBottle rosette position identifier
SAMPRFNM1DimensionlessSample reference number
SEOCCOD11Micromoles per litreConcentration standard error of organic carbon {organic_C CAS 7440-44-0} {DOC} per unit volume of the water body [dissolved plus reactive particulate
SETNCOD11Micromoles per litreConcentration standard error of total nitrogen {total_N} per unit volume of the water body [dissolved plus reactive particulate

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Open Data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

If the Information Provider does not provide a specific attribution statement, or if you are using Information from several Information Providers and multiple attributions are not practical in your product or application, you may consider using the following:

"Contains public sector information licensed under the Open Government Licence v1.0."


Narrative Documents

Shimadzu Total Organic Carbon Analyser (TOC-VCPN)

The TOC-VCPN is a Total Organic Carbon analyser, developed by Shimadzu, that uses the 680°C combustion catalytic oxidation method to efficiently analyse all organic compounds.

This model differs from the TOC-VCPH in the detection limits, measuring time for Inorganic carbon, sample injection volume and gas consumption.

Specifications

  TOC-VCPN
Measurement range Total Carbon - 50μg/L - 25000mg/L
Inorganic Carbon - 50μg/L - 3000mg/L
Total Nitrogen (optional module) - 20μg/L - 4000mg/L
Measurement Accuracy 1.5% max
Measuring time aprox 3 minutes for Total and Inorganic Carbon and 4 minutes for Total Nitrogen
Sample injection volume 10 to 150 µl
Gas consumption aprox 2210 l month-1

For more information about this model see the manufactures TOC-V series manual.

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Cruise JR20120601 (JR271) Dissolved Organic Carbon and Total Nitrogen concentrations from CTD samples

Originator's Protocol for Data Acquisition and Analysis

Filtered and acidified seawater samples were sparged with oxygen to remove dissolved inorganic carbon from the water and then injected into a combustion column. The non-purgeable organic carbon in the sample was combusted at 680 °C and converted to CO2, which can be detected by a non-dispersive infrared detector (NDIR).

BODC Data Processing Procedures

Data were submitted to BODC in Microsoft Excel spreadsheet format. Sample metadata which was provided by the originator include date, CTD number, date, latitude, longitude, niskin bottle number and sample depth.

No unit conversions were necessary as the submitted data matched the parameter codes in the BODC Parameter Dictionary. The data were loaded to the database following BODC protocols.

A parameter mapping table is provided below:

Originators Parameter Originators Units Description BODC Parameter Code BODC Units
TOC µmol l-1 Concentration of organic carbon {organic_C CAS 7440-44-0} {DOC} per unit volume of the water body [dissolved plus reactive particulate <GF/F phase] by filtration and high temperature Pt catalytic oxidation CORGCOD1 µmol l-1
Error TOC µmol l-1 Concentration standard error of organic carbon {organic_C CAS 7440-44-0} {DOC} per unit volume of the water body [dissolved plus reactive particulate <GF/F phase] by filtration and high temperature Pt catalytic oxidation SEOCCOD1 µmol l-1
TDN µmol l-1 Concentration of total nitrogen {total_N} per unit volume of the water body [dissolved plus reactive particulate <GF/F phase] by filtration and high temperature Pt catalytic oxidation NTOTCOD1 µmol l-1
Error TDN µmol l-1 Concentration standard error of total nitrogen {total_N} per unit volume of the water body [dissolved plus reactive particulate <GF/F phase] by filtration and high temperature Pt catalytic oxidation SETNCOD1 µmol l-1

Data Quality Report

No flags assigned.


Project Information

UKOARP Theme B: Ocean acidification impacts on sea surface biology, biogeochemistry and climate

The overall aim of this theme is to obtain a quantitative understanding of the impact of ocean acidification (OA) on the surface ocean biology and ecosystem and on the role of the surface ocean within the overall Earth System.

The aims of the theme are:

  • To ascertain the impact of OA on planktonic organisms (in terms of physiological impacts, morphology, population abundances and community composition).
  • To quantify the impacts of OA on biogeochemical processes affecting the ocean carbon cycle (both directly and indirectly, such as via availability of bio-limiting nutrients).
  • To quantify the impacts of OA on the air-sea flux of climate active gases (DMS and N2O in particular).

The main consortium activities will consist of in-situ measurements on three dedicated cruises, as well as on-deck bioassay experiments probing the response of the in-situ community to elevated CO2. Most of the planned work will be carried out on the three cruises to locations with strong gradients in seawater carbon chemistry and pH; the Arctic Ocean, around the British Isles and the Southern Ocean.

Weblink: http://www.oceanacidification.org.uk/research_programme/surface_ocean.aspx


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 2012-06-08
End Date (yyyy-mm-dd) 2012-06-08
Organization Undertaking ActivityScottish Association for Marine Science
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierJR20120601_CTD_CTD017s
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for JR20120601_CTD_CTD017s

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
757430   20.00 1 1  278.50  281.60  276.50 Niskin bottle No problem reported    
757433   20.00 2 2  279.00  281.00  276.40 Niskin bottle Bottle leak    
757436   20.00 3 3  151.00  151.60  149.10 Niskin bottle No problem reported    
757439   20.00 4 4  149.80  151.80  148.60 Niskin bottle No problem reported    
757442   20.00 5 5  100.60  102.00   99.60 Niskin bottle No problem reported    
757445   20.00 6 6  101.10  102.30  100.00 Niskin bottle No problem reported    
757448   20.00 7 7   80.90   81.40   79.60 Niskin bottle No problem reported    
757451   20.00 8 8   80.80   81.50   79.60 Niskin bottle No problem reported    
757454   20.00 9 9   60.40   61.70   59.70 Niskin bottle No problem reported    
757457   20.00 10 10   60.50   61.10   59.50 Niskin bottle Bottle leak    
757460   20.00 11 11   39.60   41.00   39.20 Niskin bottle No problem reported    
757463   20.00 12 12   39.70   41.80   39.60 Niskin bottle No problem reported    
757466   20.00 13 13   30.60   31.50   30.00 Niskin bottle No problem reported    
757469   20.00 14 14   30.60   31.00   29.80 Niskin bottle No problem reported    
757472   20.00 15 15   30.70   30.90   29.80 Niskin bottle No problem reported    
757475   20.00 16 16   30.20   31.10   29.60 Niskin bottle No problem reported    
757478   20.00 17 17   19.90   20.70   19.40 Niskin bottle No problem reported    
757481   20.00 18 18   20.00   20.70   19.40 Niskin bottle No problem reported    
757484   20.00 19 19   19.60   21.10   19.40 Niskin bottle No problem reported    
757487   20.00 20 20   20.40   20.90   19.70 Niskin bottle Bottle leak    
757490   20.00 21 21    6.90    7.60    6.40 Niskin bottle No problem reported    
757493   20.00 22 22    6.80    7.70    6.40 Niskin bottle No problem reported    
757496   20.00 23 23    7.00    7.90    6.60 Niskin bottle No problem reported    
757499   20.00 24 24    7.20    7.70    6.60 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name JR20120601 (JR271)
Departure Date 2012-06-01
Arrival Date 2012-07-02
Principal Scientist(s)Ray Leakey (Scottish Association for Marine Science)
Ship RRS James Clark Ross

Complete Cruise Metadata Report is available here


Fixed Station Information


No Fixed Station Information held for the Series


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: JR20120601_CTD_CTD017s

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
2280930Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
2282647Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
2282820Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
2283976Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
2288575Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
2289056Water sample data2012-06-08 06:27:3060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)
1860218Water sample data2012-06-08 06:28:0060.59422 N, 18.85645 WRRS James Clark Ross JR20120601 (JR271)