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Metadata Report for BODC Series Reference Number 2290069


Metadata Summary

Data Description

Data Category Water sample data
Instrument Type
NameCategories
Niskin bottle  discrete water samplers
Instrument Mounting lowered unmanned submersible
Originating Country Belgium
Originator Dr Michel Frankignoulle
Originating Organization University of Liège Department of Astrophysics Geophysics and Oceanography
Processing Status banked
Online delivery of data Download available - Ocean Data View (ODV) format
Project(s) OMEX II-II
 

Data Identifiers

Originator's Identifier CD110B_CTD_DOXY_69:CTD47
BODC Series Reference 2290069
 

Time Co-ordinates(UT)

Start Time (yyyy-mm-dd hh:mm) 1998-01-10 15:00
End Time (yyyy-mm-dd hh:mm) -
Nominal Cycle Interval -
 

Spatial Co-ordinates

Latitude 41.41920 N ( 41° 25.2' N )
Longitude 9.10146 W ( 9° 6.1' W )
Positional Uncertainty 0.05 to 0.1 n.miles
Minimum Sensor or Sampling Depth 4.1 m
Maximum Sensor or Sampling Depth 98.8 m
Minimum Sensor or Sampling Height 11.5 m
Maximum Sensor or Sampling Height 106.2 m
Sea Floor Depth 110.3 m
Sea Floor Depth Source PEVENT
Sensor or Sampling Distribution Variable common depth - All sensors are grouped effectively at the same depth, but this depth varies significantly during the series
Sensor or Sampling Depth Datum Instantaneous - Depth measured below water line or instantaneous water body surface
Sea Floor Depth Datum Unspecified -
 

Parameters

BODC CODERankUnitsTitle
ADEPZZ011MetresDepth (spatial coordinate) relative to water surface in the water body
BOTTFLAG1Not applicableSampling process quality flag (BODC C22)
DOXYWITX1Micromoles per litreConcentration of oxygen {O2 CAS 7782-44-7} per unit volume of the water body [dissolved plus reactive particulate phase] by Winkler titration
OXYSBW011PercentSaturation of oxygen {O2 CAS 7782-44-7} in the water body [dissolved plus reactive particulate phase] by Winkler titration and computation from concentration using Benson and Krause algorithm
SAMPRFNM1DimensionlessSample reference number

Definition of BOTTFLAG

BOTTFLAGDefinition
0The sampling event occurred without any incident being reported to BODC.
1The filter in an in-situ sampling pump physically ruptured during sample resulting in an unquantifiable loss of sampled material.
2Analytical evidence (e.g. surface water salinity measured on a sample collected at depth) indicates that the water sample has been contaminated by water from depths other than the depths of sampling.
3The feedback indicator on the deck unit reported that the bottle closure command had failed. General Oceanics deck units used on NERC vessels in the 80s and 90s were renowned for reporting misfires when the bottle had been closed. This flag is also suitable for when a trigger command is mistakenly sent to a bottle that has previously been fired.
4During the sampling deployment the bottle was fired in an order other than incrementing rosette position. Indicative of the potential for errors in the assignment of bottle firing depth, especially with General Oceanics rosettes.
5Water was reported to be escaping from the bottle as the rosette was being recovered.
6The bottle seals were observed to be incorrectly seated and the bottle was only part full of water on recovery.
7Either the bottle was found to contain no sample on recovery or there was no bottle fitted to the rosette position fired (but SBE35 record may exist).
8There is reason to doubt the accuracy of the sampling depth associated with the sample.
9The bottle air vent had not been closed prior to deployment giving rise to a risk of sample contamination through leakage.

Definition of Rank

  • Rank 1 is a one-dimensional parameter
  • Rank 2 is a two-dimensional parameter
  • Rank 0 is a one-dimensional parameter describing the second dimension of a two-dimensional parameter (e.g. bin depths for moored ADCP data)

Problem Reports

No Problem Report Found in the Database


Data Access Policy

Public domain data

These data have no specific confidentiality restrictions for users. However, users must acknowledge data sources as it is not ethical to publish data without proper attribution. Any publication or other output resulting from usage of the data should include an acknowledgment.

The recommended acknowledgment is

"This study uses data from the data source/organisation/programme, provided by the British Oceanographic Data Centre and funded by the funding body."


Narrative Documents

Niskin Bottle

The Niskin bottle is a device used by oceanographers to collect subsurface seawater samples. It is a plastic bottle with caps and rubber seals at each end and is deployed with the caps held open, allowing free-flushing of the bottle as it moves through the water column.

Standard Niskin

The standard version of the bottle includes a plastic-coated metal spring or elastic cord running through the interior of the bottle that joins the two caps, and the caps are held open against the spring by plastic lanyards. When the bottle reaches the desired depth the lanyards are released by a pressure-actuated switch, command signal or messenger weight and the caps are forced shut and sealed, trapping the seawater sample.

Lever Action Niskin

The Lever Action Niskin Bottle differs from the standard version, in that the caps are held open during deployment by externally mounted stainless steel springs rather than an internal spring or cord. Lever Action Niskins are recommended for applications where a completely clear sample chamber is critical or for use in deep cold water.

Clean Sampling

A modified version of the standard Niskin bottle has been developed for clean sampling. This is teflon-coated and uses a latex cord to close the caps rather than a metal spring. The clean version of the Levered Action Niskin bottle is also teflon-coated and uses epoxy covered springs in place of the stainless steel springs. These bottles are specifically designed to minimise metal contamination when sampling trace metals.

Deployment

Bottles may be deployed singly clamped to a wire or in groups of up to 48 on a rosette. Standard bottles and Lever Action bottles have a capacity between 1.7 and 30 L. Reversing thermometers may be attached to a spring-loaded disk that rotates through 180° on bottle closure.

Dissolved Oxygen for Belgica, Charles Darwin and Meteor cruises

Document History

Converted from CDROM documentation

Content of data series

DOXYPR01 Beckman oxygen
Beckman oxygen probe
Micromoles/litre
DOXYWITX Winkler oxygen
Winkler titration
Micromoles/litre
OXYSBB01 Oxygen saturation (Bens.Kr./Beckman)
Benson and Krause algorithm from Beckman data
Per cent
OXYSBW01 Oxygen saturation (Bens.Kr./Winkler)
Benson and Krause algorithm from Winkler titration data
Per cent

Data Originator

Dr Michel Frankignoulle, University of Liège, Belgium.

Sampling strategy and methodology

Cruises: Belgica BG9714B, BG9714C, BG9714D, BG9815B, BG9815C, BG9815D, BG9919A, BG9919B and BG9919C, Charles Darwin CD110B, CD114A and CD114B and Meteor M43_2.

Water samples from CTD rosette bottles were analysed using the classical Winkler technique with minor modifications. Calibrated 100ml oxygen bottles with ground glass stoppers were thoroughly flushed then filled without trapping any air. 1 ml of solution A (600g MnCl2. 4H2O per litre) and 2ml of solution B (250g NaOH, 350g KI per litre) were added immediately and the closed bottles shaken vigorously. The samples were shaken again once the precipitate had settled. The samples were titrated using a Metrohm automatic titration system.

The data were supplied in units of micromoles/kg. These were converted to micromoles/litre through application of the following transform:

Database value = Original value/TOKGxx01

Where TOKGxx01 is the database litres to kilogram conversion factor TOKGPR01 or TOKGSG01 (PR = CTD, SG = thermosalinograph), which is stored with the data.

Oxygen saturations were computed using calibrated temperature and salinity data and the algorithm of Benson and Krause (1984).

References

Benson, B.B., Krause D. (1984). The concentration and isotopic fractionation of oxygen dissolved in fresh water and sea water in equilibrium with the atmosphere. Limnol.Oceanogr., 29, 620-632.


Project Information

Ocean Margin EXchange (OMEX) II - II

Introduction

OMEX was a European multidisciplinary oceanographic research project that studied and quantified the exchange processes of carbon and associated elements between the continental shelf of western Europe and the open Atlantic Ocean. The project ran in two phases known as OMEX I (1993-1996) and OMEX II - II (1997-2000), with a bridging phase OMEX II - I (1996-1997). The project was supported by the European Union under the second and third phases of its MArine Science and Technology Programme (MAST) through contracts MAS2-CT93-0069 and MAS3-CT97-0076. It was led by Professor Roland Wollast from Université Libre de Bruxelles, Belgium and involved more than 100 scientists from 10 European countries.

Scientific Objectives

The aim of the Ocean Margin EXchange (OMEX) project was to gain a better understanding of the physical, chemical and biological processes occurring at the ocean margins in order to quantify fluxes of energy and matter (carbon, nutrients and other trace elements) across this boundary. The research culminated in the development of quantitative budgets for the areas studied using an approach based on both field measurements and modeling.

OMEX II - II (1997-2000)

The second phase of OMEX concentrated exclusively on the Iberian Margin, although RV Belgica did make some measurements on La Chapelle Bank whilst on passage to Zeebrugge. This is a narrow-shelf environment, which contrasts sharply with the broad shelf adjacent to the Goban Spur. This phase of the project was also strongly multidisciplinary in approach, covering physics, chemistry, biology and geology.

There were a total of 33 OMEX II - II research cruises, plus 23 CPR tows, most of which were instrumented. Some of these cruises took place before the official project start date of June 1997.

Data Availability

Field data collected during OMEX II - II have been published by BODC as a CD-ROM product, entitled:

  • OMEX II Project Data Set (three discs)

Further descriptions of this product and order forms may be found on the BODC web site.

The data are also held in BODC's databases and subsets may be obtained by request from BODC.


Data Activity or Cruise Information

Data Activity

Start Date (yyyy-mm-dd) 1998-01-10
End Date (yyyy-mm-dd) 1998-01-10
Organization Undertaking ActivityPlymouth Marine Laboratory
Country of OrganizationUnited Kingdom
Originator's Data Activity IdentifierCD110B_CTD_CTD47
Platform Categorylowered unmanned submersible

BODC Sample Metadata Report for CD110B_CTD_CTD47

Sample reference number Nominal collection volume(l) Bottle rosette position Bottle firing sequence number Minimum pressure sampled (dbar) Maximum pressure sampled (dbar) Depth of sampling point (m) Bottle type Sample quality flag Bottle reference Comments
563168   10.00      103.50  105.00   98.80 Niskin bottle No problem reported    
563169   10.00       75.20   77.20   71.00 Niskin bottle No problem reported    
563170   10.00       50.20   51.70   45.90 Niskin bottle No problem reported    
563171   10.00       24.90   26.80   21.00 Niskin bottle No problem reported    
563172   10.00        7.90    9.60    4.10 Niskin bottle No problem reported    

Please note:the supplied parameters may not have been sampled from all the bottle firings described in the table above. Cross-match the Sample Reference Number above against the SAMPRFNM value in the data file to identify the relevant metadata.

Related Data Activity activities are detailed in Appendix 1

Cruise

Cruise Name CD110B
Departure Date 1998-01-06
Arrival Date 1998-01-19
Principal Scientist(s)Axel E J Miller (Plymouth Marine Laboratory)
Ship RRS Charles Darwin

Complete Cruise Metadata Report is available here


Fixed Station Information

Fixed Station Information

Station NameOMEX II-II Repeat Section V
CategoryOffshore route/traverse

OMEX II-II Repeat Section V

Section V was one of ten repeat sections sampled during the Ocean Margin EXchange (OMEX) II-II project between June 1997 and January 1998.

The CTD measurements collected at repeat section V, at the Iberian Margin, lie within a box bounded by co-ordinates 41° 24.7' N, 09° 56.9' W at the southwest corner and 41° 25.5' N, 08° 52.4' W at the northeast corner.

Cruises occupying section V

Cruise Start Date End Date
RRS Charles Darwin 105B 10/06/1997 22/06/1997
RRS Charles Darwin 110B 06/01/1998 19/01/1998

Related Fixed Station activities are detailed in Appendix 2


BODC Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
Blank Unqualified
< Below detection limit
> In excess of quoted value
A Taxonomic flag for affinis (aff.)
B Beginning of CTD Down/Up Cast
C Taxonomic flag for confer (cf.)
D Thermometric depth
E End of CTD Down/Up Cast
G Non-taxonomic biological characteristic uncertainty
H Extrapolated value
I Taxonomic flag for single species (sp.)
K Improbable value - unknown quality control source
L Improbable value - originator's quality control
M Improbable value - BODC quality control
N Null value
O Improbable value - user quality control
P Trace/calm
Q Indeterminate
R Replacement value
S Estimated value
T Interpolated value
U Uncalibrated
W Control value
X Excessive difference

SeaDataNet Quality Control Flags

The following single character qualifying flags may be associated with one or more individual parameters with a data cycle:

Flag Description
0 no quality control
1 good value
2 probably good value
3 probably bad value
4 bad value
5 changed value
6 value below detection
7 value in excess
8 interpolated value
9 missing value
A value phenomenon uncertain
B nominal value
Q value below limit of quantification

Appendix 1: CD110B_CTD_CTD47

Related series for this Data Activity are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
1230726Water sample data1998-01-10 15:00:0041.4192 N, 9.10146 WRRS Charles Darwin CD110B
1676913Water sample data1998-01-10 15:00:0041.4192 N, 9.10146 WRRS Charles Darwin CD110B
1706283Water sample data1998-01-10 15:00:0041.4192 N, 9.10146 WRRS Charles Darwin CD110B
2262775Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2262911Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2263023Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2283208Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2283792Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2289984Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B

Appendix 2: OMEX II-II Repeat Section V

Related series for this Fixed Station are presented in the table below. Further information can be found by following the appropriate links.

If you are interested in these series, please be aware we offer a multiple file download service. Should your credentials be insufficient for automatic download, the service also offers a referral to our Enquiries Officer who may be able to negotiate access.

Series IdentifierData CategoryStart date/timeStart positionCruise
866634CTD or STD cast1997-06-14 18:10:0041.41717 N, 9.94967 WRRS Charles Darwin CD105B
865852CTD or STD cast1997-06-14 21:36:0041.4165 N, 9.78217 WRRS Charles Darwin CD105B
866646CTD or STD cast1997-06-15 01:44:0041.416 N, 9.651 WRRS Charles Darwin CD105B
866658CTD or STD cast1997-06-15 04:55:0041.41683 N, 9.518 WRRS Charles Darwin CD105B
865864CTD or STD cast1997-06-15 07:03:0041.41583 N, 9.40083 WRRS Charles Darwin CD105B
865920CTD or STD cast1997-06-15 09:30:0041.41767 N, 9.28133 WRRS Charles Darwin CD105B
866671CTD or STD cast1997-06-15 11:44:0041.41867 N, 9.18717 WRRS Charles Darwin CD105B
866683CTD or STD cast1997-06-15 13:03:0041.41617 N, 9.0985 WRRS Charles Darwin CD105B
865876CTD or STD cast1997-06-15 14:13:0041.41617 N, 8.9655 WRRS Charles Darwin CD105B
866204CTD or STD cast1997-06-15 15:20:0041.41167 N, 8.87383 WRRS Charles Darwin CD105B
867127CTD or STD cast1998-01-10 07:21:0041.4225 N, 9.38567 WRRS Charles Darwin CD110B
2262751Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
2262880Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
2263011Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
2283189Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
2289972Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
2290057Water sample data1998-01-10 08:31:4641.42242 N, 9.38564 WRRS Charles Darwin CD110B
867139CTD or STD cast1998-01-10 13:23:0041.42017 N, 9.09983 WRRS Charles Darwin CD110B
2262763Water sample data1998-01-10 13:33:3941.42022 N, 9.09978 WRRS Charles Darwin CD110B
2262892Water sample data1998-01-10 13:33:3941.42022 N, 9.09978 WRRS Charles Darwin CD110B
2283190Water sample data1998-01-10 13:33:3941.42022 N, 9.09978 WRRS Charles Darwin CD110B
867140CTD or STD cast1998-01-10 14:50:0041.41917 N, 9.1015 WRRS Charles Darwin CD110B
2262775Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2262911Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2263023Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2283208Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2283792Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
2289984Water sample data1998-01-10 15:00:2241.4192 N, 9.10146 WRRS Charles Darwin CD110B
867152CTD or STD cast1998-01-10 16:01:0041.418 N, 9.10067 WRRS Charles Darwin CD110B
2262787Water sample data1998-01-10 16:10:0941.41805 N, 9.1007 WRRS Charles Darwin CD110B
2262923Water sample data1998-01-10 16:10:0941.41805 N, 9.1007 WRRS Charles Darwin CD110B